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Chapter 4: Work and Heat

Thermodynamics 1
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(4.110/4.103) Two kilograms of water is contained
in a piston/cylinder with a massless piston
loaded with a linear spring and the outside
atmosphere. Initially the spring force is zero and
P1 = Po = 100 kPa with a volume of 0.2 m3. If
the piston just hits the upper stops the volume is
0.8 m3 and T = 600°C. Heat is now added until
the pressure reaches 1.2 MPa. Find the final
temperature, show the P–V diagram and find the
work done during the process.

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V1 0.2
State 1: v1    0.1 m3 / kg, P1  100 kPa
m 2
v f @100 kPa  v1  vg @100 kPa  it is saturated mixture

State 2: at stops
Vstop 0.8
v2    0.4 m / kg & T2  600 C
3 o

m 2
v2  vg @600o C  it is superheated

Table B.1.3  Pstop  P2 = 1 MPa < P3

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State 3: P3  1.2 MPa, v3  v2  0.4 m / kg
3

From Table B.1.3  700o C  T3  800o C


by interpolation  T3  770 Co

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W  1W2  2W3  ( P1  P2 ) (V2  V1 )  0
1 3
2
1
 (100  1000) kPa (0.8  0.2) m 3

2
 330 kJ

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(4.111/4.106) A cylinder having an initial volume of
3 m3 contains 0.1 kg of water at 40oC. The water
is then compressed in an isothermal quasi-
equilibrium process until it has a quality of 50%.
Calculate the work done by splitting the process
into two steps. Assume the water vapor is an
ideal gas during the first step of the process.

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State 1: V1  3 m3 , T1  40o C, m  0.1 kg
3 m3
v1 
0.1 kg

 30 m3 /kg > vg for 40o C 
v1 > vg @ 40oC  Superheated vapor

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From 1-2 water vapor is an ideal gas with T = C
P2  Psat@40o C  7.384 kPa
3
v2  vg @ 40o C  19.52 m /kg
3
v2 19.52 m /kg
P1  P2   7.384 kPa  3
 4.8 kPa
v1 30 m /kg
3 3
V2  mv2  0.1 kg  19.52 m /kg = 1.952 m
V2 1.952
1W2   PdV  PV
3
1 1 ln  4.8 kPa  3 m  ln
V1 3
 6.19 kJ
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Process 2-3  P  constant
v3  0.001008  0.5  19.519  9.7605 m /kg
3

V3  mv3  0.1 kg  9.7605 m /kg  0.976 m


3 3

3
W3   PdV  P2 V3  V2 
2
2

 7.348 kPa   0.976  1.952  m3


 7.21 kJ
W  1W2  2W3  6.19 kJ  7.21 kJ
1 3

 13.4 kJ

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(4.112/4.113) Air at 200 kPa, 30°C is contained in a
cylinder/piston arrangement with initial volume
0.1 m3 . The inside pressure balances ambient
pressure of 100 kPa plus an externally imposed
force that is proportional to V0.5. Now heat is
transferred to the system to a final pressure of
225 kPa. Find the final temperature and the
work done in the process.

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C.V. Air. This is a control mass. Use initial state and
process to find T2.
P1  Po  CV11/ 2  200  100  C(0.1)1/ 2  C  316.23
225  100  CV21/ 2  V2  0.156 m3

P2 V2 225  0.156
T2   T1   303.15 = 532 K
P1 V1 200  0.1

    o  1/ 2
W
1 2
PdV ( P CV ) dV
2
 Po (V2  V1 )  C   (V23/ 2  V13/ 2 )  11.9 kJ
3
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(4.115/?) Two springs with same spring constant are
installed in a massless piston/cylinder with the
outside air at 100 kPa. If the piston is at the
bottom, both springs are relaxed and the second
spring comes in contact with the piston at V = 2
m3. The cylinder contains ammonia initially at
-2°C, x = 0.13, V = 1 m3, which is then heated
until the pressure finally reaches 1200 kPa. At
what pressure will the piston touch the second
spring? Find the final temperature and the total
work done by the ammonia.

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State 0 : 0 m3 , 100 kPa
State 1: T1  2 C, x  0.13, V1  1 m
o 3

From Table B.2.1 (692)  by interpolation


P1  399.7 kPa, v1  0.00156  0.13  0.3106  0.0419 m3 /kg
State 2 : V2  2 m3
P P1  P0
Slope of line 0-1-2 
V V1  V0
399.7 kPa  100 kPa
  299.7 kPa/m 3

1 m3
P2  P1  V2  V1  P / V
 399.7 kPa   2  1 m3  299.7 kPa/m3  699.4 kPa

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State 3: P3  1200 kPa
P3  P2  V3  V2  2P / V 
V3  V2   P3  P2  /  2P / V 
 2 m3  1200  699.4  kPa /  2  299.7  kPa/m 3
 2.835 m3
v3  V3 / V1 / v1 
 2.835 m3 / 1 m3 / 0.0419 m3 /kg 
 0.1188 m3 /kg
From Table B.2.2 for P3  1200 kPa, v3  0.1188 m3 /kg 
T3  51o C
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1 1
W  1W2  2W3  ( P1  P2 ) (V2  V1 )  ( P2  P3 ) (V3  V2 )
1 3
2 2
1
 (399.7  699.4) kPa  (2  1)m3
2
1
 (699.4  1200) kPa  (2.835  2)m 3
2
 1342.6 kJ

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