Exercise 5
Exercise 5
Exercise - V JEE-Problems
0.87 7. 1 2
i × 0.004 = 0.01
2. (C) I, IV i = 2.5
i = 1 + (3 1)
3. i = 1 + 0.23 (2 -1) n = 2 for CH3COOH 2.5 = 1+ 2
i = 1 + 0.23 = 1.23
0.75
1.23 3 10 103 3 % 75%
Tf 1000 1.36
60 (500 0.997)
0.2294
8. Tb i K bm In acetone
i1 = 1
n 12 300(n 20)
Ps= 300 500 In benzene
n 12 12 n (n 12)
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Solutions Slot – 3 (Chemistry) Page # 33
72.5 nsolute
14. Tb K b water n 1000
10. 7 = i × 14 ×
94 solvent 18
i = 0.65
now water is solvent & ethanol is solute.
1
0.65 = 1 + 1 0.1
2 = 0.52 × 1000 3.21
0.9 18
0.7
Tb = 100 + 3.21 = 103.21° C
% 70% = 376.21 K.
2 phenol phenoldimer
15. Pair = KH xair
5 = 105 × xair
1
2
0.3 xair = 5 × 10-5
0.35
dissolved in water
35 %
nair (in water )
5 10 5
nair(in water ) nwater
20 1000
11. 2 = i × 1.72 ×
172 50 nwater = 10
nair(in water) = 5 × 10-4
i=½
nN2 (in water) = 5 × 10-4 × 0.8
n
K f solute 1000
w solvent
nsolute
Kf 1000
nsolvent w solvent
0.1
2 1000
0.9 46
= 4.831
Tf = 155.7 - 4.831 = 150.87 K
In solution ethanol is solvent & water is sol-
ute.
13. Ps = 0.9 × 40
= 36
(water is solute considered as non-volatile ac-
cording to question)
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