Safety Data Sheet

Videojet®
Make-Up Fluid
V731-D
Page : 1 / 10
Version : GHS (US) ENGLISH
Version number : 3
Date of issue/ Date of revision : 1/30/2022
Date of previous issue : 4/9/2021 (2.00)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : V731-D
CAS number : Not applicable.

1.2 Relevant identified uses of the substance or mixture and uses advised against
Material uses : Industrial applications: Make-Up fluid for use in a continuous ink jet process.
Replaces solvents lost through evaporation during normal ink drop recycling
process.

1.3 Details of the supplier of the safety data sheet

Website: www.videojet.com
Email: [email protected]

Videojet Technologies Inc., 1500 Mittel Boulevard, Wood Dale, IL, 60191-1073 U.S.A
Tel: 1-800-843-3610 Fax: 1-800-582-1343

1.4 Emergency telephone number

Medical 3E: (US) +1 866 519 4752
3E Code: 334466
Transporters CHEMTREC: (US) +1 800 424 9300
CHEMTREC Code: CCN 23846
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
GHS Classification
1) FLAMMABLE LIQUIDS - Category 2 Highly flammable liquid and vapor.
2) SKIN IRRITATION - Category 2 Causes skin irritation.
3) EYE IRRITATION - Category 2A Causes serious eye irritation.

Ingredients of unknown : Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 0%.
toxicity
Ingredients of unknown : Percentage of the mixture consisting of ingredient(s) of unknown hazards to the
ecotoxicity aquatic environment: 0%.

2.2 Label elements

GHS label elements

Danger. Highly flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. Harmful to
aquatic life. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
V731-D GHS (US) ENGLISH Version: 3 Page: 2/10

2.3 Other hazards

Other hazards which do : None known.
not result in classification
Additional guidance : Wear eye or face protection. Wear protective gloves. Avoid release to the
environment. If eye irritation persists: Get medical attention. Keep container tightly
closed.

SECTION 3: Composition/information on ingredients

Substance/mixture : Mixture
Product/ingredient name CAS # % GHS Classification
1) ethanol 64-17-5 85 - <95 FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
2) ammonia 1336-21-6 1 - <3 SKIN CORROSION/IRRITATION - Category 1B
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
AQUATIC HAZARD (ACUTE) - Category 1

Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband. In case of inhalation of
decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
V731-D GHS (US) ENGLISH Version: 3 Page: 3/10

Skin contact : Adverse symptoms may include the following:

irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Treat symptomatically. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion
substance or mixture hazard. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
V731-D GHS (US) ENGLISH Version: 3 Page: 4/10

Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

6.4 Reference to other sections

See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste
treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values

1) ethanol OSHA PEL 1989 (United States, 3/1989).

TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
OSHA PEL (United States, 5/2018).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
2) ammonia OSHA PEL 1989 (United States, 3/1989).
STEL: 35 ppm 15 minutes.
STEL: 27 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 50 ppm 8 hours.
TWA: 35 mg/m³ 8 hours.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring
standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.
V731-D GHS (US) ENGLISH Version: 3 Page: 5/10

8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Hand protection : Recommended: EN374 A
May be used (Short term exposure): Latex gloves. Nitrile gloves. Use gloves only
once. Gloves should be replaced regularly and if there is any sign of damage to the
glove material. The user must check that the final choice of type of glove selected
for handling this product is the most appropriate and takes into account the
particular conditions of use, as included in the user's risk assessment.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Recommended: organic vapor filter (Type A), ammonia filter (Type K)
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Liquid.
Color : Clear.
Odor : Not available.
Odor threshold : Highest known value: 100 ppm. Weighted average: 97 ppm.
pH : Not applicable.
Melting point/freezing : May start to solidify at the following temperature: 0 °C. Weighted average: -104 °C.
point
Initial boiling point and : Lowest known value: 38 °C. Weighted average: 78 °C.
boiling range
Flash point : 17 °C.
Evaporation rate (butyl : Highest known value: 1.7. Weighted average: 1.6.
acetate = 1)
Flammability (solid, gas) : Not applicable. ( Liquid )
Upper/lower flammability : Lowest known value: 3.3%. Highest known value: 25.0%.
or explosive limits
Vapor pressure : Highest known value: 360 mm Hg at 20°C. Weighted average: 49 mm Hg at 20°C.
Vapor density : Lowest known value: <1.6. Highest known value: >1.6. (Air = 1)
Relative density (Water = 1) : 0.81
Solubility(ies) : Not available.
Partition coefficient: n- : Not applicable.
octanol/water
V731-D GHS (US) ENGLISH Version: 3 Page: 6/10

Auto-ignition temperature : Lowest known value: 455 °C. Weighted average: 460 °C.
Decomposition : Thermally stable.
temperature
Viscosity : Not available.
Explosive properties : Not applicable. Not classified.
Oxidizing properties : Not applicable. Not classified.

9.2 Other information

Volatility (w/w) : 99 %.
VOC Volatility (w/w) : 93 %.

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.

10.5 Incompatible materials

Reactive or incompatible with the following materials:
oxidizing materials

10.6 Hazardous decomposition products

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ethanol LC50 Inhalation Vapor Rat >117 mg/l 4 hours
LD50 Dermal Rabbit >15800 mg/kg -
LD50 Oral Rat 10470 mg/kg -
ammonia LD50 Oral Rat 350 mg/kg -

Conclusion/Summary : Not classified. No known significant effects or critical hazards.

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
ethanol Skin - Primary dermal Rabbit 0 4 hours 14 days
irritation index (PDII)
Eyes - Irritant Rabbit - - 21 days

Conclusion/Summary
Skin : Causes skin irritation.
Eyes : Causes serious eye irritation.
Respiratory : Not classified. No known significant effects or critical hazards.
Sensitization
V731-D GHS (US) ENGLISH Version: 3 Page: 7/10

Product/ingredient name Route of exposure Species Result

ethanol skin Mouse Not sensitizing
Respiratory Rat Not sensitizing

Conclusion/Summary
Skin : Not classified. No known significant effects or critical hazards.
Respiratory : Not classified. No known significant effects or critical hazards.
Mutagenicity
Product/ingredient name Test Experiment Result
ethanol OECD 474 Experiment: In vivo Negative
Subject: Mammalian-Animal
OECD 474 Experiment: In vivo Negative
Subject: Mammalian-Animal

Conclusion/Summary : Not classified. No known significant effects or critical hazards.

Carcinogenicity
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Reproductive toxicity
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of exposure Target organs
ammonia Category 3 - Respiratory tract irritation

Specific target organ toxicity (repeated exposure)

Product/ingredient name Category Route of exposure Target organs
Not classified. No known significant effects or critical hazards.

Aspiration hazard
Conclusion/Summary : Not classified. No known significant effects or critical hazards.
Potential chronic health effects, Other
Product/ingredient name Result Species Dose Exposure
ethanol Sub-chronic NOAEL Oral Rat 1730 mg/kg 90 days
Conclusion/Summary : No known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
ethanol Acute EC50 275 mg/l Fresh water Algae - Chlorella vulgaris 72 hours
Acute LC50 5012 mg/l Fresh water Daphnia - Ceriodaphnia dubia 48 hours
Acute LC50 11200 mg/l Fresh water Fish - oncorhynchus mykiss 24 hours
Chronic EC10 11.5 mg/l Fresh water Algae - Chlorella vulgaris 72 hours
Chronic NOEC 79 mg/l Marine water Crustaceans - Palaemonetes pugio 12 days
Chronic NOEC 9.6 mg/l Daphnia - daphnia magna 10 days
Chronic NOEC 250 mg/l Fresh water Fish - Danio rerio - Embryo 120 hours

12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
Not available.

Product/ingredient name Aquatic half-life Photolysis Biodegradability

ethanol - - Readily
ammonia - - Readily

12.3 Bioaccumulative potential

V731-D GHS (US) ENGLISH Version: 3 Page: 8/10

Product/ingredient name LogPow BCF Potential

ethanol -0.35 - low

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.
Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : None.

SECTION 14: Transport information

UN IMDG IATA US DOT

14.1 UN number UN1170 UN1170 UN1170 UN1170

14.2 UN proper Ethanol solution Ethanol solution Ethanol solution Ethanol solution
shipping name

14.3 Transport hazard 3 3 3 3

class(es)

14.4 Packing group II II II II

14.5 Environmental No. No. No. No.

hazards

Additional information - Emergency schedules 3-06 - -

14.6 Special precautions for user

No special measures required.

14.7 Transport in bulk according to IMO instruments

Not available.
V731-D GHS (US) ENGLISH Version: 3 Page: 9/10

SECTION 15: Regulatory information

CERCLA: Hazardous : The following components are listed: ammonia (1 - <3%)
substances.
SARA 313 : The following components are listed: ammonia (1 - <3%)
California Prop. 65 : This product contains a chemical or chemicals known to the state of California to
cause cancer. The following components are listed: acetaldehyde (<0.01%). This
product contains a chemical or chemicals known to the state of California to cause
birth defects or other reproductive harm. The following components are listed:
methanol (<0.1%).
National Fire Protection : Flammability
Association (U.S.A.) 3
Health 1 0 Reactivity

special hazard
Tariff Code - harmonized : 3814.00 Organic composite solvents and thinners, not elsewhere specified or
system included.
USA ...50.90
EU ...90.99
Heavy Metals : Total concentration: Pb, Hg, Cd, Cr(VI) < 100 ppm
California, VOC Content : 809 grams volatile organic / liter less water or exempt volatile.
Chemical Weapons Convention List Chemical Weapons Convention List Chemical Weapons Convention List
Schedule I Chemicals Schedule II Chemicals Schedule III Chemicals

Not listed Not listed Not listed

SECTION 16: Other information

Revision comments : Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
acronyms GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the
Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Procedure used to derive the classification
Classification Justification
FLAMMABLE LIQUIDS - Category 2 On basis of test data
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination
of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with
caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
V731-D GHS (US) ENGLISH Version: 3 Page: 10/10