Loctite 404 Eng PDF

Safety Data Sheet
Revision Number: 004.0 Issue date: 10/24/2022
1. PRODUCT AND COMPANY IDENTIFICATION

Product name: LOCTITE 404 INSTANT ADHESIVE IDH number: 135465
known as LOCTITE® 404™ INSTANT
ADHESIVE
Product type/use: Cyanoacrylate Item number: 46551
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: BONDS SKIN IN SECONDS.
COMBUSTIBLE LIQUID.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF CAUSING CANCER.
HAZARD CLASS HAZARD CATEGORY

FLAMMABLE LIQUID 4
EYE IRRITATION 2B
CARCINOGENICITY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S)
Precautionary Statements
Prevention:
Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Keep away from heat, sparks, open flames, hot surfaces - no smoking.
Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling. Use only
outdoors or in a well-ventilated area. Wear protective gloves, clothing, eye and face protection.
Response:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. IF exposed or concerned: Get medical attention. If eye irritation persists: Get
medical attention. In case of fire: Use foam, dry chemical or carbon dioxide to extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal:
Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.

IDH number: 135465 Product name: LOCTITE 404 INSTANT ADHESIVE known as LOCTITE® 404™ INSTANT ADHESIVE
Page 1 of 5
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Component(s) CAS Number Percentage*
Ethyl 2-cyanoacrylate 7085-85-0 80 - 100
Hydroquinone 123-31-9 0.1 - 1
* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.
4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.
Skin contact: Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart
using a blunt instrument. If skin is burned due to the rapid generation of heat
by a large drop, seek medical attention. If lips are bonded, apply warm water
to the lips and encourage wetting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart with direct opposing force.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. Get medical
attention. If eyelids are bonded closed, release eyelashes with warm water by
covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and will cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually within 1-3
days. Medical attention should be sought in case solid particles of
polymerized cyanoacrylate trapped behind the eyelid caused abrasive
damage.
Ingestion: Ensure breathing passages are not obstructed. The product will polymerize
rapidly and bond to the mouth making it almost impossible to swallow. Saliva
will separate any solidified product in several hours. Prevent the patient from
swallowing any separated mass.
Symptoms: See Section 11.
Notes to physician: Surgery is not necessary to separate accidentally bonded tissues. Experience
has shown that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal burns they should be treated
symptomatically after adhesive is removed.
5. FIRE FIGHTING MEASURES

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode.
Unusual fire or explosion hazards: None
Hazardous combustion products: Trace amounts of toxic and/or irritating fumes may be released and the use of
breathing apparatus is recommended.
6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and
unprotected personnel.
Environmental precautions: Ventilate area. Do not allow product to enter sewer or waterways.
Clean-up methods: Do not use cloths for mopping up. Flood with water to complete polymerization
and scrape off the floor. Cured material can be disposed of as non-hazardous
waste. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.
Page 2 of 5
7. HANDLING AND STORAGE
Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Avoid contact with fabric or paper goods.
Contact with these materials may cause rapid polymerization which can
generate smoke and strong irritating vapors, and cause thermal burns.
Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper
exposure controls and protective equipment for each task performed.
Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

1 ppm STEL
0.2 ppm TWA
Ethyl 2-cyanoacrylate (Respiratory None None None
sensitization)
(Dermal sensitization)
1 mg/m3 TWA
Hydroquinone 2 mg/m3 PEL None None
Engineering controls: Use positive down-draft exhaust ventilation if general ventilation is insufficient
to maintain vapor concentration below established exposure limits.
Respiratory protection: Use a NIOSH approved supplied air respirator with an organic cartridge if the
potential to exceed established exposure limits exists.
Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.
Skin protection: Use nitrile gloves and aprons as necessary to prevent contact. Do not use
PVC, nylon or cotton.
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Liquid
Color: Clear, Colorless
Odor: Sharp, Irritating
Odor threshold: 1 - 2 ppm
pH: Not applicable
Vapor pressure: < 0.2 mm hg
Boiling point/range: > 149 °C (> 300.2 °F)
Melting point/ range: Not determined
Specific gravity: 1.09 at 23.9 °C (75.02 °F)
Vapor density: 3 Approximately
Flash point: 80 - 93 °C (176°F - 199.4 °F) Tagliabue closed cup
Flammable/Explosive limits - lower: Not determined
Flammable/Explosive limits - upper: Not determined
Autoignition temperature: 485 °C (905°F)
Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Polymerises in presence of water.
Partition coefficient (n-octanol/water): Not determined
VOC content: < 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)
Viscosity: Not available.
Decomposition temperature: Not available.
Page 3 of 5
10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.
Hazardous reactions: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and
alcohols.
Hazardous decomposition None

products:
Incompatible materials: Water, amines, alkalis and alcohols.
Reactivity: Not available.
Conditions to avoid: Spontaneous polymerization.
11. TOXICOLOGICAL INFORMATION

Relevant routes of exposure: Skin, Inhalation, Eyes
Potential Health Effects/Symptoms
Inhalation: May cause respiratory tract irritation. Exposure to vapors above the established exposure limit
results in respiratory irritation, which may lead to difficulty in breathing and tightness in the
chest.
Skin contact: Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported to cause
allergic reaction but due to rapid polymerization at the skin surface, an allergic response is rare.
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop will burn the
skin. Cured adhesive does not present a health hazard even if bonded to the skin.
Eye contact: Irritating to eyes. Causes excessive tearing. Eyelids may bond.
Ingestion: Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It
is almost impossible to swallow.
Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Ethyl 2-cyanoacrylate None Irritant, Allergen, Respiratory
Oral LD50 (Rat) = 320 mg/kg
Blood, Bone Marrow, Central nervous
Oral LD50 (Mouse) = 245 mg/kg
Hydroquinone system, Developmental, Eyes, Immune
Oral LD50 (Rabbit) = 540 mg/kg
system, Irritant, Liver, Mutagen, Skin, Thyroid
Dermal LD50 (Rat) = > 900 mg/kg
OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Ethyl 2-cyanoacrylate No No No
Hydroquinone No No No
12. ECOLOGICAL INFORMATION

Ecological information: Not available.
13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.
Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.
14. TRANSPORT INFORMATION

The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.
U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Combustible liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: Combustible Liquid
Identification number: NA 1993
Packing group: III
DOT Hazardous Substance(s): Hydroquinone
Page 4 of 5
International Air Transportation (ICAO/IATA)
Proper shipping name: Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: 9
Identification number: UN 3334
Packing group: III
Exceptions: (Not more than 500ml) Unrestricted
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated

Hazard class or division: None
Identification number: None
Packing group: None
15. REGULATORY INFORMATION

United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed as active or are exempt from listing on the Toxic Substances
Control Act (TSCA) inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
CERCLA/SARA Section 302 EHS: Hydroquinone (CAS# 123-31-9).

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire, Reactive
CERCLA/SARA Section 313: None above reporting de minimis.
CERCLA Reportable quantity: Hydroquinone (CAS# 123-31-9) 100 lbs. (45.4 kg)
California Proposition 65: No California Proposition 65 listed chemicals are known to be present.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.
16. OTHER INFORMATION

This safety data sheet contains changes from the previous version in sections: 3,8,13,15
Prepared by: Product Safety and Regulatory Affairs
Issue date: 10/24/2022
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.
Page 5 of 5
Safety Data Sheet

Product name: LOCTITE 454 PRISM SURF IDH num ber: 233998
Product type/use: Adhesive Item number: 45404
Com pany address: Contact information:
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: w ww.henkelna.com
EMERGENCY OVERVIEW
COMBUSTIBLE LIQUID.

FLAMMABLE LIQUID 4
EYE IRRITATION 2B
PICTOGRAM(S)
Prevention:
Keep aw ay from heat, sparks, open flames, hot surfaces - no smoking. Avoid breathing vapors,
mist, or spray. Wash affected area thoroughly after handling. Use only outdoors or in a w ell-
ventilated area. Wear protective gloves, eye protection, and face protection.
Response:
breathing. Call a POISON CENTER or physician if you feel unw ell. IF IN EYES: Rinse
cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage:
Store in a w ell-ventilated place. Keep container tightly closed. Store in a w ell-ventilated place.
Disposal:
Classification complies w ith OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of t he

Hazardous Component(s) CAS Num ber Percentage*
IDH number: 233998 Product name: LOCTITE 454 PRISM SURF
Page 1 of 5
Siloxanes and Silicones, di-Me, reaction
67762-90-7 5 - 10
products w ith silica
* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate pr otections.

Skin contact: Do not pull bonded skin apart. Soak in w arm soapy water. Gently peel apart
by a large drop, seek medical attention. If lips are bonded, apply w arm water
to the lips and encourage w etting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart w ith direct opposing force.
Eye contact: Immediately flush w ith plenty of w ater for at least 15 minutes. Get medical
covering w ith a w et pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and w ill cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually w ithin 1-3
damage.
Ingestion: Ensure breathing passages are not obstructed. The product w ill polymerize
rapidly and bond to the mouth making it almost impossible to sw allow. Saliva
w ill separate any solidified product in several hours. Prevent the patient from
sw allowing any separated mass.
Sym ptoms: See Section 11.
has show n that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal bums they should be treated


Environm ental precautions: Ventilate area. Do not allow product to enter sew er or waterways.
Clean-up methods: Do not use cloths for mopping up. Flood w ith w ater to complete polymerization
w aste. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.

Page 2 of 5
Handling: Prevent contact w ith eyes, skin and clothing. Do not breathe vapor and mist.
Contact w ith these materials may cause rapid polymerization w hich can
Storage: Not available.

Em ployers should complete an assessment of all w orkplaces to determine the need for, and selection of, proper

1 ppm STEL
0.2 ppm TWA
sensitization)
10 mg/m3 TWA 15 mg/m3 TWA Total
Siloxanes and Silicones, di-Me, reaction Inhalable dust. dust.
None None
products w ith silica 3 mg/m3 TWA 5 mg/m3 TWA
Respirable fraction. Respirable fraction.
Engineering controls: Use positive dow n-draft exhaust ventilation if general ventilation is insufficient
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s). Use NIOSH approved respirator if there is potential to exceed
exposure limit(s).
be used if the potential for splashing or spraying of product exists. Safety
goggles or safety glasses with side shields. Full face protection should be
used if the potential for splashing or spraying of product exists.
PVC, nylon or cotton. Use nitrile gloves and aprons as necessary to prevent
contact. Do not use PVC, nylon or cotton.

Color: Colorless
Odor: Irritating
Odor threshold: Not available.
pH: Not available.
Vapor pressure: < 0.2 mm hg no method < 26.7 Pa no method < 700 mbar (50 °C (122°F)) no
method
Melting point/ range: Not available.
Vapor density: Not available.
Flash point: 80 - 93 °C (176°F - 199.4 °F)
Flam m able/Explosive limits - low er: Not available.
Flam m able/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Flam m ability: Not applicable
Solubility in w ater: Polymerises in presence of w ater.
Partition coefficient (n-octanol/water): Not available.
Viscosity: 18,000.00 - 40,000.00 mPa.s
Viscosity: 18,000.00 - 40,000.00 mPa.s
Decom position temperature: Not available.

Page 3 of 5
Hazardous reactions: Rapid exothermic polymerization w ill occur in the presence of water, amines, alkalis and
alcohols.

products:
Incom patible materials: Water, amines, alkalis and alcohols.

results in respiratory irritation, w hich may lead to difficulty in breathing and tightness in the
chest.
Skin contact: May cause skin irritation. Bonds skin in seconds. Cyanoacrylates have been reported to cause
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop w ill burn the
is almost impossible to sw allow.
Hazardous Component(s) LD50s and LC50s Im m ediate and Delayed Health Effects
None No Data
OSHA Carcinogen
No No No

Ecological inform ation: Not available.

Recom mended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

The transport information provided in this section only applies to the material/formulation itself, and is not specific to an y

Packing group: III

Page 4 of 5
Packing group: III
Exceptions: Primary packs containing less than 500ml are unregulated by this mode of
transport and may be shipped unrestricted.

Packing group: None

CERCLA/SARA Section 302 EHS: None above reporting de minimis.

CERCLA/SARA Section 311/312: Reactive, Fire, Immediate Health, Delayed Health
California Proposition 65: This product contains a chemical know n to the State of California to cause birth defects or
other reproductive harm.
CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other
components are listed on or are exempt from listing on the Domestic Substances List.
Components listed on the NDSL must be tracked by all Canadian Importers of Record as
required by Environment Canada. They may be imported into Canada in limited quantities.
Please contact Regulatory Affairs for additional details.

This safety data sheet contains changes from the previous version in sections: 9
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. How ever, Henkel
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property a nd
Henkel specifically disclaims all w arranties, express or implied, including w arranties of merchantability and fitness for a particular
information in accordance with U.S. federal law only. No w arranty or representation of any kind is given w ith respect to the
substantive or export law s of any other jurisdiction or country. Please confirm that the information provided herein conforms to the

Page 5 of 5
Safety Data Sheet

Product name: Retaining Compound 641 Medium IDH number: 233546
Strength
Product type/use: Sealant Item number: 28802
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE.

SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2
PICTOGRAM(S)
Prevention: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear protective
gloves, eye protection, and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical
attention if you feel unwell. If skin irritation or rash occurs: Get medical attention. If eye irritation
persists: Get medical attention. Take off contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local

Polyglycol dioctanoate 18268-70-7 10 - 30
Cumene hydroperoxide 80-15-9 1-5
IDH number: 233546 Product name: Retaining Compound 641 Medium Strength
Page 1 of 5
Saccharin 81-07-2 1-5
Methyl methacrylate 80-62-6 0.1 - 1

Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Wash clothing before reuse. Get medical
attention.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.

Never give anything by mouth to an unconscious person. Get medical
attention.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. In case of fire, keep containers cool with water spray.
Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in
explosions or rupture of storage containers.
Hazardous combustion products: Oxides of carbon. Irritating organic vapours.

Environmental precautions: Do not allow product to enter sewer or waterways.
Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up as much material as possible. Store in a
partly filled, closed container until disposal. Refer to Section 8 "Exposure
Controls / Personal Protection" prior to clean up.

Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and
clothing. Do not breathe vapor and mist. Wash thoroughly after handling.
Keep container closed. Refer to Section 8.
Storage: For safe storage, store at or below 38 °C (100.4 °F)

Keep in a cool, well ventilated area away from heat, sparks and open flame.
Page 2 of 5

Polyglycol dioctanoate None None None None
1 ppm (6 mg/m3)
Cumene hydroperoxide None None TWA None
(SKIN)
Saccharin None None None None
50 ppm TWA
100 ppm (410
Methyl methacrylate 100 ppm STEL None 50 ppm
mg/m3) PEL
Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.
limit(s).
showers and eye wash stations should be available.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact. Neoprene gloves.

Color: Yellow
Odor: Characteristic
pH: Not applicable, Product is non-polar/aprotic.
Vapor pressure: < 5 mm hg (27 °C (80.6 °F)) < 0.13 mbar (20 °C (68°F))
Boiling point/range: > 150 °C (> 302°F)
Melting point/ range: Not applicable, Product is a liquid
Specific gravity: 1.08 at 20 °C (68°F)
Vapor density: > 1 20 °C
Flash point: > 100 °C (> 212°F) Tagliabue closed cup; No flash point up to 100 °C
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Flammability: The product is not flammable.
Solubility in water: Slight
Solubility in water: Miscible
VOC content: 0.07 %; 0.75 g/l
0.7 %

Stability: Stable under normal conditions of storage and use.
Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the
presence of incompatible materials.
Hazardous decomposition Oxides of carbon. Irritating organic vapours.

products:
Incompatible materials: Free radical initiators. Oxidizing agents. Reducing agents. Metal oxides. Acids. Alkalis.
Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from
incompatible materials.
Page 3 of 5
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. May
cause irritation to nose and throat.
Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye irritation.
Ingestion: May cause irritation to the gastrointestinal tract, mouth and mucous membranes.
Polyglycol dioctanoate None Irritant
Allergen, Central nervous system, Corrosive,
Cumene hydroperoxide None
Irritant, Mutagen
Saccharin Oral LD50 (Mouse) = 17 g/kg No Target Organs
Oral LD50 (Rat) = 7,800 mg/kg
Allergen, Irritant, Kidney, Liver, Mutagen,
Methyl methacrylate Oral LD50 (Rabbit) = 6,000 mg/kg
Nervous System, Respiratory
OSHA Carcinogen
Polyglycol dioctanoate No No No
Cumene hydroperoxide No No No
Saccharin No No No
Methyl methacrylate No No No



The transport information provided in this section only applies to the material/formulation itself, and is not specific to any packaging.

Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Packing group: III
DOT Hazardous Substance(s): alpha,alpha-Dimethylbenzylhydroperoxide

Packing group: III

Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Packing group: III
Page 4 of 5

CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2).
CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg)
California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
Substances List.

This safety data sheet contains changes from the previous version in sections: 3,8,9,11,15
Page 5 of 5
Safety Data Sheet

Product name: LOCTITE 454 INSTANT ADHESIVE IDH number: 680522
GEL known as LOCTITE®
QUICKTITE® INSTANT AD
Product type/use: Adhesive Item number: 39202
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW
COMBUSTIBLE LIQUID.

FLAMMABLE LIQUID 4
EYE IRRITATION 2B
PICTOGRAM(S)
Prevention:
Keep away from heat, sparks, open flames, hot surfaces - no smoking. Avoid breathing vapors,
mist, or spray. Wash affected area thoroughly after handling. Use only outdoors or in a well-
ventilated area. Wear protective gloves, eye protection, and face protection.
Response:
breathing. Call a POISON CENTER or physician if you feel unwell. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention. In case of fire: Use foam, dry
chemical or carbon dioxide to extinguish.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Disposal:
IDH number: 680522 Product name: LOCTITE 454 INSTANT ADHESIVE GEL known as LOCTITE® QUICKTITE®
INSTANT AD
Page 1 of 5
67762-90-7 5 - 10
products with silica

Skin contact: Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart
by a large drop, seek medical attention. If lips are bonded, apply warm water
to the lips and encourage wetting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart with direct opposing force.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. Get medical
covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and will cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually within 1-3
damage.
Ingestion: Ensure breathing passages are not obstructed. The product will polymerize
rapidly and bond to the mouth making it almost impossible to swallow. Saliva
will separate any solidified product in several hours. Prevent the patient from
swallowing any separated mass.
has shown that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal bums they should be treated


Environmental precautions: Ventilate area. Do not allow product to enter sewer or waterways.
Clean-up methods: Do not use cloths for mopping up. Flood with water to complete polymerization
waste. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.
INSTANT AD
Page 2 of 5
Contact with these materials may cause rapid polymerization which can
Storage: Not available.


1 ppm STEL
0.2 ppm TWA
sensitization)
10 mg/m3 TWA 15 mg/m3 TWA Total
Siloxanes and Silicones, di-Me, reaction Inhalable dust. dust.
None None
products with silica 3 mg/m3 TWA 5 mg/m3 TWA
Respirable fraction. Respirable fraction.
Engineering controls: Use positive down-draft exhaust ventilation if general ventilation is insufficient
limit(s). Use NIOSH approved respirator if there is potential to exceed
exposure limit(s).
goggles or safety glasses with side shields. Full face protection should be
used if the potential for splashing or spraying of product exists.
PVC, nylon or cotton. Use nitrile gloves and aprons as necessary to prevent
contact. Do not use PVC, nylon or cotton.

Color: Colorless
Odor: Irritating
pH: Not available.
Vapor pressure: < 0.2 mm hg no method < 26.7 Pa no method < 700 mbar (50 °C (122°F)) no
method
Flash point: 80 - 93 °C (176°F - 199.4 °F)
Solubility in water: Polymerises in presence of water.
Viscosity: 18,000.00 - 40,000.00 mPa.s
Viscosity: 18,000.00 - 40,000.00 mPa.s
INSTANT AD
Page 3 of 5
Hazardous reactions: Rapid exothermic polymerization will occur in the presence of water, amines, alkalis and
alcohols.

products:
Incompatible materials: Water, amines, alkalis and alcohols.

results in respiratory irritation, which may lead to difficulty in breathing and tightness in the
chest.
Skin contact: May cause skin irritation. Bonds skin in seconds. Cyanoacrylates have been reported to cause
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop will burn the
is almost impossible to swallow.
None No Data
OSHA Carcinogen
No No No




Packing group: III
INSTANT AD
Page 4 of 5
Packing group: III
Exceptions: Primary packs containing less than 500ml are unregulated by this mode of
transport and may be shipped unrestricted.

Packing group: None


CERCLA/SARA Section 311/312: Reactive, Fire, Immediate Health, Delayed Health
California Proposition 65: This product contains a chemical known to the State of California to cause birth defects or
other reproductive harm.
CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other
components are listed on or are exempt from listing on the Domestic Substances List.
Components listed on the NDSL must be tracked by all Canadian Importers of Record as
required by Environment Canada. They may be imported into Canada in limited quantities.
Please contact Regulatory Affairs for additional details.

INSTANT AD
Page 5 of 5
Safety Data Sheet

Product name: LOCTITE® Quickstix™ 561™ PST® IDH number: 463973
Pipe Sealant with PTFE
Product type/use: Anaerobic Sealant Item number: 37127
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW
REPEATED EXPOSURE.

SKIN IRRITATION 2
EYE IRRITATION 2A
PICTOGRAM(S)
Prevention: Do not breathe dust or fumes. Wash affected area thoroughly after handling. Wear protective
attention if you feel unwell. If skin irritation occurs: Get medical attention. If eye irritation

Ethene, tetrafluoro-, homopolymer 9002-84-0 1-5
Silica, amorphous, fumed, crystal-free 112945-52-5 1-5
Ethylene glycol 107-21-1 1-5
Ethene, homopolymer 9002-88-4 1-5
IDH number: 463973 Product name: LOCTITE® Quickstix™ 561™ PST® Pipe Sealant with PTFE
Page 1 of 6
Titanium dioxide 13463-67-7 1-5
Cumene hydroperoxide 80-15-9 0.1 - 1

artificial respiration. Get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
attention.

attention.

Hazardous combustion products: Irritating organic vapours. Oxides of carbon. Toxic fluorine compounds.

universal binder, sawdust). Scrape up as much material as possible. Store in a

Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and

Page 2 of 6

10 mg/m3 TWA Total
dust.
Ethene, tetrafluoro-, homopolymer None None None
5 mg/m3 TWA
Respirable fraction.
20 MPPCF TWA
10 mg/m3 TWA 0.8 mg/m3 TWA
Inhalable dust. 50 MPPCF TWA
3 mg/m3 TWA Total dust.
Respirable fraction. 5 mg/m3 TWA
Silica, amorphous, fumed, crystal-free None None
3 mg/m3 TWA Respirable fraction.
Respirable particles. 15 mg/m3 TWA Total
10 mg/m3 TWA dust.
Inhalable particles. 15 MPPCF TWA
25 ppm TWA Vapor
fraction
50 ppm STEL Vapor
Ethylene glycol None None None
fraction
10 mg/m3 STEL
Aerosol, inhalable.
15 MPPCF TWA
15 mg/m3 TWA Total
dust.
10 mg/m3 TWA 50 MPPCF TWA
Inhalable particles. Total dust.
Ethene, homopolymer None None
3 mg/m3 TWA 5 mg/m3 TWA
Respirable particles. Respirable fraction.
5 mg/m3 PEL
15 mg/m3 PEL Total
dust.
15 mg/m3 PEL Total
dust.
0.2 mg/m3 TWA 15 MPPCF TWA
Respirable nanoscale Respirable fraction.
particles 15 mg/m3 TWA Total
Titanium dioxide None None
2.5 mg/m3 TWA dust.
Respirable finescale 50 MPPCF TWA
particles Total dust.
5 mg/m3 TWA
1 ppm (6 mg/m3)
(SKIN)
exposure limits.
limit(s).
Page 3 of 6
Physical state: Wax
Color: White
Odor: Mild
pH: Not applicable, Product is non-polar/aprotic.
Vapor pressure: < 10 mm hg (27 °C (80.6 °F)) < 13 mbar (25 °C (77°F)) < 0.13 mbar (20 °C
(68°F))
Boiling point/range: > 149 °C (> 300.2 °F)> 150 °C (> 302°F)
Melting point/ range: > 80 °C (> 176°F)
Specific gravity: 1.1394
Vapor density: Not applicable, Product is a solid.
Flash point: Not applicable

Hazardous decomposition Oxides of carbon. Toxic fluorine compounds. Irritating organic vapours.
products:
Incompatible materials: Strong oxidizing agents.

Page 4 of 6
Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Ingestion: May cause gastrointestinal tract irritation if swallowed.
Ethene, tetrafluoro-, homopolymer None No Target Organs
Silica, amorphous, fumed, crystal-free None Nuisance dust
Oral LD50 (Rat) = 5.89 g/kg Blood, Bone Marrow, Central nervous
Ethylene glycol Oral LD50 (Mouse) = 14.6 g/kg system, Developmental, Eyes, Irritant,
Dermal LD50 (Rabbit) = 9,530 mg/kg Kidney, Liver, Metabolic
Ethene, homopolymer None No Target Organs
Inhalation LC50 (Rat, 4 h) = > 6.82 mg/l
Irritant, Respiratory, Some evidence of
Titanium dioxide Inhalation LC50 (Rat, 4 h) = > 2.28 mg/l
carcinogenicity
Inhalation LC50 (Rat, 4 h) = > 3.56 mg/l
Irritant, Mutagen
OSHA Carcinogen
Ethene, tetrafluoro-, homopolymer No No No
Silica, amorphous, fumed, crystal-free No No No
Ethylene glycol No No No
Ethene, homopolymer No No No
Titanium dioxide No Group 2B No
Saccharin No No No



The transport information provided in this section only applies to the material/formulation itself, and is not specific to any packaging.

Proper shipping name: RQ, Environmentally hazardous substance, solid, n.o.s.
Packing group: III

Packing group: III

Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Packing group: III
Page 5 of 6
TSCA 12 (b) Export Notification: None above reporting de minimisNone above reporting de minimis
CERCLA/SARA Section 302 EHS:

CFR 372). Ethylene glycol (CAS# 107-21-1). Saccharin (CAS# 81-07-2).
reproductive harm.
Substances List.

This safety data sheet contains changes from the previous version in sections: 2,3,8,9,11,15
Page 6 of 6
Safety Data Sheet

Product name: Loctite(R) 220 Threadlocker IDH num ber: 483618
Product type/use: Anaerobic Sealant Item number: 37388
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW
REPEATED EXPOSURE.

SKIN IRRITATION 2
EYE IRRITATION 2A
PICTOGRAM(S)
Prevention: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated w ork clothing should not be allow ed out of the w orkplace. Wear protective
Response: IF ON SKIN: Wash w ith plenty of water. IF IN EYES: Rinse cautiously w ith water for several
attention if you feel unw ell. If skin irritation or rash occurs: Get medical attention. If eye irritation
Disposal: Dispose of contents and/or container according to Federal, State/Prov incial and local
Classification complies w ith OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of t he

IDH number: 483618 Product name: Loctite(R) 220 Threadlocker
Page 1 of 6
Cumene 98-82-8 0.1 - 1
Methyl methacrylate 80-62-6 0.1 - 1

difficult, give oxygen. Get medical attention.
Skin contact: Immediately flush skin w ith plenty of w ater (using soap, if available). Remove
attention.
Eye contact: Rinse immediately w ith plenty of w ater, also under the eyelids, for at least 15

attention.

turn-out gear. In case of fire, keep containers cool w ith w ater spray.
Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.

Environm ental precautions: Do not allow product to enter sew er or waterways.
prevent entry into w ater system; w ear full protective equipment during clean-
up. Soak up w ith inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, saw dust). Scrape up as much material as possible. Store in a

Handling: Use only w ith adequate ventilation. Prevent contact w ith eyes, skin and

Keep in a cool, w ell ventilated area aw ay from heat, sparks and open flame.

Page 2 of 6
Em ployers should complete an assessment of all w orkplaces to determine the need for, and selection of, proper

1 ppm (6 mg/m3)
(SKIN)
50 ppm (245 mg/m3)
Cumene 5 ppm TWA PEL None None
(SKIN)
50 ppm TWA
100 ppm (410
Methyl methacrylate 100 ppm STEL None 50 ppm
mg/m3) PEL
Engineering controls: Provide adequate local exhaust ventilation to maintain w orker exposure below
exposure limits.
limit(s).
show ers and eye wash stations should be available.

Color: Blue
Odor: Mild
pH: Not applicable
Vapor pressure: < 5 mm hg (27 °C (80.6 °F))
Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup
Flam m able/Explosive limits - low er: Not available.
Flam m able/Explosive limits - upper: Not available.
Solubility in w ater: Slight

Page 3 of 6
Hazardous decomposition Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.
products:
Incom patible materials: Strong oxidizing agents.
Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store aw ay from

Ingestion: May cause gastrointestinal tract irritation if sw allowed.
Irritant, Mutagen
Oral LD50 (Rat) = 2.91 g/kg
Cumene Central nervous system, Irritant, Lung
Allergen, Irritant, Kidney, Liver, Mutagen,
Methyl methacrylate Oral LD50 (Rabbit) = 6,000 mg/kg
Nervous System, Respiratory
OSHA Carcinogen
Saccharin No No No
Reasonably Anticipated to be
Cumene Group 2B No
a Human Carcinogen.
Methyl methacrylate No No No


Page 4 of 6


Packing group: III

Packing group: III

Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Packing group: III


CERCLA/SARA Section 313: This product contains the follow ing toxic chemicals subject to the reporting requirements of
CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2). Cumene
(CAS# 98-82-8).
California Proposition 65: This product contains a chemical know n in the State of California to cause cancer. This
product contains a chemical know n to the State of California to cause birth defects or other
reproductive harm.
Substances List.

This safety data sheet contains changes from the previous version in sections: 3, 8, 11, 13, 15

Page 5 of 6
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property a nd

Page 6 of 6
Safety Data Sheet

Product name: LOCTITE® QUICKTAPE™ 249™ IDH number: 1395405
THREADLOCKER TAPE
Product type: Anaerobic thread sealant Item number: 1395405
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW
REPEATED EXPOSURE.

SKIN IRRITATION 2
EYE IRRITATION 2A
CARCINOGENICITY 2
PICTOGRAM(S)
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Do not breathe vapors, mist, or spray. Wash affected area thoroughly
after handling. Contaminated work clothing should not be allowed out of the workplace. Wear
protective gloves, clothing, eye and face protection.
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or
concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention. If eye
irritation persists: Get medical attention. Take off contaminated clothing.
Storage: Store locked up.
IDH number: 1395405 Product name: LOCTITE® QUICKTAPE™ 249™ THREADLOCKER TAPE
Page 1 of 6

Silica, amorphous, fumed, crystal-free 112945-52-5 5 - 10
Ethene, tetrafluoro-, homopolymer 9002-84-0 1-5
Cumene 98-82-8 0.1 - 1
1-Acetyl-2-phenylhydrazine 114-83-0 0.1 - 1
Methyl ethyl ketone 78-93-3 0.1 - 1

Skin contact: Remove contaminated clothing and footwear. Immediately flush skin with
plenty of water (using soap, if available). Wash clothing before reuse. Get
medical attention.

attention.

turn-out gear.
Unusual fire or explosion hazards: In case of fire, keep containers cool with water spray.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Hydrogen cyanide. Hydrocarbons.
Irritating organic vapours.

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.
Page 2 of 6
up. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean
universal binder, sawdust). Store in a partly filled, closed container until
disposal.

Wash thoroughly after handling. Refer to Section 8. Use only with adequate
ventilation. Keep container closed.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

10 mg/m3 TWA
Inhalable dust. 20 MPPCF TWA
Silica, amorphous, fumed, crystal-free None None
3 mg/m3 TWA 0.8 mg/m3 TWA
1 ppm (6 mg/m3)
(SKIN)
10 mg/m3 TWA Total
dust.
Ethene, tetrafluoro-, homopolymer None None None
5 mg/m3 TWA
50 ppm (245 mg/m3)
(SKIN)
1-Acetyl-2-phenylhydrazine None None None None
200 ppm TWA 200 ppm (590
Methyl ethyl ketone None None
300 ppm STEL mg/m3) PEL
exposure limits.
limit(s).
Eye/face protection: Safety goggles or safety glasses with side shields. Safety showers and eye
wash stations should be available.
apron or body suit to prevent skin contact. Neoprene, Butyl-rubber, or nitrile-
rubber gloves.

Physical state: Solid, Film
Color: Blue
Odor: Mild
Page 3 of 6
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: Not available.
Flash point: Product is a solid.
Solubility in water: Not available.
VOC content: 5 g/l (calculated)

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Hydrocarbons. Irritating organic vapours.
products:
Incompatible materials: Strong oxidizing agents. Reducing agents. Aldehydes. Amines. Alkalis. Peroxides. Free radical
initiators.
Conditions to avoid: Heat, flames, sparks and other sources of ignition. Store away from incompatible materials.

Page 4 of 6
Ingestion: May cause gastrointestinal disturbances.
Silica, amorphous, fumed, crystal-free None Nuisance dust
Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l
Irritant, Mutagen
Ethene, tetrafluoro-, homopolymer None No Target Organs
Cumene Oral LD50 (Rat) = 1,400 mg/kg Central nervous system, Irritant, Lung
Inhalation LC50 (Rat, 4 h) = 8000 ppm
Allergen, Blood, Kidney, Mutagen, Some
1-Acetyl-2-phenylhydrazine Oral LD50 (Mouse) = 270 mg/kg
evidence of carcinogenicity
Oral LD50 (Mouse) = 670 mg/kg
Oral LD50 (Rat) = 2,300 - 3,500 mg/kg
Methyl ethyl ketone Oral LD50 (Rat) = 4,500 - 6,800 mg/kg Irritant, Central nervous system
Dermal LD50 (Rabbit) = > 8,000 mg/kg
Inhalation LC50 (Rat, 4 h) = 11700 ppm
OSHA Carcinogen
Silica, amorphous, fumed, crystal-free No No No
Ethene, tetrafluoro-, homopolymer No No No
Saccharin No No No
Cumene Group 2B No
a Human Carcinogen.
1-Acetyl-2-phenylhydrazine No No No
Methyl ethyl ketone No No No

Ecological information: Harmful to aquatic organisms. May cause long-term adverse effects in the
aquatic environment. Do not empty into drains / surface water / ground water.

Hazardous waste number: This product contains a component or components identified as hazardous
under 40 CFR 261.24. D035: Methyl Ethyl Ketone.


Packing group: III
Page 5 of 6
Packing group: III

Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Packing group: III

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: Ethene, tetrafluoro-, homopolymer (CAS# 9002-84-0).

CFR 372). Cumene hydroperoxide (CAS# 80-15-9). Saccharin (CAS# 81-07-2).
reproductive harm.
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.

Page 6 of 6
Safety Data Sheet

Product name: LOCTITE® 243™ THREADLOCKER IDH number: 1329837
Product type/use: Threadlocker Item number: 1329837
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW

SKIN IRRITATION 2
EYE IRRITATION 2A
CARCINOGENICITY 2
PICTOGRAM(S)
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Avoid breathing vapors, mist, or spray. Wash affected area thoroughly
after handling. Contaminated work clothing should not be allowed out of the workplace. Wear
protective gloves, clothing, eye and face protection.
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or
concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention. If eye
irritation persists: Get medical attention. Take off contaminated clothing.
Storage: Store locked up.
IDH number: 1329837 Product name: LOCTITE® 243™ THREADLOCKER

Page 1 of 6
Tetramethylene dimethacrylate 2082-81-7 10 - 30
Amorphous fumed silica 68611-44-9 1-5
Ethene, homopolymer 9002-88-4 1-5
Propane-1,2-diol 57-55-6 1-5
Cumene hydroperoxide 80-15-9 0.1 - 1
1-Acetyl-2-phenylhydrazine 114-83-0 0.1 - 1
Cumene 98-82-8 0.1 - 1

Skin contact: Remove contaminated clothing and footwear. Immediately flush skin with
plenty of water (using soap, if available). Wash clothing before reuse. Get
medical attention.

attention.

Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
fragments.

personnel.
up. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean
universal binder, sawdust). Store in a partly filled, closed container until
disposal.

Page 2 of 6
Wash thoroughly after handling. Keep container closed. Use only with
adequate ventilation. Refer to Section 8.


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure

Tetramethylene dimethacrylate None None None None
0.8 mg/m3 TWA
Amorphous fumed silica None None None
20 MPPCF TWA
15 MPPCF TWA
15 mg/m3 TWA Total
dust.
10 mg/m3 TWA 50 MPPCF TWA
Inhalable particles. Total dust.
Ethene, homopolymer None None
3 mg/m3 TWA 5 mg/m3 TWA
Respirable particles. Respirable fraction.
5 mg/m3 PEL
15 mg/m3 PEL Total
dust.
10 mg/m3 TWA
Propane-1,2-diol None None None
Aerosol.
1 ppm (6 mg/m3)
(SKIN)
1-Acetyl-2-phenylhydrazine None None None None
50 ppm (245 mg/m3)
(SKIN)
exposure limits.
limit(s).
apron or body suit to prevent skin contact. Butyl rubber gloves. Neoprene
gloves. Natural rubber gloves.

Color: Blue
Odor: Characteristic
pH: Not available.
Vapor pressure: < 0.1 mm hg (27 °C (80.6 °F))

Page 3 of 6
Flash point: > 93 °C (> 199.4 °F)

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Irritating organic fragments.
products:
Incompatible materials: Strong oxidizing agents. Reducing agents. Strong alkalis. Oxygen scavengers. Other
polymerization initiators. Heavy metals.


Page 4 of 6
Ingestion: May cause gastrointestinal tract irritation if swallowed.
Tetramethylene dimethacrylate None Irritant, Allergen
Amorphous fumed silica None No Target Organs
Ethene, homopolymer None No Target Organs
Oral LD50 (Rabbit) = 18 g/kg
Propane-1,2-diol Oral LD50 (Mouse) = 23.9 g/kg Irritant
Oral LD50 (Rat) = 30 g/kg
Irritant, Mutagen
Allergen, Blood, Kidney, Mutagen, Some
1-Acetyl-2-phenylhydrazine Oral LD50 (Mouse) = 270 mg/kg
evidence of carcinogenicity
Cumene Central nervous system, Irritant, Lung
OSHA Carcinogen
Tetramethylene dimethacrylate No No No
Amorphous fumed silica No No No
Ethene, homopolymer No No No
Propane-1,2-diol No No No
1-Acetyl-2-phenylhydrazine No No No
Cumene Group 2B No
a Human Carcinogen.


Hazardous waste number: Not a RCRA hazardous waste.


Packing group: III

Page 5 of 6
Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. (Fatty acid amide)
Packing group: III

Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fatty
acid amide)
Packing group: III
Marine pollutant: Fatty acid amide

Inventory.

Hydroquinone (CAS# 123-31-9).
CFR 372). Cumene (CAS# 98-82-8).
reproductive harm.
Substances List.


Page 6 of 6
Safety Data Sheet

Product name: LOCTITE LB 8065 COPPER ANTI- IDH num ber: 466863
SEIZE STICK known as C5-A® Copper
Anti-Seize Stick
Product type/use: Lubricant Item number: 37229
1-800-424-9300 (toll free) or 1-703-527-3887
EMERGENCY OVERVIEW

SKIN IRRITATION 2
EYE IRRITATION 2A
PICTOGRAM(S)
Prevention: Wash affected area thoroughly after handling. Wear protective gloves, eye protection, and face
protection.
Response: IF ON SKIN: Wash w ith plenty of water. IF IN EYES: Rinse cautiously w ith water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation
occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off
contaminated clothing.
Disposal: Not prescribed
Classification complies w ith OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the

Copper 7440-50-8 10 - 30
Graphite 7782-42-5 10 - 30
IDH number: 466863 Product name: LOCTITE LB 8065 COPPER ANTI-SEIZE STICK know n as C5-A® Copper Anti-Seize
Stick
Page 1 of 6
Distillates (petroleum), hydrotreated
64742-52-5 10 - 30
heavy naphthenic
Petroleum distillates, hydrotreated, light
64742-53-6 10 - 30
naphthenic
Quartz (SiO2) 14808-60-7 0.1 - 1

difficult, give oxygen. If symptoms develop and persist, get medical attention.
Skin contact: Wash w ith soap and w ater. If symptoms develop and persist, get medical
attention.
Eye contact: Immediately flush eyes w ith plenty of water for at least 15 minutes. Get
medical attention.
Ingestion: Do not induce vomiting. Aspiration may cause pulmonary edema and
pneumonitis. Get medical attention.

Special firefighting procedures: None
Hazardous combustion products: Oxides of carbon.

personnel.
Environm ental precautions: Do not allow product to enter sew er or waterways.
Clean-up methods: Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.
For large spills absorb onto inert absorbent material and place in sealed
container for disposal. For small spills w ipe up w ith paper towel and place in
container for disposal. Scrape up as much material as possible. Clean
residue w ith soap and w ater.

Handling: Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
Keep container closed.
Storage: Keep in a cool, w ell ventilated area.
Stick
Page 2 of 6
Em ployers should complete an assessment of all w orkplaces to determine the need for, and selection of, proper exposure

0.2 mg/m3 TWA (as 1 mg/m3 PEL (as Cu)
Cu) Fume. Dust and mist.
Copper None None
1 mg/m3 TWA (as 0.1 mg/m3 PEL (as
Cu) Dust and mist. Cu) Fume.
5 mg/m3 PEL
2 mg/m3 TWA Respirable fraction.
Graphite None None
Respirable fraction. 15 mg/m3 PEL Total
dust.
500 ppm (2,000
Distillates (petroleum), hydrotreated 5 mg/m3 TWA
mg/m3) PEL None None
heavy naphthenic Inhalable fraction.
5 mg/m3 PEL Mist.
500 ppm (2,000
Petroleum distillates, hydrotreated, light 5 mg/m3 TWA
mg/m3) PEL None None
naphthenic Inhalable fraction.
5 mg/m3 PEL Mist.
0.05 mg/m3 TWA
(Respirable dust.)
(Respirable dust.)
0.025 mg/m3
OSHA_ACT
0.025 mg/m3 TWA (Respirable dust.)
Quartz (SiO2) None None
Respirable fraction. 0.05 mg/m3 PEL
Respirable dust.
2.4 MPPCF TWA
Respirable.
0.1 mg/m3 TWA
Respirable.
Engineering controls: Use only w ith adequate ventilation. Local exhaust ventilation is recommended
w hen general ventilation is not sufficient to control airborne contamination
below occupational exposure limits.
limit(s). Observe OSHA regulations for respirator use (29 CFR 1910.134).
be used if the potential for splashing or spraying of product exists.
Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin
contact.

Physical state: Solid
Color: Copper
Odor: Mild, Petroleum
pH: Not applicable
Vapor pressure: Not determined
Boiling point/range: Not available.
Vapor density: Not determined
Flash point: Product is a solid. Burn Rate: Approx 14 mm/2 minutes
Flam m able/Explosive limits - low er: Not determined
Flam m able/Explosive limits - upper: Not determined
Autoignition temperature: Not determined
Evaporation rate: Not determined
Solubility in w ater: Insoluble
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Partition coefficient (n-octanol/water): Not determined
VOC content: 0%

Stability: Stable at normal conditions.
Hazardous reactions: Will not occur.
Hazardous decomposition Oxides of carbon.

products:
Incom patible materials: Oxidizing agents.
Conditions to avoid: None know n

Inhalation: Inhalation of copper fumes may result in metal fume fever. Symptoms include metallic taste,
discoloration of skin or hair. This product has low volatility and is not expected to cause
respiratory tract irritation during normal conditions of use. May cause respiratory tract irritation.
Abrasion of cured material such as by sanding or grinding could release respirable partic les of
silica quartz, a cancer hazard by inhalation. Normal use of this product causes no such release.
Skin contact: Causes skin irritation.
Ingestion: May cause gastrointestinal tract irritation if sw allowed. Principal hazard of ingestion is
aspiration into the lungs and subsequent pneumonitis.
Allergen, Blood, Central nervous system,
Developmental, Gastrointestinal, Immune
Copper None
system, Irritant, Kidney, Liver, Mutagen,
Sensory, Skin
Inhalation LC50 (Rat, 4 h) = > 2,000 mg/m3
Graphite Lung
Inhalation LC50 (Rat, 4 h) = > 2,000 mg/m3
None Irritant
heavy naphthenic
None Irritant
naphthenic
Immune system, Lung, Some evidence of
Quartz (SiO2) None
carcinogenicity
OSHA Carcinogen
Copper No No No
Graphite No No No
No No No
heavy naphthenic
No No No
naphthenic
Know n To Be Human
Quartz (SiO2) Group 1 Yes
Carcinogen.
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Page 4 of 6

Hazardous waste number: Not a RCRA hazardous waste.


Packing group: None

Packing group: None

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper)
Packing group: III
Marine pollutant: Copper

Inventory.

CERCLA/SARA Section 311/312: Immediate Health
CERCLA/SARA Section 313: This product contains the follow ing toxic chemicals subject to the reporting requirements of
CFR 372). Copper (CAS# 7440-50-8).
CERCLA Reportable quantity: Copper (CAS# 7440-50-8) 5,000 lbs. (2,270 kg)
California Proposition 65: This product contains a chemical know n in the State of California to cause cancer.
Substances List.

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Safety Data Sheet

Revision Number: 004.0 Issue date: 10/24/2022

1. PRODUCT AND COMPANY IDENTIFICATION

HAZARD CLASS HAZARD CATEGORY

See Section 11 for additional toxicological information.

4. FIRST AID MEASURES

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Unusual fire or explosion hazards: None

6. ACCIDENTAL RELEASE MEASURES

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

9. PHYSICAL AND CHEMICAL PROPERTIES

Hazardous decomposition None

Incompatible materials: Water, amines, alkalis and alcohols.

Reactivity: Not available.

Conditions to avoid: Spontaneous polymerization.

11. TOXICOLOGICAL INFORMATION

Potential Health Effects/Symptoms

12. ECOLOGICAL INFORMATION

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

U.S. Department of Transportation Ground (49 CFR)

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated

15. REGULATORY INFORMATION

CERCLA/SARA Section 302 EHS: Hydroquinone (CAS# 123-31-9).

Canada Regulatory Information

16. OTHER INFORMATION

Prepared by: Product Safety and Regulatory Affairs

Issue date: 10/24/2022

Revision Number: 005.1 Issue date: 08/25/2021

1. PRODUCT AND COMPANY IDENTIFICATION

HAZARD CLASS HAZARD CATEGORY

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS

4. FIRST AID MEASURES

Sym ptoms: See Section 11.

5. FIRE FIGHTING MEASURES

Unusual fire or explosion hazards: None

6. ACCIDENTAL RELEASE MEASURES

IDH number: 233998 Product name: LOCTITE 454 PRISM SURF

Storage: Not available.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER

9. PHYSICAL AND CHEMICAL PROPERTIES

IDH number: 233998 Product name: LOCTITE 454 PRISM SURF

Hazardous decomposition None

Incom patible materials: Water, amines, alkalis and alcohols.

Reactivity: Not available.

Conditions to avoid: Spontaneous polymerization.

11. TOXICOLOGICAL INFORMATION

Potential Health Effects/Symptoms

12. ECOLOGICAL INFORMATION

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

U.S. Department of Transportation Ground (49 CFR)

IDH number: 233998 Product name: LOCTITE 454 PRISM SURF

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated

15. REGULATORY INFORMATION

TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.