Yti 45 Tu VD0 QKJ Beh Ekm L

This section contains multiple choice questions.
Each question has 4 choices (a),

(b), (c), (d), out of which ONLY ONE is correct. Choose the correct option.
1. Which property of an element is a whole number

(a) Atomic Weight (b) Atomic Volume
(c) Atomic Number (c) Atomic Radius
2. The ratio of charge to mass of which particles is the greatest?
(a) proton (b) neutron (c) He 2  (c) electron
3. Nucleons are
(a) electrons and proton (b) protons only
(c) neutrons and electrons (d) protons and neutrins
4. The correct increasing order of Molecular Weight is:
(a) H2O  H2S  CO2  SO2 (b) H2O  H2S  CO2  SO2
(c) H2O  H2S  CO2  SO2 (d) H2O  H2S  CO2  SO2
5. The ratio of weights of Hydrogen and Oxygen in H2O2 is:
(a) 8:1 (b) 1:8 (c) 1:9 (d) 1:16

6. If two elements combine to form two or more compounds they obey
(a) Law of Conservation of Mass (b) Law of Definite proportion
(c) Law of Multiple Proportion (c) all three laws
7. A balanced equation is a direct consequence of
(a) Law of Multiple Proportion (b) Law of Conservation of Mass
(c) Law of Definite proportion (d) none of these
8. The Law of Multiple Proportions can be applied to which compounds out
of CO2 ,SO2 ,SO3 ,H2O
2
(a) CO2 ,SO2 (c) SO3 , H2O (d) SO2 ,SO3
(b) CO2 ,SO2
9. The standard unit of mass of subatomic particles is:
(a) kg (b) coulombs (c) mg (d) amu
10. Fractional atomic weight are due to the existence of
(a) many atoms (b) different sources of elements
(c) neutrons in the nucleus (d) isotopes
11. The symbol of Lead and Mercury are respectively
(a) Hg, Pb (b) Pb, Hg (c) Le, Me (d) Ld, My
12. A symbol of an element does not convey information about
(a) atomic number (b) atomic weight
(c) mass number (d) all three options (a, b and (c)
13. The atomicity of an element tells about
(a) physical properties
(b) number of electrons
(c) number of atoms in one molecule
(d) Its combining capacity
14. A formula tells about
(a) number of atoms present in one molecule
(b) gives a mathematical formula
(c) an element
(d) the source of the compound
15. The molecular formula is a short form representation of
(a) a compound (b) an element
(c) a mixture (d) an alloy
16. The formula of Ammonium ferricyanide is:
3
Am3 Fe CN 6  NH4 Fe CN 6 
(a) (b)
(c)  NH4 3 Fe CN 6  (d) NH4 Fe CN 6 

3
17. A balanced chemical equation supports

(a) Law of chemical equilibrium (b) Law of conservation of energy
(c) Law of conservation of mass (d) none of these
18. Na2C2O4 is the formula of sodium
(a) carbonate (b) formate (c) oxalate (d) acetate

19. The ion that is not univalent is:
(a) Ammonium (b) sodium (c) bicarbonate (d) sulphate
20. The trivial name of Na2CO3 is:
(a) soda ash (b) soda carb (c) soda (d) baking soda
21. Which of the following phrases would be incorrect to use?
(a) a molecule of an element (b) an atom of an element
(c) a molecule of a compound (d) an atom of a compound
22. For liquefaction of a gas the favourable conditions are
(a) low temperature and pressure
(b) low temperature and catalyst
(c) low temperature and high –pressure
(d) low temperature, high pressure and a catalyst.
23. Arrange in decreasing order of the total number of atoms
p) 2.4  1020 molecules of O3 q) 11,200 ml of SO2 at STP
r) 3 gm, atoms of Ar s) 1 mole of H2SO4
(a) s>r>q>p (b) p>q>r>s (c) s=r=q=p (d) p>r>s>q
4
24. Arrange in increasing order of the volume at STP.
p) 3  1022 atoms of He q) 11 gm of N2O
r) 0.2 gm atoms of O2 s) 1.5  1022 molecules of H2
(a) p>q>s>s (b) p<q<s<s (c) s<p<r<q (d) s>p>r>q

25. The kinetic energy of a gas molecule would be zero at:
(b) 273 0 C (c) 273 C (d) 1160 C
0 0
(a) 0 C
26. Weight of one gram molecule =
(a) The weight in grams of one molecule
(b) Molecule present in 1 gm
(c) Mol.. Wt. expressed in grams
(d) none of these
27. Weight of one gram atom=
(a) At. Wt. expressed in grams (b) The weight in grams of one atom
(c) Atoms present in 1 gm (d) none of these
28. Gram Molar Volume = Volume occupied at STP by
(a) One gram molecule of gas (b) one molecule of gas
(c) one gram of gas (d) none of these
29. Number of gram atoms present in one mole Vitamin B12 given its formula
is C63H88CoN14O14P
(a) one (b) 181 (c) 6 (d) 6  10 23

30. Assuming Avogadro Number to be N, the number of electrons in one
mole of Oxygen molecules is:
(a) 16 N (b) 8 N (c) 4 N (d) N
31. Number of moles of CO that contain same number of gram atoms as
present in 4 moles of NH3 is:
5
(a) 4 moles (b) 2 moles (c) 6 moles (d) 8 moles
32. Ratio of weights of N2O and CO2 that occupies same volume at STP is:
(a) 1:2 (b) 2:1 (c) 1:1 (d) 1:3

33. Ratio of volume of N2O and CO2 at STP that have same weight is:
(a) 1:2 (b) 2:1 (c) 1:1 (d) 1:3

34. Avogadro Number of atoms of Hydrogen weigh
(a) Half gram molecule (b) One gram atoms
(c) 2 gm (d) 1 gm
35. Avogadro Number cof atoms of Hydrogen weigh
(a) Half gram molecule (b) One gram atoms
(c) 2 gm (d) 1 gm
36. The number of gram atoms present in 128 grams of sulphur?
(a) 1 (b) 2 (c) 3 (d) 4
37. The weight of 2.0 moles of KCIO3 in grams is:
(a) 145 (b) 345 (c) 245 (d) 100

38. The number of moles present in 400 grams of CaCO3 is:
(a) 4 (b) 3 (c) 2 (d) 1

39. The total number of electrons present in 3.2 gm of Methane is:
(a) 12  10 (b) 12  10 24 (c) 12  10 (d) 12  10 21

22 23
40. The total mass of protons in grams present in 4.4 gm of carbon dioxide is:
(a) 13.2  10 amu (b) 13.2  1023

22
(c) 5) amu 13.2  1024 amu (d) 5) 13.2  1023 mg

41. The total number of neutrons present in 7 mg of nitrogen is:
(a) 2.1 10 (b) 0.21 1020 (c) 210  10 20 (d) 21 10 20

20
42. The total mass of neutrons in amu in 7 mg of carbon 14 is:
6
(a) 24  10 (b) 24  10 21 (c) 210  10 (d) 210  1019
20 22
43. The total number of electrons present in one CO32 ion is:
(a) 32 (b) 64 (c) 60 (d) 62

44. The volume occupied by 2.5 mole of CO2 at NTP is:
(a) 5.6l (b) 0.56 l (c) 0.0056 l (d) 56 l

45. The volume occupies by 0.5 mole of N2 at NTP is:
(a) 0.112 l (b) 1.12 l (c) 11.2 l (d) 112 l

46. The number of moles and molecules present in 40 gm of oxygen is
____,_______ respectively.
(a) 1.25,75.2  10 (b) 1.25,7.52  1023

23
(c) 12.5,7.52  1023 (d) 0.125,7.52 1023

47. The weight of 0.4 – gram atom of carbon in grams is:
(a) 4.8 (b) 48 (c) 0.48 (d) 480
48. A Phosphate rock contains 42.6% Ca 3  PO4 2 by wt. The number of
moles of Ca 3  PO4 2 present in 5 kg of rock is:
(a) 687 (b) 6.87 (c) 68.7 (d) 0.687

49. The weight of carbon and oxygen present in 3 moles carbon dioxide is:
(a) 36,96 (b) 96, 36 (c) 3.6,9.6 (d) 9.6, 3.6
50. The volume occupied by 1.5  1022 molecules of NO2 at NTP is:
(a) 0.56 l (b) 5.6 l (c) 56 l (d) 560 l

51. The weight in gram of 1024 molecules of nitric oxide is:
(a) 49.8 (b) 4.98 (c) 498 (d) 0.498
52. The weight of calcium in grams that contains the same number of atoms
as 3 gm of carbon?
7
(a) 1000 (b) 1 (c) 100 (d) 10
53. What weight of nitrogen in grams contains the same number of molecules
as 5.6 litres of CO2 at NTP?
(a) 0.7 (b) 70 (c) 7 (d) 700

54. The weight in grams of a sinlge atom of carbon is:
(a)
1.99  10 23
gm (b) 1.99  1023 gm
(c) 19.9  1023 gm (d) 199  1023 gm
55. The volume im ml of 1 molecule of water assuming density of water is

1g/cc, is:
(a) 2.99  10 23 l (b) 2.99  10 23 ml
(c) 2.99  10 23 ml (d) 2.99  10 23 l
56. A drop of water occupies 0.05cc. If the density of water is 1g/cc find the
number of molecules in each drop.
(a) 1.67  1021 (b) 16.7  1021 (c) 167  10 21 (d) 1.67  1020
57. Arrange in decreasing order of total number of atoms:
p) SO3  SO4 2 2.4  1020 molecules of O3
q) 11,200 ml of SO2 at STP
r) 3 GM ATOMS OF aR
s) 1 MOLE OF H2SO4
(a) s> r>q>p (b) s<r<q<p (c) s=r=q=p (d) s<r<q<p

58. Arrange in increasing order of volume occupied at STP:
p) 3  10 22 atoms of He q) 11 gm of N2O
r) 0.2 gm atoms of oxygens s) 1.5  1022 molecules of H2
(a) s> p>r>q (b) s<p<r<q (c) s=p=r=q (d) s>r>q>p
8
This section contains certain number of questions. Each question contains
STATEMENT-1 (Assertion) and STATEMENT - 2 (Reason). Each question has 4
choices (a), (b), (c) and (d) out of which ONLY ONE is correct. Choose the
correct option.
59. STATEMENT-1: Atomic Number is a non-zero positive whole number.

because
STATEMENT - 2: Protons are positively charged particles.
(a) Statement - 1 is True, Statement - 2 is True; Statement - 2 is a correct
explanation for statement - 1
(b) Statement - 1 is True, Statement - 2 is True; Statement - 2 is NOT a
correct explanation for Statement - 1
(c) Statement - 1 is True, Statement - 2 is False
(d) Statement - 1 is False, Statement - 2 is True
60. STATEMENT-1: The Mass Number of Hydrogen is equal to its Atomic
Number.
because
STATEMENT - 2: H – atom has no neutrons.
61. STATEMENT-1: The ratio of weights of Carbon and Oxygen is CO2 is
9
3:8 and it is a constant.
because
STATEMENT - 2: The atomic weights of Carbon and Oxygen are a
constant.
62. STATEMENT-1: Both Atomic Weight and Molecular Weight are not
physical quantities
because
STATEMENT - 2: Atomic Weight and Molecular Weight are ratios and
have no units.
63. STATEMENT-1: Ferrous ion is a divalent ion.
because
STATEMENT - 2: Iron atom loose two electrons to carry positive charges.
10
64. STATEMENT-1: Balancing a chemical equation is important to study a
chemical reaction.
because
STATEMENT - 2: A balanced equation tells about energy changes that
take place.
65. STATEMENT-1: As both calcium and sulphate carry two positive charges
the formula of calcium sulphate is Ca2  SO4 2
because
STATEMENT - 2: Calcium sulphate is a compound formed by
combination of calcium and sulphate ions.
11
66. STATEMENT-1: Dry ice does not have water in it.
because
STATEMENT - 2: As dry ice is dry, water is absent.
67. STATEMENT-1: The number of moles in one Gram Molecular Weight of
any pure substance is same.
because
STATEMENT - 2: One Gram Molecular Weight of any pure substance
has the same number of molecules.
68. STATEMENT-1: Equal weights of CO2 and N2O will have same number
of molecules under similar conditions.

because
STATEMENT - 2: The molecular weight of the two gases is the same.
12
69. STATEMENT-1: A molecules of SO2 gas has 3 atoms.
because
STATEMENT - 2: A gram molecule of SO2 has three gram atoms of all
atoms.
70.. STATEMENT-1: One gm-molecules of steam will occupy 22.4 l.
because
STATEMENT - 2: One gm- molecule of any gas at STP will occupy 22.4
l.
71. STATEMENT-1: One gm-atom of any inert gas at STP has the same
volume as one gm-molecules of H2 also at STP.
13
because
STATEMENT - 2: Atomicity of Inert gases is one.
72. STATEMENT-1: A volume of 22.4 l of any gas at STP will have the same
weight.
because
STATEMENT - 2: If volume of any gas is 22.4 l at STP the weight will be
one gm –molecule.
73. STATEMENT-1: The number of gram atoms in one gram molecule of
SO3 is three.
because
STATEMENT - 2: One gram molecules is the gram molecular weight of
compound.
14
74. STATEMENT-1: Equal volumes occupied by different gases have same
number of molecules.
because
STATEMENT - 2: At STP gram molar volume of all gases is same.
75. STATEMENT-1: The ratio of moles present in equal weight of two gases
of Molecular weight M1 and M2 is M2 / M1
because
STATEMENT - 2: Number of Moles =Weight /Molecular Weight
76. STATEMENT-1: The ratio of weights of two gases of Molecular weight
M1 and M2 if number of moles is same is M1 / M2
15
because
STATEMENT - 2: Weight has no relation to Molecular Weight.
77. STATEMENT-1: The number of gram atoms in one mole of Helium will
be numerically the same as the number of gram molecules present in one
mole of CO2 .
because
STATEMENT - 2: The atomicity of Helium is 1.
78. STATEMENT-1: The number of gram atoms in 1 mole of CaCO3 is one.
because
STATEMENT - 2: One mole CaCO3 has 40 gms Calcium, 12 gms
Carbon and 48 gms Oxygen.

16
79. STATEMENT-1: The volume occupied by half-mole SO2 at STP is the
same as the volume occupied by 1 gram of H2 at STP.
because
STATEMENT - 2: Gram Molar volume of all gases is same.
80. STATEMENT-1: The atomicity of H-molecules is 2.
because
STATEMENT - 2: The weight of one H-molecule is 2gm.
81. STATEMENT-1: The atomic weight of Carbon is 12gm.
because
STATEMENT - 2: Atomic Weight is a ratio.
17
This section contains paragraphs. Based upon each paragraph multiple

choice questions have to be answered. Each question has 4 choices (a),
(b), (c) and (d), out of which ONLY ONE is correct. Choose the correct
option.
Paragraph for questions 41 to 44

Molecular Formula gives the short form representation of the formula of a
compound. It represents one unit or molecule of the compound. Molecular
Formula tells about the elements present in the compound. It gives the actual
number of atoms of each element that are combined chemically to form the one
molecule of the compound. An Empirical Formula on the other hand gives the
simple ratio of the number of atoms of each element present in the compound.
The Molecular Formula is a whole number multiple of the Empirical Formula.
81. The Empirical Formula of C6H12O6 is:
(a) C3H4O2 (b) C2H4O2 (c) C12H24O12 (d) CH2O
83. The Molecular Weight divided by Empirical Weight is always a

(a) positive non-zero whole number
(b) fraction
18
(c) unity
(d) infinite
82. The common information conveyed both Molecular Formula and
Empirical Formula is:
(a) the weight of molecule
(b) the number of atoms in the molecule
(c) the elements present in one molecule (d) the ratio of atoms
Paragraph for questions 85 to 87

When matter undergoes a change. The changes are of two types: Physical and
Chemical Change. A
Physical Change is a change that involves only a change in the physical state of
matter. Its chemical properties remain the same. Usually increasing the
temperature or applying pressure or both brings about a Physical Change. On
reversing the condition, i.e,. reducing the temperature or reducing the pressure or
both, the original state of matter is restored. In other words, Physical are
reversible. A Chemical Change is change that involve a change in the chemical
composition of matter. A new substance is formed. In a Chemical Change, the
chemical and physical properties of the substance formed will be different from
the original substance.
85. Rain formation is a
(a) chemical change (b) physical change
(c) no change takes place (d) gravitational phenomenon
85. When zinc carbonate is heated and cooled, the change that is observed is
(a) physical
(b) nuclear changes
19
(c) first chemical and then physical
(d) first physical and then chemical
85. In a chemical change the properties that change are
(a) chemical only (b) physical only
(c) both chemical and physical (d) neither chemical nor physical
Paragraph for question 88 to 92

Chemical reactions involves interaction of atoms and molecules. A large number
of atoms/molecules (approximately 6.023  1023 ) are present in a few grams of
any chemical compound varying with atomic/molecular masses. To handle such
large numbers conveniently, the mole concept was introduced. This concept has
implications in diverse areas such as analytical chemistry, biochemistry,
electrochemistry and radiochemistry. The following example illustrates a typical
case, which requires a clear understanding of mole concept. A drop of water
(assuming its volume to be 0.5 ml and density to be 1g/c(c) has 1.7  1022
molecules!
(Part of the above paragraph is an extract from IIT – JEE 2007 question paper)
88. If one dozen eggs is numerically equal to 12 eggs, then one mole of water
is numerically =
(a) drop of water (b) 3 molecules of water
(c) one molecule of water (d) 6.023  1023 molecules of water
89. The volume occupied by one mole of a gas at STP
(a) 0.5 ml (b) 0.5 l
(c) gram molar volume (d) 1 l
90. If the atomicity of a gas 2 then the number of atoms present in 1 gram
molar volume is
20
(a) 0.5 moles (b) 1 mole (c) 2 moles (d) 4 moles
91. The order of size of an atom is
0 0
(a) 108 cm (b) 10 24 cm (c) 108 A (d) 10 A
92. A mole is equal to
(a) one molecule (b) one dozen
(c) 6.023  1023 molecules (d) a drop of water
Paragraph for question 93 to 97

The physical volume of the all the gas molecules added up is a tiny fraction of the
actual volume occupied by the gases. Consider one mole of Hydrogen gas at STP.
0
Assuming that the molecules are spheres of radius 1A , the volume of each
Hydrogen molecule using formula, can be found to be approximately 4.17  10 24
cc. Since one mole has 6.023  1023 molecules, the physical volumes of all these
molecules will be approximately 2.516 cc! The actual volume occupied by these
molecules at STP is 22,400 cc! This gives an idea of how small the molecules are
and also about the extent of inter-molecular spaces (between the molecules).
93. The actual physical volume of all molecules in one mole of Hydrogen gas
at STP expressed as a percentage of the actual volume occupied by the
gas molecules at STP is
(a) 10 to 11% (b) 1 to 2 %
(c) 0.01 to 0.02 % (d) 100 %
94. One mole of Hydrogen gas at STP has
(a) 6  10 23 molecules (b) 6  10 23 atoms
(c) 12  10 23 molecules (d) 12  10 23 atoms
95. In the above example, if only half mole of hydrogen gas is taken the
actual physical volume of all molecules in one mole of Hydrogen gas at
21
STP expressed as a percentage of the actual volume occupied by the gas
molecules at STP will be
(a) 0.005 to 0.01 % (b) 0.5 to 1%
(c) 0.01 to 0.02% (d) 50%
96. The volume of each Hydrogen molecule is
(a) 3.733  10 22 ml (b) 3.733  10 21 ml
(c) 0.3733  10 22 lx (d) 22.4 l
97. The weight of each Hydrogen molecules is
(a) 2 gm (b) 1 gm (c) 2 amu (d) 1 amu
This section contains Matrix-Match type questions. Each question contains

statements given in two columns which have to be matched. Statements
(a, b, c, (d) in Column I have to be matched with statements (p, q, r, s) in
Column II. The answers to these questions have to be appropriately
bubbled as illustrated in the following example.
If the correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the
correctly bubbled 4 x 4 matrix should be as follows:
48. Match the sub particle/ion in Column I with the mass in amu in Column II
22
Column I Column II
(a) electron (p) 1 amu
(b) neutron (q) 0 amu
(c) proton (r) 4 amu
(d) He 2  (s) 1/1836 amu
99. Match the charge in Column I with sub atomic particle/ion in Column II
Column I Column II
(a) -1 (p) electron
(b) 0 (q) proton
(c) +1 (r) alpha particle
(d) +2 (s) neutron
100. Match the compound in Column I with molecular weight in Column II
Column I Column II
(a) CO2 (p) 60
(b) N2O (q) 64
(c) SO2 (r) 44
(d) NH2CONH2 (s) 18
101. Match the ions in Column I with the typical examples given in Column II
Column I Column II
(a) divalent cation (p) Al 3 

(b) divalent anion (q) Ca 2  
(c) a trivalent radical (r) ZnO22
(d) a trivalent ion (s) PO43
102. Match the formula of the compounds in Column I with their names in
23
Column II
Column I Column II
(a)  NH4 2 CO3 (p) Ammonium oxalate
(b) HCOONH4 (q) Ammonium acetate
(c)  NH 4 2 C2O4 (r) Ammonium formate
(d) CH3COONH4 (s) Ammonium carbonate
103. Match the trivial names in Column I with the chemical names in Column
II
Column I Column II
(a)Tear gas (p) N2O
(b) Marsh gas (q) CCl3 .NO2
(c) Laughing gas (r) CO.Cl 2
(d) War gas (s) CH4
104. Match the actual weights in Column I with their equivalent in Column II
Column I Column II
(a) Weight of one mole of H gas (p) 1 amu
(b) Weight of one molecule of H gas (q) 1 gm
(c) Weight of one atom of H (r) 2 gm
(d) Weight of 11.2 l of H gas at STP (s) 2 amu
105. Match number of gm. Atoms in Column I with one gm, molecule of
24
element/compound in Column II
Column I Column II
(a) one (p) Ammonia
(b) two (q) CO2
(c) three (r) Oxygen

(d) four (s) Helium
106. Match the volumes at STP in Column I with the weights in Column II
Column I Column II
(a) one gram molar volume (p) 16 gm of O2
(b) 11.2 l (q) 44 gm of N2O
(c) 44.8 l (r) 44 gm of CO2
(d) 22.4 l (s) 4 gm of H2
107. Match conditions in Column I with the value in Column II

Column I Column II
(a) STP (p) 0 0 C , 1 atm
(b) absolute zero (q) 273k, 76 cm of Hg
(c) NTP (r) 273 K
(d) 0 0 C (s) 273 0 C
108. Match conditions in Column I with the quantity in Column II
Column I Column II
(a) Avogadro Number (p) 22.4 l at STP
(b) Loshcmidt Number (q) 2  Vapour Density
(c) Molecuar Weight (r) 2.689  1019 ml
(d) Gram Molar Volume (s) 6.023  1023
109. Match the quantities given in Column I with those in Column II
25
Column I Column II
(a) Gram Molar Volume of Oxygen at STP (p) 11.2 l
(b) Half mole of Oxygen at STP (q) 6  10 22
(c) Two gram atoms of Oxygen (r) 22.4 l
(d) 0.1 gram molecule of Oxygen (s) 32 gm
110. Match the quantities in Column I with those in Column II
Column I Column II
(a) one gram molecule (p) atomic weight expressed in grams
(b) one gram atom (q) 6  10 23 unite
(c) one mole (r) molecular weight expressed in
grams
(d) gram molar volume (s) 22.4 l at STP
111. Match the quantities in Column I with those in Column II
Column I Column II
(a) 2 moles of SO2 (p) 100 gm
(b) 0.5 moles of N2 (q) 440 gm
(c) 1 mole of CaCO3 (r) 11.2 l at STP
(d) 10 moles of CO2 (s) 99.6 l at 0 K and 0.5 atm
112. Match the volume in Column I with the quantities in Column II

Column I Column II
(a) 11.2 l of SO2 at STP (p) 44gm
(b) 22.4 l of CO2 at STP (q) 0.5 gm
(c) 5.6 l of H2 at STP (r) 6  10 23 molecules
(d) 22.4 l of N2O at STP (s) 32 grams
113. Match the number of molecules in Column I with the quantities in
26
Column II
Column I Column II
(a) 6  10 20 (p) 0.01 mole of N2 gas
(b) 6  10 21 (q) 1 mole of helium gas

(c) 6  10 22 (r) 0.1 mole of CO2 gas
(d) 6  10 23 (s) 0.001 mole of O2 gas
27
1. Atomic Number is a whole number as the number of protons in
the nucleus cannot be a fraction.
Hence C is the correct option.
2. The ratio of charge to mass (in amu) of proton is 1, of neutron is 0,

of He2+ is 1 2 , and of electron is 1840/1.
Hence D is the correct option.
3. Nucleons are sub atomic particles present in the nucleus - neutrons

and protons.
4. The molecular weights of H2O is 18, of H2 S is 34, of CO2 is 44

and of SO 2 is 64.
5. The sum of atomic weights of Hydrogen is 2 and of Oxygen is 32

in H2O2 . The ratio is thus 1 : 16.
6. When two elements combine to give two or more than two

compounds the ratio of masses of one of the elements that
combines with a fixed mass of the other element will be simple.
This is the Law of Multiple Proportion. The elements will obey the
other two laws also in the individual compounds.
7. A balanced equation is another way of saying that matter can

neither be created nor destroyed. In a balanced equation the
number of atoms of each element will be the same on both sides of
the equation as atoms can neither be created nor destroyed.
2
Hence B is the correct option.
8. The Law of Multiple Proportions can be applied if two elements

combine to give more than one compound. So the law can be
applied to SO 2 and SO3.
9. The standard unit of mass is amu and is equal to one-twelfth the

mass of one atom of C12 atom.
10. Fractional atomic weights are due to the phenomenon of Isotopy

as atoms of different atomic masses will be present to varying
degrees in a given sample of an element exhibiting Isotopy.
11. The Latin name of lead is Plumbago (hence the symbol Pb) and of
mercury is Hydrargyrumum (hence the symbol Hg).
12. The symbol of an element does not give information about the
atomic number, atomic weight or mass number.
13. Atomicity by definition is the number of atoms in one molecule of

an element.
14. A formula tells about the simple ratio or actual number of atoms of
all elements present in one molecule of the compound.
Hence A is the correct option.
3
15. The molecular formula is a short form representation of a
compound giving the actual number of atoms of all elements
present in one molecule of the compound.
16. The formula of ammonium ion is NH+ and that of ferricyanide ion
is  Fe  CN 6  .
3+
17. A balanced chemical equation has the same number of atoms of

each element on each side of the equation as the atoms present in
the reactants cannot be destroyed or new ones created when
products are formed.
18.  COOH 2 or C2O4H2 is the formula of oxalic acid. Na 2C2O4 is the

formula of sodium oxalate.
19. Ammonium  NH  ,
4

sodium  Na 
+
and bicarbonate ions
 HCO3 -  are univalent as they carry unit positive or negative
 
 
charge. Sulphite ion  SO4 2-  is bivalent.
20. Trivial name of sodium carbonate is soda ash.

21. A compound is made up of two or more atoms combined

chemically.
4
22. For liquefaction of gases high pressure is to be applied as the
particles come close together. Low temperature conditions reduce
the kinetic energy of the particles.
23. Using mole concept the number of molecules in each option can
be calculated as follows.
p - Ozone, O3 3  2.4 1020 atoms of O=7.2×1020.
q - As 22,400 ml of SO 2 at STP has 6 1023 molecules 11, 200 ml
of SO 2 at STP has 31023 molecules.
As 1 molecules of SO 2 has 3 atoms, 31023 molecules of SO 2
have 3 x 3 x 1023  9000 1020 atoms.
r - As 1 gm. atom of Argon has 6 1023 atoms 3 gm. atoms of
Argon has 3 6 1023 atoms = 18000 1020 atoms
s - As 1 molecule of H2SO4 has 7 atoms 6 1023 molecules of
H2SO4 have 7  6 1023 atoms = 42000 1020 atoms.
Thus the decreasing order of total number of atoms is s > r > q >
p. Hence A is the correct option.
24. Use mole concept as shown above to derive volume of each gas
given in each option.
25. As all gases become liquids at 0K or 273K, the kinetic energy of

the gas molecules becomes zero at this temperature.
26. Atomic Number of an element cannot ice be zero or less than. It is

also a whole number as the number of protons in an atom cannot
be a fraction. Statement 2 is true but not the reason.
5
27. The number of neutrons in H-atom is zero while the number of
protons is 1. Hence, the Mass Number is 1 and Atomic Number is
1.
28. The atomic weight of all atoms of Carbon and oxygen in CO2 is
12 and 32 respectively. The ratio of carbon to oxygen in CO2 is
thus 3 : 8. Statement 2 is also true but not the reason.
29. Both Atomic and Molecular Weights are physical quantities. They
are ratios of weights of one atom/one molecule with weight of one
H-atom.
30. Ferrous ion has the formula Fe2+ . It is divalent as it carries two
positive charges. The ion is formed when iron atom looses two
electrons.
31. Both Statements are correct though Statement 2 is not the reason
for balancing chemical equations. Balancing of equations helps us
to study the quantities of reactants required and products formed.
32. The formula of calcium sulphate is Ca  SO 4  as both ions carry-two

unit charges the simplified factors are in the ratio 1 : 1. Statement
2 is correct.
33. Dry ice is chemically carbon dioxide in solid state. Statement 2 is

incorrect, as water has no connection with dry ice.
6
34. According to Mole Concept the number of molecules in one gram
molecule of any pure substance is the same 6.0231023
molecules.
35. As per Avogadro’s Law equal volumes of any gas will have the
same number of molecules under similar conditions. This can be
derived using Mole Concept.
22400 ml of any gas at STP will have 6 1023 molecules.
So, 22400 ml of CO2 at STP will have 6 1023 molecules
Also, 22400 ml of N2O at STP (similar conditions) will also have
6 1023 molecules.
The molecular weight of CO2 is same as that of N2O . Statement 2
is not the reason for Statement 1.
36. A molecule of SO 2 is made up of one S-atom and two 0-atoms-

total 3 atoms. The number of atoms that combine with another
element depends on the valence configuration and other atomic
properties like Electro negativity, Ionisation Energy. Statement 1 is
correct. A gram molecule of SO 2 weighs 64 gms derived from
combination of 32 gm (1 gm. atom) of sulphur and 32 gm (2 gm.
atoms of oxygen). Thus, the total number of gm. atoms of both
elements is three. Statement 2 is thus correct though not the
reason for Statement 1.
37. Statement 1 is incorrect as steam forms at 100o C . The volume

mentioned (22.41) is for gases at STP (1 aim and 0o C ).
38. As Helium is mono atomic (atomicity is 1) one gram atom of

Helium will have 6 1023 atoms However since Hydrogen is
diatomic one-gram molecule of hydrogen will have the same
7
number of molecules. The volumes of both gases will be the same
as per Mole Concept at STP- 22.4l.
39. The weight of 22.4l at STP of any gas will be equal to its gram
molecular weight (one gm -molecule). Molecular weights of gases
differ. Hence Statement 1 is incorrect and Statement 2 is correct.
40. Empirical Formula gives the simple ratio of atoms of all elements
in a molecule of a compound.
41. Since Empirical Weight is derived from the Empirical formula that
is obtained by dividing the number of atoms of each element in the
molecule by a common factor, the ratio of Molecular Weight to
Empirical Weight is a whole number.
42. The common information conveyed by a molecular and empirical

formula is both tell about the actual elements present in the
molecule.
43. Rain formation is a physical change of cloud formation due to

evaporation of water and subsequent condensation to give rain.
44. When zinc carbonate is heated it decomposes to zinc oxide and

carbon dioxide. Zinc oxide is yellow when hot and white when
cold. So, the first change is chemical and the second change is
physical.
45. In chemical change new substances are formed with new chemical
and physical properties.
8
46. One mole is a number whose value is 6.023 1023.

47. The gram molar volume of a gas is the volume occupied by one
mole of the gas at STP and is numerically equal to 22 Al.
48. If atomicity of a gas is two, it means that each molecule of the gas
has 2 atoms. One gram molar volume is equal to 22.4l of gas at
STP and the weight of this volume is one mole. One mole of a
diatomic gas contains 6 1023 molecules. As atomicity is two, the
number of atoms is 2  6 1023 atoms or two moles of atoms.
49. The atomic radius of H-atom (the smallest atom amongst all
elements) is 0.59A  0.53 108 cm. The order is thus 108 cm .
50. This is as per mole concept.

51. As per mole concept, weight of one gram molecule is equal to the
molecular weight expressed in grams.
52. As per mole concept, weight of one gram atom is equal to the
atomic weight expressed in grams.
53. As per mole concept, Gram Molar Volume is the volume occupied
by one gram molecule of a gas at STP.
9
54. One mole of Vitamin B12 weighs one gram molecule. Its weight is
the molecular weight expressed in grams. The gm molecular
weight is calculated by adding the gm atomic weights of all the
atoms.
1 mole has 63 gm atoms of Carbon
88 gm atoms of Hydrogen
1 gm atom of Cobalt
14 gm atoms of Nitrogen
14 gm atoms of Oxygen and
1 gm atom of Phosphorous.
63 + 88 + 1 + 14 +14+1= 181 gm atoms.
55. One mole of Oxygen has N molecules of oxygen (N = Avogadro

Number).
As one molecule of oxygen has two atoms of oxygen
N molecules of oxygen have 2N atoms of oxygen.
As each atom of oxygen has 8 electrons 2N atoms have 2N x 8
electrons = 16N electrons.
56. 1 mole of NH3 has 4 gm atoms (1 gm atom of Nitrogen + 3 gm

atoms of Hydrogen)
4 moles of NH3 have 4 x 4 = 16 gm atoms.
2 gm atoms are present in 1 mole of CO (1 gm atom of Carbon +
1 gm atom of Oxygen)
16 gm atoms are present in 8 moles of CO.
57. Consider the gram molar volumes of the two gases.

22.4 l of N2O at STP weighs 1 gm molecule = 28 + 16 = 44 gm
22.4 l of CO2 at STP weighs 1 gm molecule =12 + 32 = 44 gm
10
Thus, ratio of weights = 1 : 1.
58. Consider the gram molecular weight of the two gases.
44 gm of N2O (gm molecular weight) at STP occupies 22.4l.
44 gm of N2O (gm molecular weight) at STP occupies 22.4l.
As the gm molecular weights of the two gases are the same,
The ratio of the two volumes is 1 : 1.
59. Avogadro Number of molecules of Hydrogen means 6 1023

molecules of Hydrogen. 6 1023 molecules is 1 mole.
The weight of 1 mole of Hydrogen is = 2 gm. (its gram molecular
weight).
60. Avogadro Number of atoms means 6 1023 atoms.

As each molecule of Hydrogen has 2 atoms 6 1023 atoms of
Hydrogen have 31023 molecules of Hydrogen.
As 6 1023 molecules of Hydrogen weigh 2gm (its gram molecular
weight) 31023 molecules of Hydrogen weigh 1 gm.
61. As 32 gm of Sulphur (its gram atomic weight) is equivalent to 1 gm

atom 128 gm of Sulphur is equivalent to 4 gm atoms.
62. As the weight of 1 mole of KClO3 is 39 + 35.5 + 48 = 122.5 gm

(sum of atomic weights) 2 moles of KClO3 weighs 2 x 114.5 gm =
245 gm.
11
63. As molecular weight of CaCO3 is 40 +12 + 48 = 100 gm (sum of
atomic weights)
100 gm of CaCO3 is equivalent to 1 mole of CaCO3
So, 400 gm of CaCO3 is equivalent to 4 moles of CaCO3 .
64. The gram molecular weight of CH4 is 16 gm.

16 gm of CH4 has 6 1023 molecules of CH4 3.2 gm of CH4 has
3.2  6 1023
 1.2 1023 molecules of CH4
16
Each molecule of CH4 has 10 electrons (6 electrons in C-atom
and \ electrons in 4 H-atoms)
1.2 1023 molecules has 1.2 1023 electrons.
65. 44 gm of CO2 (gram molecular weight) has 6 1023 molecules.

4.4 gm of CO2 has 6 1022 molecules.
Each molecule of CO2 has 22 protons (6 protons in C-atom and
16 atoms is two O-atoms)
So, 6 1022 molecules have 6  22 1022  132 1022 protons.
Each proton weighs 1 amu = 1.66 1024 gm
So, 132 1022 protons weigh 132 1022 amu = 13.2 1023 amu.
66. 28 gm of N 2 (gram molecular weight) has 6 1023 molecules.

0.007 gm (= 7 mg) of N 2 has 1.5 1020 molecules.
Each molecule of N 2 has 14 neutrons (Mass Number = 14, Atomic
Number = 7. So, 14 - 7 = 7)
So, 1.5 1023 molecules have 14 1.5 1020  211020 neutrons.
12
67. 14 gm of C -14 (gram atomic weight) has 6 1023 atoms.
4
0.007 gm (= 7mg) of C-14 has  r 3 atoms.
3
Each atom of C-14 has 8 neutrons (14 – 6 = 8)
So, 31020 atoms have 24 1020 neutrons.
Each neutron weighs = 1 amu
So, 24 1020 neutrons weigh 24 1020 1  24 1020 amu.
68. A CO32- ion has one C-atom, 3 O-atoms and 2 extra electrons as
the ion carries 2-charge.
So, the total number of electrons is 6+ (3 x 8) + 2 = 32 electrons.
69. One mole of CO2 at NTP occupies 22.4l So, 2.5 moles of CO2 at
NTP occupy 2.5  22.4  56l .
70. One mole of N 2 at NTP occupies 22.4l So, 0.5 moles of N 2 at

NTP occupies 0.5  22.4  11.2l.
71. 32 gm of oxygen (gram molecular weight) is equivalent to 1 mole

So, 40 gm of oxygen has 40 / 32 = 1.25 moles.
1 mole of oxygen has 6.0231023 molecules of oxygen
So, 1.25 moles have 1.25×6.023×1023 =7.52×1023 molecules.
72. 1 gram atom of Carbon weighs 12 gm

So, 0.4 gm atoms weighs 4.8 gm.
73. 100 gm of rock has 42.6 gm of Ca 3  PO 4 2
13
So, 5000 gm (= 5 kg) of rock has (42.6 x 5000) / 100 = 2130 gm
of Ca 3  PO 4 2 .
310 gm [(3 x 40) + 2 x (31 + 64)] is the gram molecular weight of
Ca 3  PO 4 2 .
310 gm of Ca 3  PO 4 2 is equivalent to 1 mole of Ca 3  PO 4 2
So, 2130 gm of Ca 3  PO 4 2 has 2130 / 310 = 6.87 moles of
Ca 3  PO 4 2 .
74. 1 mole of CO2 has 12 gm of Carbon (wt of one gm atom) and 32

gm of oxygen (wt of 2 gm atoms).
So, 3 moles of CO2 have 36 gm of Carbon and 96 gm of oxygen.
75. 6 1023 molecules of NO2 at NTP occupies 22.4l

So, 1.5 1022 molecules of NO2 at NTP occupies
22.4 1.5 1023
 0.56l
6 10h23
76. 6.0231023 molecules of NO weighs 30 gm (gm mol wt = 14 +

16)
So, 1024 molecules of NO weigh 0.498 gm.
77. 12 gm of carbon (gm atomic weight) has N atoms of Carbon

(Avogadro Number) So, 3 gm of carbon has N/4 atoms of carbon.
N atoms are present in 40 gm of Ca (gm atomic weight)
So, N/4 atoms of Ca weigh 10 gm of Ca.
14
78. 22.4l of CO2 at NTP has 6 1023 molecules of CO2
So, 5.61 of CO2 has 1.5 1023 molecules of CO2
16 1023 of Nitrogen weighs 28 gm (gm molecular weight of N 2 )
So, 1.5 1023 molecules of nitrogen weigh 7gm.
79. 6.0231023 atoms of Carbon weigh 12 gm (gm atomic weight)

So, 1 atom of Carbon weighs 1.99 1023 gm.
80. 6.0231023 molecules of oxygen weigh 18 gm (gm molecular

weight)
So, 1 molecule of water weighs 2.99 1023 gm.
Assuming inter particle space to be negligible in volume, since
density is 1 gm /cc
Volume occupied by one molecule is 2.99 1023 ml.
81. 0.05cc of water weighs 0.05 gm.

18 gm has 6 1023 molecules of water
So, 0.05 gm has 1.67 1021 molecules of water.
82. Option p: p has 3 2.4 10207.2  1020  0.072 1022 atoms.

Option q: For q the calculation of number of atoms is as follows.
22400 ml of SO 2 has 6 1023 molecules of SO 2 at STP
So, 11200 ml of SO 2 has 31023 molecules of SO 2 at STP 1
molecule of SO 2 has 3 atoms
So, 31023 molecules has 9 1023 = 90 1022 atoms q has 90 1022
15
atoms
Option r: For r the calculation of number of atoms is as follows.
1 gm atom of argon has 6 1023 atoms
So, 3 gm atoms of argon have 18 1023 = 180 1022 atoms.
r has 180 1022 atoms
Options: For s the calculation of number of atoms is as follows.
1 mole of H2SO4 has 6 1023 molecules of H2SO4
1 molecules of H2SO4 has 7 atoms
So, 6 1023 molecules have 42 1023  420 1022 atoms
r has  420 1022 atoms.
Arranging in increasing order of number of atoms we get s > r > q
> p.
83. Do the sum using mole concept to calculate the four volumes in a
similar method as shown in question number 33.
84. The number of gm atoms in one gm molecule of SO 2 is 3. One

gm molecule weighs one gram molecular weight (Statement 2) and
is made up of is made up of 1 gram atom.
85. Equal volumes occupied by different gases will have the same
number of molecules only if the conditions of temperature and
pressure are the same. Statement 2 is correct as per mole concept.
86. The number of moles is obtained by dividing weight by molecular

weight as given in Statement 2. Since masses are same, the ratio of
number of moles will be M1 / M 2 .
16
87. Same argument as question number 38 applies - only the number
of moles is same. Statement 2 is false as weight is related to
molecular weight as follows: weight of gas = number of moles x
molecular weight.
88. As atomicity (number of atoms in one molecule of an element) of

Helium is 1 (Statement 2), the number gm atoms ( = one) in one
mole of Helium will be numerically equal to number of gram
molecules ( = 1) in one mole of CO2 .
89. The number of gram atoms in 1 mole of CaCO3 is 5 (1 gm atom

of Ca + 1 gm atom of C + 3 gm, atoms of 0). So Statement 1 is
incorrect. Statement 2 is correct as 100 gm is the gm molecular
weight obtained by adding the gm atomic weights of all atoms.
90. The volume occupied by half mole of SO2 at STP is 11.2l. The
volume occupied by 1 gm (half a gram molecule) of Hydrogen at
STP is also 11.2l. So, Statement 1 is correct, as Gram Molar
Volume of all gases is same (Statement-2).
91. Atomicity of hydrogen is two, as two atoms of hydrogen comprised

a molecule of hydrogen. The number of atoms in a molecule
depends on valence configuration. Statement 2 is not correct as
weight of 1 gram molecule of hydrogen is 2 gm and not the weight
of one molecule of .hydrogen.
92. The gram atomic weight (not the atomic weight) of carbon is 12
gm. Statement 2 is correct.
17
93. 1 mole of hydrogen has 6 1023 molecules Assuming each molecule
4
to be a sphere of radius 1A°, whose volume is given by  r 3
3
24
Volume of each molecule is 4.17 10 cc.
Thus, volume of all 6 1023 molecules is 2.516 cc.
The percentage of actual volume occupied at STP by 1 mole of
hydrogen which is 22400 ml, is therefore 0.01 to 0.02%.
94. One mole of Hydrogen has 6 1023 molecules or 12 1023 atoms

(as each hydrogen molecule has two atoms).
95. As half a mole of hydrogen has half the number of molecules the
actual volume occupied will be 11200 ml at STR The physical
volume of all these molecules to the actual volume will be the
same as calculated in question number 46.
Hence C is the correct option is C.
96. The volume of hydrogen molecule is 3.7331022 cc. (More

accurate values of Avogadro Number is 6.0231023 and gram
molar volume is 22414 ml at STE These values are taken while
calculating the volume).
97. 6 1023 molecules of hydrogen weigh 2gm (gram molecular

weight) So, 1 molecule of hydrogen weighs
3.33 1024 gm  2 1.66 1024 gm  2 amu.
18
98.
99.
100.
101.
102.
103.
19
104.
105.
106.
107.
108.
20
109.
110.
111.
112.
113.
21

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This section contains multiple choice questions.

Each question has 4 choices (a),

1. Which property of an element is a whole number

5. The ratio of weights of Hydrogen and Oxygen in H2O2 is:

(a) 8:1 (b) 1:8 (c) 1:9 (d) 1:16

(c)  NH4 3 Fe CN 6  (d) NH4 Fe CN 6 

17. A balanced chemical equation supports

(a) carbonate (b) formate (c) oxalate (d) acetate

r) 3 gm, atoms of Ar s) 1 mole of H2SO4

(a) s>r>q>p (b) p>q>r>s (c) s=r=q=p (d) p>r>s>q

r) 0.2 gm atoms of O2 s) 1.5  1022 molecules of H2

(a) p>q>s>s (b) p<q<s<s (c) s<p<r<q (d) s>p>r>q

(a) one (b) 181 (c) 6 (d) 6  10 23

(a) 1:2 (b) 2:1 (c) 1:1 (d) 1:3

(a) 1:2 (b) 2:1 (c) 1:1 (d) 1:3

(a) 145 (b) 345 (c) 245 (d) 100

(a) 4 (b) 3 (c) 2 (d) 1

(a) 12  10 (b) 12  10 24 (c) 12  10 (d) 12  10 21

(a) 13.2  10 amu (b) 13.2  1023

(c) 5) amu 13.2  1024 amu (d) 5) 13.2  1023 mg

(a) 2.1 10 (b) 0.21 1020 (c) 210  10 20 (d) 21 10 20

42. The total mass of neutrons in amu in 7 mg of carbon 14 is:

(a) 32 (b) 64 (c) 60 (d) 62

(a) 5.6l (b) 0.56 l (c) 0.0056 l (d) 56 l

(a) 0.112 l (b) 1.12 l (c) 11.2 l (d) 112 l

(a) 1.25,75.2  10 (b) 1.25,7.52  1023

(c) 12.5,7.52  1023 (d) 0.125,7.52 1023

48. A Phosphate rock contains 42.6% Ca 3  PO4 2 by wt. The number of

moles of Ca 3  PO4 2 present in 5 kg of rock is:

(a) 687 (b) 6.87 (c) 68.7 (d) 0.687

(a) 0.56 l (b) 5.6 l (c) 56 l (d) 560 l

(a) 0.7 (b) 70 (c) 7 (d) 700

(c) 19.9  1023 gm (d) 199  1023 gm

55. The volume im ml of 1 molecule of water assuming density of water is

p) SO3  SO4 2 2.4  1020 molecules of O3

q) 11,200 ml of SO2 at STP

(a) s> r>q>p (b) s<r<q<p (c) s=r=q=p (d) s<r<q<p

r) 0.2 gm atoms of oxygens s) 1.5  1022 molecules of H2

(a) s> p>r>q (b) s<p<r<q (c) s=p=r=q (d) s>r>q>p

59. STATEMENT-1: Atomic Number is a non-zero positive whole number.

the formula of calcium sulphate is Ca2  SO4 2

of molecules under similar conditions.

Carbon and 48 gms Oxygen.

same as the volume occupied by 1 gram of H2 at STP.

This section contains paragraphs. Based upon each paragraph multiple

Paragraph for questions 41 to 44

83. The Molecular Weight divided by Empirical Weight is always a

Paragraph for questions 85 to 87

Paragraph for question 88 to 92

Paragraph for question 93 to 97

This section contains Matrix-Match type questions. Each question contains

(b) N2O (q) 64

(c) SO2 (r) 44

(d) NH2CONH2 (s) 18

(a) divalent cation (p) Al 3 

(c) a trivalent radical (r) ZnO22

(d) a trivalent ion (s) PO43

(a)  NH4 2 CO3 (p) Ammonium oxalate

(b) HCOONH4 (q) Ammonium acetate

(c)  NH 4 2 C2O4 (r) Ammonium formate

(d) CH3COONH4 (s) Ammonium carbonate

(b) Marsh gas (q) CCl3 .NO2

(c) Laughing gas (r) CO.Cl 2