ANSWER KEY PAPER-1

PART-1 : PHYSICS
Q. 1 2 3 4
SECTION-I (i)
A. C C B B
Q. 5 6 7 8 9 10 11 12
SECTION-I (ii)
A. A,B,D A,C A,B,C,D A,C A,B,C A,C A,B,D B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 4.00 20.00 2.80 2.50 0.14 to 0.16 1.00

PART-2 : CHEMISTRY
Q. 1 2 3 4
SECTION-I (i)
A. C D C D
Q. 5 6 7 8 9 10 11 12
SECTION-I (ii)
A. A,B,C B,C A,C,D A,B,C,D A,B A,B,C,D A,B,C,D A,B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 4.04 1.00 7.00 2.00 10.00 7.00

PART-3 : MATHEMATICS
Q. 1 2 3 4
SECTION-I (i)
A. A B C C
Q. 5 6 7 8 9 10 11 12
SECTION-I (ii)
A. A,B,C,D A,C,D A,C,D A,C A,D B A,B,D B,C
Q. 1 2 3 4 5 6
SECTION-II
A. 7.00 11.00 11.00 4.00 10.00 1.00

HINT – SHEET
PART-1 : PHYSICS 3. Ans ( B )
SECTION-I (i) For 0 ⩽ t ⩽ 1 , body will perform SHM with
2
1. Ans ( C ) time period 2 sec starting from –ve amplitude.
If resistance of rheostat is increased current will ∴ At t = 1 sec, body passes through x = 0 with
2
decrease. Now since current decreases, so will speed 2π m/sec.
the potential difference across each branch and π
∴ At x = , we have
hence voltmeter reading will increase. 2
2 2 π
v = 4π + 2 × 5π × (v2 = u2 + 2as)
2. Ans ( C ) 2
⇒ v = 3π m/sec
fxnet = mg cos 30∘
∴ ax = g cos 30° 4. Ans ( B )
1 1
ϕ = − R2 θ B1 + B2 3R2 θ
2 2
dϕ R2 θ dB1 3R2 θ dB2
∴ =ε= −
dt 2 dt 2 dt
R2 θ 3R2
= .2K0 − θ4K0
2 2
∴ emf = 5T2θK
 PART-1 : PHYSICS For cylinder
SECTION-I (ii) TR – fR = Iα
5. Ans ( A,B,D ) T – µN = Ia/R2
T – 0.2 × 200 = Ma/2 = 2a
T – 40 = 2a --------(C)
From (B) & (C)
Tension in the spring = kR 160 = 6a
Horizontal Force on the plank a = 80/3 m/s2
= – kR sin θ T = 40 + 160/3 = 280/3 N
x kx
= −kR × =− 7. Ans ( A,B,C,D )
2R 2
kx/2
a=− Velocity of sound in 2nd tube is twice of the 1st
M + 2 × (M + ICM /R2 ) × 1/4
kx/2 tube thus the wave length. Possible configuration
a=−
M + 2 × (M + M/2) × 1/4
2kx
may be:
a=− = −ω 2 x
7M
7M
T = 2π √ = 0.2s
2k
6. Ans ( A,C )

8. Ans ( A,C )
n λD
y=
d
dy nλ dD nλD dD y
vf = = = = vmean
dt d dt dD dt D
For L shaped massless body 5
= × (100 × 1) = 10 cm/s
F–N=0 ⇒ N = 200N ------ (A) 50

For the system

200 – T = 4a ------- (B)
9. Ans ( A,B,C ) PART-1 : PHYSICS
Initially : SECTION-II
P1 AL1 = nRT1 1. Ans ( 4.00 )
nRT1
P1 A = ωb = ΔVE + ΔUsurface
L1
2
θ nRT1 εr ε0 AV 2
1 εr ε0 AV 2
= = + σ ⋅ 2A
2A∈0 L1 d 2 d
Finally : 4 σd
V =√
P2 AL2 = nRT2 ε0 εr

nRT2 2. Ans ( 20.00 )

P2 A =
L2
2 2
β Q nRT2
=
2A∈0 L2
By energy conservation :
1 f
∈0 E 2 AL1 + nRT1
2 2
1 f
= ∈0 E AL2 + nRT2
2

2 2
2
10. Ans ( A,C )
H 2
Overlapping both phaser diagrams
y = ax2 ; y=
x
R2
1 dv
mg − ρL πx2 yg = m
2 dt
dv dv ρL x2 yg
V ⋅ = =g− ×
dy dt ρ s R2 H
ρL
∫ V dv = ∫ ( g− gy 2 ) dy
ρs

11. Ans ( A,B,D )

Let charge at (–1) be q1 & at (+1) be q2.
Kq1 Kq2 Kq1 Kq2 In trapezium ABCO
∴ + = + [V = 2.7 volt]
0.5 1.5 1 1
2 2α + θ = 2β + θ
⇒ 2q1 + q2 = q1 + q2
3 α =β
q2 q1 1
⇒ q1 = ⇒ =
3 q2 3 In rectangle OACD
Both the charges are positive.
2α + β = 90°
12. Ans ( B,C ) 3α = 90°
We have,
α = 30°
hc
eV = −ϕ
λ Thus hexagon OABCDE is regular and
1 eV ϕ
⇒ = + [y = mx + c] V0 =10 × 2 = 20 V
λ hc hc
3. Ans ( 2.80 ) ∴ m2 (ℓ 0 −
L0
) = m2 (ℓ 1 −
Lt
) or ℓt − ℓ0 = 1
(Lt − L0 )
2 2 2
The maximum possible acceleration of the top
or l0 αi t = 1 L0 (γm − 2αg )t
block without slipping is mbamax = µmtg. If the top 2
block is not slipping then the angular frequency is where suffix i is for iron, m for mercury and g for
given by glass.
αi
∴ L0 = 2I0
k γm − 2 α g
ω2 = √ ,
mt + mb 2 × 1 × 12 × 10−6
⇒ L0 = = 0.146 m ≃ 0.15m
so amax ⩾ Aω 2

2
182 × 10−6 − 2 × 9 × 10−6

or Ac = μg mt (1 + mt ) 6. Ans ( 1.00 )
k mb
2 2
= 0.5 × 10 × (1 + )
500 5
7
= m
250
= 2.8 cm
4. Ans ( 2.50 ) PART-2 : CHEMISTRY
Work performed in one cycle = area under the SECTION-I (i)
curve 1. Ans ( C )
From the given information,
P 0 V0 Rλ300
W= =
4 4
100R
∴ Heat rejected/cycle = = 25R 2. Ans ( D )
4
25R XF4 type molecule have zero dipole moment
∴ ΔT /Cycle = = 2.5
1 × 10R when it is either tetrahedral or square planar.
5. Ans ( 0.14 to 0.16 )
4. Ans ( D )
Let m1 = mass of the iron rod, m2 = mass of mercury,
(A) Victor Mayer's Test is given by Halide and
l0 = length of the iron rod at 0°C, L0 = height of Alcohol both
mercury at 0°C, A0 area of cross-section of the glass (B) Beilstein test is given by Halogen containing
tube at 0°C. The distance of the centre of mass from compound
the point of suspension at 0°C is given by (C) Manomer of polyethene is ethene
(D) It is a test to distinguish fructose and glucose
m1 ℓ20 + m2 (ℓ0 −
L0
)
2
xcm at 0∘ C = PART-2 : CHEMISTRY
m1 + m2
m1 x 1 + m2 x 2 SECTION-I (ii)
( ∵ xcm = )
m1 + m2
Lt Lt 5. Ans ( A,B,C )
m1 2
+ m2 ( ℓ t − 2
)

Similarly xcm at t∘ C = Since cis form is polar

m1 + m2 ∴ more soluble in polar solvent while trans form
In order that the centre of mass of the pendulum may is more soluble in non polar solvent
not rise or fall. 6. Ans ( B,C )
xcm at 0∘ C = xcm at t∘ C It is neutral.
or m1
ℓ 0 + m (ℓ − L 0 ) = m ℓ t + m (ℓ − L t ) NO gas is not isoelectronic with superoxide
2 0 1 2 t
2 2 2 2
When the rod is light m1 = 0 Exhibit resonance.
7. Ans ( A,C,D ) 9. Ans ( A,B )
It look as if process is reversible as it is carried AgBr(s) ⇌ Ag ⊕ + Brs−
x
out in small steps. ⊕
Ag ⊕ + 2NH3 ⇌ [Ag(NH3 )2 ]
But Pex = 0, So w = 0. x 0.2−2s s

The wall is diathermic, so process is isothermal. x×s=2× 10–10

Hence, T1 = T2. s
x×s = 16 × 10−4
2
x(0.2 − 2s)
So, ΔU = 0 s
= 4 × 10−2
So, U2 = U1 0.2 − 2s
As gas has expanded without change in ⇒ s = 8×10–3 – 8×10–2s
temperature, so pressure has decreased.
⇒ s = 8 × 10–3
So, q = 0
10−7
x=
8. Ans ( A,B,C,D ) 4
K×1
Let PA* and PB* be the vapor pressures of pure Now, λ1 =
1000 × x
liquids and let nA and nB be the moles of A and KAg + = λ × 1000 × x
B in starting liquid. 10−7
=6×
Hence 4
nA nB = 1.5 × 10–7 sm–1
900 = PA ∘ × + PB ∘ × . . . (1)
nA + nB nA + nB
1 = 64 × 10–3 sm–1
Total moles of residue = (nA + nB );
3
1 1 10. Ans ( A,B,C,D )
nA (residue) = 0.3 × (nA + nB ) = (nA + nB )
3 10
(A) −CF3 − C Θ Cl2 → CF2 = CCl2
Total moles in condensate = 2 (nA + nB )
3
2 2
⇒ nA (condensate) = 0.6 ×
3
(nA + nB ) = (nA + nB )
5
(B) → P hC Θ H − CH2 − F → C6 H5 CH = CH2
1 2
⇒ nA (total) = (nA + nB ) + (nA + nB )
10 5 (C) PhSO2–CH=CH2
nA 1
⇒ =
nA + nB 2
⇒ Initial xA = 0.5; xB = 0.5 (D)
PAo PBo
⇒ 900 = + . . . . (2)
2 2
PT over residue = 860
⇒ 860 = PAo × 0.3 + PBo × 0.7 . . . (3)

Solving (2) and (3) gives

PBo = 800 torr

PAo = 1000 torr

PT over condensate = 1000 × 0.5 + 800 × 0.4

= 600 + 320 = 920 torr
 PART-2 : CHEMISTRY 5. Ans ( 10.00 )
SECTION-II (a)
1. Ans ( 4.04 ) 2 products
−4
2.6 × 10
ΛNa2 SO4 = × 1000 = 260
10−3 (b)
ΛSO −2 = 260 − 2(50) = 160
4

CaSO 4 (s) ⇌ Ca 2+ + SO 2−

x 10 – 3 +x
7 × 10 – 4 = 10 – 3 [2 × 10 – 3 × 50 + x × 120 + 4 products
(10 – 3 + x) × 160] (c)
11
∴ x= × 10 – 3
7
lHence, K sp of CaSO 4 = x × (10 – 3 + x)
= 4.04 × 10 – 6 M 2
2 products
2. Ans ( 1.00 )
Atoms on one face of unit cell = 2.
(d)
Total number of atoms one face of crystal
1
=2× × 6 × 1030 = 2 × 1030 2 products
6
1 6. Ans ( 7.00 )
∴ Unit cells at one face N = × 1015; 1030 = N2
√ 2 A, B, C, D, F, G, I
∴ √ 2a = 4(50)
PART-3 : MATHEMATICS
200
a= nm SECTION-I (i)
√ 2
Edge length of crystal 1. Ans ( A )
Let an be total ways of division when there are n
200 1 balls of each colour.
= ( × 10−9 m) × × 1015 = 108 m
√ 2 √ 2 Case I If we make one group B1W1R1 remaining
balls division can be done in an–1 ways.
∴ Area = a = 10 m 2 16 2
Case II If we make one group B1W1R2
remaining balls division can be done in an–2 ways.
4. Ans ( 2.00 ) Case III If we make one group B1W2R1
I − + IO + H + → I2 −

3
remaining balls division can be done in an–2 ways.
(A) (B) Case IV If we make one group B1W2R2
Na2 SO3 + S → Na2 S2 O3 remaining balls division can be done in an–2 ways.
(C) ∴ an = an−1 + 3an−2
I2 + Na2 S2 O3 → NaI + Na2 S4 O6
Now a1 = 1, a2 = 4
(B) (A) (D) ∴ a3 = 4 + 3 = 7
a4 = 7 + 12 = 19
a5 = 19 + 21 = 40
a6 = 40 + 57 = 97
2. Ans ( B ) 4. Ans ( C )
Let f(x) = ax + b
f(0) = – 5 ⇒ b = –5
f(f(0)) = – 15 ⇒ a = 2
∴ f(x) = 2x – 5
r1 + r2
FG = Now f(x) • f(m – x) ≥ 0
2
5 5
2 2 ∴ (x − ) (x − (m − )) ⩽ 0
GB = √(F G) + (F B) 2 2
2 2 5 5
(r1 + r2 ) d 2 − (r1 − r2 ) Case I > m − , here length of interval
(GB)2 = + 2 2
4 4 5 5
2
= −m+ =2 ⇒m=3
d + 4r1 r2 2 2
= 5 5
4 Case II < m − , here length of interval
2 2
(C1 C2 )2 + 4r1 r1 5 5
R =
2
= 40 =m− − =2
1
4 2 2
(C1 C2 )2 − 4r1 r1 ⇒m=7
R =
2
= 10
2
4 ∴ two values of m
3. Ans ( C )
PART-3 : MATHEMATICS
Given equation simplifies to
(4sin2x – 2sin2z)2 + 4(2sinx • sinz – siny)2 + SECTION-I (ii)

2(sin2y – 1)2 = 0 5. Ans ( A,B,C,D )

∴ sin2y = 1, 2 sinx • sinz = sin y, 2 sin2x = sin2z 2A + 3BBT = I, B−1 = AT . . . . . . (i)
No. of (2A + 3BBT )T = I
Cases
triplets. 2AT + 3BBT = I . . . . (ii)
T
sin y = 1, ∴ A=A also AT = B−1
sin ∴ A = B−1 or A−1 = B ....(iii)
4 4
4
sin x = (
1
) , sin z = (
1
)
AB = BA = I = BB−1
8 2 Now AT = B−1
sin y = 1, A−1 B = I
1
4
1
4 4
sin x = −( ) , sin z = −( ) From (iii) ∴ B = A−1
8 2
∴ BT = (A−1 )T = (AT )−1
sin y = –1,
BT = (B−1 )−1 ∴ B = BT
1
4
1
4 4
sin x = ( ) , sin z = −( ) 2A + 3B2 = I ∴ 2AB + 3B3 = B
8 2
2I + 3B3 = B ∴ 3B3 = B − 2I
sin y = –1,
4 4 4 Let ∴ α= ∣
∣ A−1 − 3B3 + BA∣∣ = |B − (B − 2I) + I| = |3I| = 27
1 1
sin x = −( ) , sin z = +( ) β = tr (A−1 − 3B3 − BA) = tr ((B − (B − 2I) − I)
8 2
β = tr (I) = 3
6. Ans ( A,C,D ) 7. Ans ( A,C,D )

Transposing & ∴ an = 3bn − 1 . . . (i)

Interchange
interchange
column twice.
row twice

­ ↑ ­↑ bn = an−1 + bn−1 + bn−1

bn = an−1 + 2bn−1 . . . . (ii)
From (i) and (ii)
an+1 = 3an−1 + 2an
Clearly a2 = 0, a3 = 3
∣ 1 0 0 ∣
∴ a4 = 6
∣
∣
∣
∣
a5 = 21
f(x) = ∣ 2 9g 2 (x) 2x2 ∣ = 9g 2 (x) − 6x2 g(x) + 2x4
∣ ∣ a6 = 60
∣ ∣
∣ x 3g(x) − x2 1 ∣ a7 = 183
1

(i) m = ∫ [
2
(3g(x) − x2 ) + x4 ] dx for minimum 8. Ans ( A,C )
0
Three planes intersect in a line
1 ∴ D = D1 = D2 = D3 = 0
4 1 x2
∴ m=∫ x dx = and g(x) = Here D1 = D2 = D3 = 0, ∴ D = 0
5 3
0 Δ=0
x
t3 ∣ −1 sin α sin β ∣
(ii) ϕ(x) = ∫ ( − et + e−t ) dt ∣ ∣
9 ∣
0
∣
sin α −1 sin θ ∣∣ = 0
x2 x2
ϕ′′ (x) = − ex − e−x = 0 ∴ = ex + e−x ∣ ∣

3 3 ∣sin β sin θ −1 ∣
2
−1(1 − sin θ) − sin α(− sin α − sin θ sin β)
+ sin β (sin α sin θ + sin β) = 0
No solution. sin2 θ + sin2 α + sin2 β + 2 sin α sin β sin θ = 1
Now D.R's of line
∣ i j k ∣
∣ ∣
∣
∣
−1 sin α sin β ∣∣
∣ ∣
∣ sin α −1 sin θ ∣

= i (sin α sin θ + sin β) + j(sin α sin β + sin θ) + k(1 − sin2 α)

This vector is parallel to line.
sin α sin θ + sin β sin α sin β + sin θ 1 − sin2 θ
∴ = =
cos θ cos β cos α

sin α sin θ + sin β = cos θ cos α

π
cos (θ + α) = cos( − β)
2
π
∴ α + β + θ = 2nπ +
2
9. Ans ( A,D ) 11. Ans ( A,B,D )

A(4 cos α, 2 sin α)

B(4 cos β, 2 sin β)

Corresponding points of A and B on auxiliary

Area of R1 = 10 cosθ • 6sinθ = 30 sin 2θ : for
circle will be
this to be maximum
C = (4 cos α, 4 sin α)
5 3
D = (4 cos β, 4 sin β) ⇒ θ = π/4 ⇒ P ≡ ( , )

1 1 1
√ 2 √ 2
Area of ΔAOB = ar (ΔCOD) = ⋅ ⋅ 4 ⋅ sin θ
2 2 2 Hence, for subsequent areas of rectangles Rn
π
∴ Max. area = 4 when ∠COD =
2 to be maximum the coordinate will be in G.P.
1
Slope of AB = slope of CD
2 1
with common ratio r =
Let mCD = m ∵ CD also .......... through P √ 2
5 3 bn
2
4
Equation of CD is y = m ( x − √264) ⇒ an = n−1
; bn = n−1
; e n = √1 − =
5
(√ 2) (√ 2) an
2

∣√
∣ 264 ⋅ m∣∣
1 dist. frm origin = = 2 √2 Eccentricity of all the ellipse will be same
√
1+ tan2
−1 −1
∴ m= , mAB = Distance between focus of ellipse
4 √2 8 √2
5 4 1
E11 = 2a11 e11 = 2 ( )( ) =
32 5 4
10. Ans ( B ) Length of latus rectum of ellipse
2b 2
9
E7 = =
7

a7 20
∞
30 30
∵ ∑ (area of Rn ) = 30 + + +. . . . . upto ∞ = 60
2 2 2
n=1
N
⇒ ∑ (area of Rn ) < 60 for each positive
n=1

integer N

Equation of A′ A′′ is 2x + y = 8

4 16
B ≡ (3, 2) C≡( , )
3 3
12. Ans ( B,C ) 2. Ans ( 11 )
Z4 − |Z|4 = 12iZ2 f (x) = x3 + (x − 1)3 − 4x +
5
2 2
Z 4 − Z 2 Z̄ = 12iZ 2
5
Z 2 − Z̄
2
= 12i f (1 − x) = (1 − x)3 + (−x)3 − 4 (1 − x) +
2
( Z − Z̄ ) (Z + Z̄ ) = 12i
⇒ f (x) + f (1 − x) = 1
Let Z = x + iy
7

2iy (2x) = 12 i 8

Let I = ∫ f (f (x)) dx ............. (1)

xy = 3 1
8
Z1 lies of xy = 3 in first quadrant and Z2 lies on
Apply king property
xy = 3 in third quadrant
7

⇒ ∣∣Z1 − Z2 ∣∣ is minimum when Z1 ≡ 3, √3)

8

(√

I= ∫ f (1 − f (x)) dx ............. (2)

and Z2 ≡ ( −√3, −√3) 1
8
⇒ ∣∣Z1 − Z2 ∣∣ minimum = 2√6
Adding (1) and (2)
⇒ Required area of triangle = 6
7 7

8 8

PART-3 : MATHEMATICS
2I = ∫ f (f (x)) dx + ∫ f (1 − f (x)) dx
SECTION-II 1 1
8 8

1. Ans ( 7.00 )
7

3
Let f (x) = ax3 + bx2 + cx + d 2I = ∫ dx =
4
1
f (0) = 5 ⇒ d = 5 8

3
f (1) = 8 ⇒ a + b + c = 3 ⇒I=
8
Now, f ′ (x) = 3ax2 + 2bx + c
m=3
f ′ (0) = 0 ⇒ c = 0

f ′′ (x) = 6ax + 2b n=8

f ′′ (0) = 0 ⇒ b = 0
m + n = 11
⇒a=3

⇒ f (x) = 3x3 + 5
1
( 3x3 + 5) dx
= 10[tan−1 (x)]
1
Now, ∫
(1 + x2 ) 0

−1
π 5π
= 10 =
4 2
m = 5, n = 2
m+n=7
3. Ans ( 11.00 ) 4. Ans ( 4.00 )
4
Let
Let I = ∫ x h (x) dx P (a prime number) P (a composite) P (1)
= = =k
2 2 1 3

By parts, So, P(a prime number) = 2k

4
P(a composite number)= k
I = (x f −1
(x)) − ∫ f −1 (x) dx
4

2
& P(1) = 3k
2
4
& 3 × 2k + 2 × k + 3k = 1
1
I = 4f −1 − 2f −1 (2) − ∫ f −1 (x) dx ⇒k=
11
2 4
P(success) = P(1 or 4) = 3k + k=
f–1(4) = 1 11
Number of trials, n = 11
4
f–1(2) = 0 Mean = np = 11 × =4
11
5. Ans ( 10.00 )
We know,
The given sequence 4, 7, 1, 8, 9, 7, 6, 3, 9, 2, 1, 3, 4, 7, 1
b f (b )

∫ f (x) dx + ∫ f −1 (x) dx = bf (b) − af (a) S12 = 4 + 7 + 1 + ..... + 1 +3 = 60

a f(a) Sn > 10004
1 4

10004
∫ f (x) dx + ∫ f −1 (x) dx = 1 ⋅ f (1) − 0 ⋅ f (0) = 166 and 166 × 12 = 1992
60
0 2 S1992 = 60 × 166 = 9960
1 1

Now, ∫ f (x) dx = ∫ ( x3 + x + sin 2πx + 2) dx 9960 + 4 + 7 + 1 + 8 + 9 + 7 + 6 = 10002 + 3 = 10005

0 0
4 2 1 No. of terms = 2000
x x cos 2πx
=( + − + 2x)
4 2 2π 0
S2000 > 10004
1 1 1 1 11
= ( + − + 2 ) − (− ) = 6. Ans ( 1.00 )
4 2 2π 2π 4
4 Nr : nC0 n + k – 1Cn–1 + nC1 n+k–2 Cn–1 +
11
So, + ∫ f −1 (x) dx = 4 nC2 n + k – 3Cn – 1 + ..... nCk – 1 • nCn – 1 + nCk n–1Cn–1
4
2
4
= coefficient of xn – 1 in
5
⇒ ∫ f −1 (x) dx = nC (1 + x)n + k – 1 + nC (1 + x) n + k – 2 + ..... +
0 1
4
2 nC (1 + x)n – 1 + nC n – 2 + ..... + nC (1 + x)k – 1
k k + 1 (1 + x) n
5 11
Now, I = 4 − = = coefficient of xn – 1 in
4 4
(1 + x)n + k – 1 (1 + (1 + x)–1)n = (1 + x)k – 1 (x + 2)n
k−1
= ∑ n Cr 2r xn−r (1 + x)
n
= ∑ 2r ⋅n Cr ⋅k−1 Cr−1
r=1
N r = Dr
ANSWER KEY PAPER-2
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8
SECTION-I (i)
A. A,B D A,C A,B A,C,D A,B,C A A,B,C
Q. 9 10 11 12
SECTION-I (ii)
A. C D A B
Q. 1 2 3 4 5 6
SECTION-II
A. 168.00 31.00 1.00 50.00 3.00 3.00

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8
SECTION-I (i)
A. B,D A,B,C B,C A,C,D A,C B,D A,C A,D
Q. 9 10 11 12
SECTION-I (ii)
A. B C C D
Q. 1 2 3 4 5 6
SECTION-II
A. -0.18 to -0.19 83.33 120.00 4.00 9.74 11.00

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8
SECTION-I (i)
A. C,D A,B,C A,C A,B,C A,B,C A,C B,C,D C,D
Q. 9 10 11 12
SECTION-I (ii)
A. C D B C
Q. 1 2 3 4 5 6
SECTION-II
A. 2.00 37.00 5.00 6.00 2.00 4.00

HINT – SHEET
PART-1 : PHYSICS 2. Ans ( D )
E
SECTION-I (i) = Cθ ...... (1)
500 + Rg
1. Ans ( A,B ) ⎡ ⎤
E 10 C θ3
⎢ ⎥ = ..... (2)
⎣ 500 +
Rg×10
⎦
(10 + Rg) 28
Rg+10
From (1) & (2) Rg = 100 Ω
3. Ans ( A,C )
Applying conservation of momentum and angular
1 2 momentum about com of L–shape frame.
√ 2λℓ2 E =
Iw
2
2 1 mℓ 2 2
√2λℓ E = ( sin 45) × 4 w2
2 3
2 mℓ 2 2
√2λℓ E = w motion will be oscillatory.
3
3 √2 λ E 3 √2 × 1 × 4
w=√ ⇒w=√ = √12√2
m 1
5. Ans ( A,C,D ) 8. Ans ( A,B,C )
F0 2F
x=( − x0 ) + x0 = ( 0 − x0 ) For just reaching at D, particle just complete
k k
m
y = – y 0 ⇒ T = 2π √
k lower circular motion.
1 5R
(A) mgh = m(5gR) ⇒ h =
2 2
1
(B) Velocity at C : mg(h − 2R) = mVc2
2

⇒ Vc = √gR
7. Ans ( A )
vs = 20 m/s, v0 = 10 m/s, u = 5 m/s, vw = 30 m/s, mVc2
N = mg + = 17mg
f0 = 500 Hz, v = 300 m/s R/16

(C) Energy conservation from C to D :-

1 R 1
m(gR) = mg. + mVD2
2 8 2
3gR
VD = √
v − (u − vw ) v + v0 − vw 4
f1 = f0 , f2 = ( ) f1 ,
v − (vs − vw ) v + u − vw
(v + v0 − vw ) (v + vw − u) time of flight :
f2 = f0
(v + u − vw ) (v + vw − vs )
2h 17R
(300 − 30 + 10) (300 + 30 − 5) √ =√
f2 = f0 g 4g
(300 + 30 − 20) (300 − 30 + 5)
280 × 325 51
= × 500 Distance = VDT = √
R
310 × 275 16
28 65 28 × 13 364
= ×
31 55
× 500 =
31 × 11
× 500 = = 534 Hz
341
× 500

Wavelength of sound received by wall

v − (vs − vw ) v + vw − vs
λ= =
f0 f0
300 + 30 − 20
= = 0.62m
500
Wavelength of sound received by listner after
reflection from wall

v − u − vw (v + u − vw ) (v + vw − vs )
=
f1 (v + vw − u) f0
(300 + 5 − 30) (300 + 30 − 20)
=
(300 + 30 − 5) × 500
275 × 310
= = 0.52 m
325 × 500
 PART-1 : PHYSICS 11. Ans ( A )
SECTION-I (ii)
9. Ans ( C )

σ1A1 + σ2A2 = – (σ3A1 + σ4A2)

σ1A1 + σ2A2 = (σ5A1 + σ6A2)
_______________________________
2(σ1A1 + σ2A2) = (σ5 – σ3)A1 + (σ6 – σ4)A2
σ1 σ (σ5 − σ3 ) (σ6 − σ4 )
= E1 , 2 = E2 , = E, =E
∈0 ∈0 2∈0 2∈0
500 g = 500 + 500gh ×10–2 + 4000 2A1E1∈0 + 2A2E2∈0 = 2∈0EA1 + 2∈0EA2
500 = 50 h ⇒ h = 10 m A!E1 + A2E2 = E(A1 + A2) ....(1)
E1d1 = E2d2 ....(2)
Force by liquid on upper object E1 = Ed2
(A1 + A2 )
=
100 × 2(1 + 2)
=
200 × 3
= 150
A1 d2 + A2 d1 (2 + 2 × 1) 4
(A1 + A2 )
E2 = Ed1 = 75
(A1 d2 + A2 d1 )
E1 + E2 = 225
E1 – E2 = 75
PART-1 : PHYSICS
SECTION-II

5000 – 500 = 4500 N 1. Ans ( 168.00 )

x + y = 10
Force by liquid on lower object y–x=2
–––––––––
2y = 12
y = 6 cm
x = 4 cm

5000 + 500 = 5500

Total force by liquid on both object
It becomes a square of side length = 6 cm
5500 + 4500 = 104 N

2 2 2
I= ml = × 7 × (6)2
3 3
= 14 × 12 = 168 kg cm2
2. Ans ( 31.00 ) 3. Ans ( 1.00 )
Using mirror symmetry drawing in two D plane.

In loop (1) :
5aρ ρa dB 3a2
−i1 − i2 = × ...(1)
2S S dt 4

in loop (2) :
3aρ ρa dB a2
−(i1 − i2 ) + i2 = × ...(2)
2S S dt 4

From equation (1) & (2)

Req R2
2 dB aS + R = Req
R
i2 = − × × Req + 2
31 dt ρ
R Req
Force on jumper wire : = (Req − R)
2req + R
dp
F= = iℓ B ⇒ 2R2eq + Req R − 2RReq
dt
dp
= i2 aB
dt −R2 = RReq
dp 2 dB a2 SB
=− ×
dt 31 dt ρ 2R2eq − 2RReq − R2 = 0
mv 0
2 a2 S
∫ dP = − ∫ B dB 2R ± √4R2 + 8R2 2R ± 2√3R R + √3R
31 ρ Req = = =
0 B0 4 4 2
a2 B 2 S
v= 1 2 3R + √3R √ 3R(1 + √3)
31ρm RAB = + = =
R ( R + √3R) R 2 ( 1 + √3 ) R2 (1 + √3)

α = 31 R √ 3
⇒ RAB = ( ) = = 1Ω
√ 3 √ 3
4. Ans ( 50.00 ) PART-2 : CHEMISTRY
1
P =− V +5 ...(i) SECTION-I (i)
16
P V γ = cont. 1. Ans ( B,D )
The electron pair back donated by metal goes
into antibonding MO of carbon monoxide, thus
decreases the bond order and increases the bond
length.
P The π-acceptor tendency of ligands are in order
Slope = −γ
V PF3 > PCl3 > PMe3.
P 1
−γ =−
V 16 2. Ans ( A,B,C )
V Magnesium metal can't be extracted from
P= ...(ii)
16V
Equation (i) and (ii) aqueous solution.
V V 5. Ans ( A,C )
=− +5
16 × γ 16 10
V ×3 V ΔTb = 0.54 × × 1000 = 10
+ =5 540
16 × 5 16 30
V 8 P s = P ∘ XH 2 O = 35 × = 26.25
× =5 40
16 5
V = 50 litre PART-2 : CHEMISTRY
5. Ans ( 3.00 ) SECTION-I (ii)
9. Ans ( B )

(I)

P P h3
(II) −−−−→ R–CH=CH–R+Ph3P=O
reduction

Torque about point O, (III)

ℓ mℓ 2
mg. cos 60∘ = ×α
2 3
3g
α=
4ℓ (IV)

12. Ans ( D )
K4 [F e(CN)6 ]
F e+3 −−−−−−−→ F e4 [F e(CN)6 ] ↓
Blue
K4 [F e(CN)6 ]
ℓ 3g
acom = α. = Zn+2 −−−−−−−→ K2 Zn3 [F e(CN)6 ] ↓
2 8 W hite
3 √3 K4 [F e(CN)6 ]
ax = acom· cos 30° = g Cu+2 −−−−−−−→ Cu2 [F e(CN)6 ] ↓
16
Choclate brown
3 √3
fr = max = mg K4 [F e(CN)6 ]
16 F eSO4 −−−−−−−→ K2 F e[F e(CN)6 ] ↓
fr = 3 W hite ppt
 PART-2 : CHEMISTRY 6. Ans ( 11.00 )
SECTION-II
1. Ans ( -0.18 to -0.19 )
0
ΔHreaction = 29.0 kJ
0
ΔSreaction = 95.1 JK −1

ΔG0reaction = ΔH ∘ − T ΔS ∘

= 29000 – 300 × 95.1

= 470 J
− Δ G∘
ln K = = −0.188
RT
2. Ans ( 83.33 )
1
No. of m mol. of FeC2O4 = 100 × 20
= 5m mol.

5
The solution now has + 2y mol of
3
PART-3 : MATHEMATICS
+3 +2
Fe Which will convert to Fe SECTION-I (i)
5 1. Ans ( C,D )
∴ + 2y = 10
3 For equilateral triangle (0, 0) is centroid and
Mass of Fe2(SO4)3 circumcentre
i.e. m = 1
25 5000 5
= × 400 = mg = g
6 3 3

Mass of FeC2O4 = 0.24 g

5/3
% purity of Fe2(SO4)3 = × 100 = 83.33
2

3. Ans ( 120.00 )
For right angled isosceles
For rate to reach 36%

At = 0.6 Å

1
k=
1440 × 7
2 1
∴ t = 1440 × 7 [ × ] n = 3.
3 56 × 10−3
t = 120 × 103 sec
2. Ans ( A,B,C ) 5. Ans ( A,B,C )
1 C2 = 4C1; C3 = 4C2 = 16C1
x
h(t) = f( ) dx; x = ty
∫
t
R2 = 6 + R1; R3 = 6 + R2 = 12 + R1
1
−1
1
R1 + R2 + R3 = C1 + C2 + C3
t
h(t)
t
⇒ 18 + 3R1 = 21C1
= ∫ f (y) . tdy; = ∫ 3−|y| . dy; ⇒ 6 + R1 = 7C1 = R2
t
−1 −1
t
1
t
⎡
0 0 1⎤
t
⎢
⎥
= 2∫ 3 −|y|
. dy M=⎢
⎢
0 0 7 ⎥⎥
⎢ ⎥
0 ⎣
1 4 8⎦
−∞
2 2
Now LHL = 2 ∫ 3y . dy = [3y ]−0 ∞ = − 6. Ans ( A,C )
ln 3 ln 3 200 200
0 Zj
∞ ∑ ∑ = (Z1 + Z2 + ..... Z200)
−y 2 −y ∞ 2 j=1 k=1
Zk
RHL = 2 ∫ 3 . dy = − [3 ]
0
=
ln 3 ln 3 1 1 1
0 ( + +. . . . . + ) ..... (I)
Z1 Z2 Z200
3. Ans ( A,C ) 200 200
Zj
1 ∑ ∑ =0
g(x + 1) = g(x); j=1 k=1
Zk
3
1 1 7. Ans ( B,C,D )
g(x + 2) = g(x + 1) = g(x)
3 9 ∣ 1 + ℓ1 m1 + ℓ21 m21 1 + ℓ2 m1 + ℓ22 m21 1 + ℓ3 m1 + ℓ23 m21 ∣
Now, ∣ ∣
∣ ∣
D = ∣ 1 + ℓ 1 m2 + ℓ 1 m2 1 + ℓ2 m2 + ℓ22 m22 1 + ℓ3 m2 + ℓ23 m22
2 2
∣
∣ ∣
∣ ∣
∣ 1 + ℓ 1 m3 + ℓ 2 2
1 m3 1 + ℓ 2 m3 + ℓ 2 2
2 m3 1 + ℓ 3 m3 + ℓ 2 2
3 m3 ∣
3 1 1
1 ∣ 1 ℓ1 ℓ21 ∣ ∣ 1 m1 m21 ∣

∫ g(x)dx; x = t + 2; ∫ g(t + 2)dt = ∫ g(x)dx ∣ ∣ ∣ ∣

9 ∣ ∣ ∣ ∣
2 0 0 = ∣1 ℓ2 ℓ22 ∣ ∣ 1 m2 m22 ∣
1 ∣ ∣ ∣ ∣
1 1 ∣ ∣ ∣ ∣
i.e. n→
lim αn = ∫ g(x)dx (1 + + +. . . . . ∞) ∣ 1 ℓ3 ℓ23 ∣ ∣ 1 m3 m23 ∣
∞ 3 9
0 = (ℓ1 − ℓ2 ) (ℓ2 − ℓ3 ) (ℓ3 − ℓ1 ) (m1 − m2 ) (m2 − m3 ) (m3 − m1 )
1 −ve −ve +ve −ve −ve +ve
3
= ∫ g(x)dx = +ve so D > 0
2
0
8. Ans ( C,D )
4. Ans ( A,B,C )
x ∈ (0, cos 1) ⇒ cos−1 x > 1 > sin−1 x
1
x ∈ (cos 1, ) ⇒ sin−1 x < cos−1 x < 1
√ 2
x ∈ (sin 1, 1) ⇒ sin−1 x > 1 > cos−1 x
→
− → −
− →
1 AC = AB + AD
x∈( , sin1) ⇒ cos−1 x < sin−1 x < 1 →
− →
−
√ 2 2 −
→ AP AR
AQ = +
γ α β
−
→ →
−
AP −
→ 2
AR
⇒ + (− ) AQ + =0
α γ β
1 2 1 1 1 2
⇒ − + =0⇒ + =
α γ β α β γ
 PART-3 : MATHEMATICS 10. Ans ( D )
SECTION-I (ii)
9. Ans ( C )

2
Length of P Q = T CT = √92 − (6 − 3) = 6√2
let C1 : x2 + y 2 = 92
2 let ∠QT N = θ
Length of P Q = T CT = √92 − (6 − 3) = 6√2
let C1 : x2 + y 2 = 92 NT r 3 1 TQ
∴ = 3 = = = ⇒N is
MT r2 6 2 TP
let ∠QT N = θ
mid-point of TM
NT r 3 1 TQ
∴ = 3 = = = ⇒N is mid- ⇒ T P = 2T Q ⇒ T Q = P Q
MT r 2 6 2 TP
point of TM ⇒ T Q = 6 √2
⇒ T P = 2T Q ⇒ T Q = P Q
∴ NT = √72 + 9 = 9
⇒ TQ = 6 2 √
⇒ LT = 9 + (9 − 3) = 15
∴ NT = √72 + 9 = 9
∵ L (0, 0) ⇒ T (−15, 0)
⇒ LT = 9 + (9 − 3) = 15
∵ L (0, 0) ⇒ T (−15, 0) NQ 3 1
sin θ = = =
NT 9 3
NQ 3 1
sin θ = = = 6 √2 2 √2
NT 9 3 ⇒ cos θ = =
9 3
6 2
√ 2 2
√
⇒ cos θ = = 2√2r r
9 3 Any point on chord AB be ( −15 + , )
3 3
2√2r r
Any point on chord AB be ( −15 + , )
lie on circle C1 : x2 + y2 = 81
3 3
lie on circle C1 : x2 + y2 = 81 ⇒ r2 − 20√2r + 144 = 0
⇒ r2 − 20√2r + 144 = 0
∴ AB = |r1 − r2 | = √(r1 + r2 )2 − 4r1 r2
2
∴ AB = |r1 − r2 | = √(r1 + r2 ) − 4r1 r2 = √800 − 576 = √224
= √800 − 576 = √224 = 4√14
= 4√14

∵N is mid-point of TM and D is mid-point of

∵N is mid-point of TM and D is mid-point of
QM
QM
1
1 ⇒ ND = TQ
⇒ ND = TQ 2
2 1 √
1 = (6 2)
= ( 6 √2 ) 2
2
= 3 √2 = 3 √2
11. Ans ( B ) 12. Ans ( C )
 PART-3 : MATHEMATICS 3. Ans ( 5.00 )
x x
SECTION-II f(t)
∵∫ e dt = ∫ g (x − 1) dt + 2x + 3
1. Ans ( 2.00 ) a 0
x x
f(t)
⇒∫ e dt = ∫ g (t) dt + 2x + 3
a 0
(Using King Property)
Differential both sides, we get
ef(x) = g (x) + 2
D(aλ, 0, 0) E(0, bλ, 0) F(0, 0, cλ)
⇒ g (x) = ef(x) − 2
p = 2EF ⇒ p2 = 4 (EF)2
⇒ g ′ (x) = ef(x) ⋅ f ′ (x)
⇒p 2 = 4(b + c )
2 2 λ2
∵ ef(x) is always greater than zero.
q = 4(a + c )
2 2 2 λ2
∴ Sign of g' (x) is same as sign of f' (x) .
r = 4(a + b )
2 2 2 λ2
∴ Sign of g' (x)
p2 + q2 + r2 = 8λ2 (a2 + b2 + c2)
p 2 + q 2 + r2
p2 + q2 + r2 = 8λ2 ( ) ⇒ λ2 = 1/4 Clearly, local extremum (maximum or
2
minimum) will occur at
2. Ans ( 37.00 )
x = 99, 97, 95, ...., 3, 1
(1,1), (1,4), (4,1), (2,4), (4,2), (3,4), (4,3), (4,4) –
all have one choice for image. ∴ Sum of all the values = 1 + 3 + 5 + ..... + 99
50
(2,1), (1,2), (2,2) – all have three choice for = [2 × 1 + (50 – 1) × 2] = 2500
2
image
4. Ans ( 6.00 )
(3,2), (2,3), (3,1), (1,3), (3,3) – all have two From the given equation we have,
choices for image. x+y x−y x+y x+y
2 sin cos = 2 sin cos
So the total functions = 3 × 3 × 2 × 2 × 2 = 72 2 2 2 2
x+y x−y x+y
Case 1 : None of the pre-images have 3 as ⇒ sin [cos − cos ] = 0
2 2 2
image x+y x y
⇒ sin × 2 sin sin = 0
Total functions = 2 × 2 × 1 × 1 × 1 = 4 2 2 2
x+y x
Case 2 : None of the pre-images have 2 as Which holds if either sin = 0 or sin = 0
2 2
image Also since |x| + |y| = 1 ⇒ |x|≤ 1, |y| ≤ 1. So, the
Total functions = 2 × 2 × 2 × 2 × 2 = 32 required solution is either x + y = 0 or x = 0 or y = 0
Case 3 : None of the pre-images have either 3 or If x = 0, y = ± 1, and if y = 0, x = ± 1 and if x + y = 0
2 as image 1
⇒ y = – x ⇒ |y| = |–x| = |x| =
Total functions = 1 × 1 × 1 × 1 × 1 = 1 2
∴ Total onto functions = 72 – 4 – 32 + 1 = 37
So that the required pairs (x, y) are
1 1 1 1
(0, ±1), (±1, 0), ( , − ) , (− , ) which are 6
2 2 2 2
in number.
5. Ans ( 2.00 ) 6. Ans ( 4.00 )
6 27 x2 + (2 − tan θ) x − (1 + tan θ) = 0
2 −1
9A − 6A = [ ] B
α + β = tan θ − 2
−10 −1
−6 27 αβ = − tan θ − 1
2
⇒ (3A − I) = [ ]
From equation (1) + (2)
−3 0
2 α + β + αβ = −3
⇒ (3A − I) = 81
(α + 1) (β + 1) = −2
⇒ |3A − I| = ± 9 (1)
a b
Hence either α + 1 = −2 and β + 1 = 1
Let A = [ ] then α = −3, β = 0
c d or α + 1 = −1 and β + 1 = 2
∴ 9(ad – bc) = 18 or 0 (using equation 1)
α = −2 and β = 1
Since A ≠ 0 If α = −3, β = 0 then tan θ = −1
∴ ad − bc = 2 ⇒ |A| = 2 3π 7π
⇒α= ,
4 4
If α = −2, β = 1 then tan θ = 1
π 5π
⇒θ= ,
4 4
3π 7π π 5π
Sum = + + + = 4π = 4
4 4 4 4