A Reconfigurable Terahertz Metamaterial Absorber For Gas Sensing Applications
A Reconfigurable Terahertz Metamaterial Absorber For Gas Sensing Applications
Article
A Reconfigurable Terahertz
Metamaterial Absorber for
Gas Sensing Applications
Shruti, Sasmita Pahadsingh, Bhargav Appasani, Avireni Srinivasulu, Nicu Bizon and
Phatiphat Thounthong
Special Issue
Active, Tunable and Reconfigurable Elastic Metamaterials
Edited by
Dr. Kuo-Chih Chuang, Dr. Yanfeng Wang and Dr. Yongquan Liu
https://doi.org/10.3390/cryst13020158
crystals
Article
A Reconfigurable Terahertz Metamaterial Absorber for Gas
Sensing Applications
Shruti 1 , Sasmita Pahadsingh 1 , Bhargav Appasani 1, *, Avireni Srinivasulu 2 , Nicu Bizon 3,4,5, *
and Phatiphat Thounthong 6,7
The content of this research work is categorized into five sections which are as follows:
Section 2 elaborates the design concept of the proposed MA along with its absorption
characteristics followed by the description of the absorption mechanism Section 3. Section 4
illustrates the results and discussion along with the gas detection capability. Section 5
includes the conclusion of the work.
Concentric circular and square resonators are widely used to achieve good resonance
with a high absorption rate. In this work, concentric square resonators were modified to
U-shaped structures and it was observed that this pattern gives a very high absorption rate
as well as high sensitivity.
where A is the absorption coefficient, S11 is the reflection coefficient and S21 is transmission
coefficient. The bottom ground plane has been taken sufficiently thick to prevent the
transmission of electromagnetic waves, i.e., S21 = 0. So the above equation reduces to:
A = 1− | S11 |2 (2)
Crystals 2023, 13, 158 4 of 15
The Finite Element Method (FEM) is used to simulate this proposed unit cell of MA
and periodic boundary conditions along x and y axis and the wave source is plane EM wave
along the z direction was used in commercially available CST software. The absorption
characteristics are shown in Figure 2. It can be observed that this proposed THz MA shows
one narrow peak at 3.045 THz with a high absorption rate of 99.75%. The full width half
maximum (FWHM) of this proposed structure is found to be 0.035 THz which indicates a
strong frequency selectivity due to narrow bandwidth. Quality factor (Q-factor) is defined
as Q = Resonance frequency/FWHM which is calculated to be 87 which is quite high for
sensing applications.
To show the accuracy of the FEM method, the structure proposed in [21] is simulated
using FEM and its results are compared as shown in Figure 3. There is a high similarity
between the proposed method and that simulated in [21]. Thus, the proposed method gives
accurate results.
Figure 3. Comparison between the absorptions of the metamaterial absorber reported in [21] and
our work.
were decided after performing the parametric analysis. The parametric analysis of the
proposed structure is carried out with respect to the width (w) of the U-shaped strips,
the height of the substrate (t2 ), periodicity (p) of the unit cell, and gap (g) between the
U-shaped strips. Parametric analysis was conducted by varying the different values of these
parameters and the optimum values were chosen to obtain the best results. Figure 4 shows
the variation of absorptivity with the width (w) of U-shaped strips. It can be concluded
that the absorption peak gets shifted left by increasing the width from 2 µm to 6 µm, i.e., by
increasing the width of the strips we will obtain the peak at a lower frequency. We have
chosen the optimum value of width as 4 µm because it results in a higher absorption rate
as well as narrow-band as compared to other values.
Figure 5 shows the variation of the absorptivity with the thickness of the substrate (t2 ).
From this plot, it can be seen that the absorption peak shifted to a lower frequency with
the increasing height of the substrate from 6 µm to 9 µm. The thickness of the dielectric
substrate is responsible for the resonance effect, i.e., it traps the electromagnetic radiation
and dissipates it as dielectric losses. The optimum value of t2 is 7 µm as we obtain the
maximum absorption rate. At t2 = 6 µm, the peak is narrow, but the absorption rate is low.
So the thickness t2 is 7 µm.
Figure 6 shows the variation of absorptivity with the periodicity (p) of the unit cell.
By increasing the periodicity of the unit cell from 170 µm to 200 µm, the absorption band is
shifted to a lower frequency as the frequency is inversely proportional to the wavelength.
The periodicity of the unit cell is taken as 180 µm as it results in a higher absorption rate
compared to other values. The width of all the absorption bands is almost the same at all
the values of periodicity. Figure 7 shows the variation of absorption rate with the gap (g)
between the U-shaped strips. The optimum value of the gap is chosen as 10 µm as there is
a maximum absorption compared to other values.
Crystals 2023, 13, 158 6 of 15
Figure 6. Absorption spectra obtained by varying the periodicity of the unit cell.
The absorption peak of the proposed design does not shift with the polarization angle.
This can be seen in Figure 8.
Figure 7. Absorption spectra obtained by varying the gap between the U-shaped strips.
Figure 9. Process flow: (1) and (2) are the photolithography to define the metamaterial geometry,
while (3) and (4) show the wet etching and washing of the photoresist to fabricate the metamaterial
structures, and (5) is the evaporation of metallic substrate layer on another side of the polyimide layer.
Crystals 2023, 13, 158 8 of 15
1
fo = √ (9)
2π LC
The circuit parameters are taken as L = 0.8 nH, C = 0.0035 fF, and R = 800 Ohm.
The value of R is chosen so that the bandwidth of the equivalent circuit matches that of
the proposed design. The equivalent circuit response is shown in Figure 13, along with
the result of FEM. The mechanism behind the absorption is that the impedance of the free
space (≈377 Ω) should match the impedance of the equivalent circuit model. The total
impedance of the circuit model (ZTotal ) can be calculated as:
1
ZTotal = ( R||( jωL + ) + Z )|| Z (10)
jωC
Figure 13. Comparison of Equivalent circuit and FEM method of the proposed absorber.
respect to the refractive index. The sensitivity of this proposed MA is calculated by using
the following equation:
∆f
S= (11)
∆n
where ∆ f is the frequency shift and ∆n is the change in refractive index. From the plot,
it can be clearly seen that the sensitivity is 3.01 THz/RIU which is the slope of the curve.
Q-factor and FoM were calculated using the equations:
fr
Q= (12)
FW HM
S
FoM = (13)
FW HM
where f r is the resonance frequency and S is the sensitivity. The Q-factor and FoM were
found to be 87 and 86, respectively, which is suitable for the sensor. Since the sensitivity is
high so it can be widely used for sensing applications. The linear relationship between the
resonance frequency ( f r ) and the refractive index (n) is obtained using curve fitting and is
given by the equation.
f = −3.01071n + 6.05495 (14)
Figure 15. Absorption spectra as a function of the refractive index of the surrounding medium.
Figure 16. The position of the peak as a function of the refractive index of the surrounding medium.
Crystals 2023, 13, 158 12 of 15
Figure 17. Absorption vs Frequency for carbon monoxide, chlorine, chloroform, methane, carbon
dioxide, and helium.
Table 2 compares the performance of this proposed RI sensor with those in the liter-
ature in terms of various parameters. We can observe from the table that this proposed
design has some advantages over those reported in the literature, such as high absorption
rate, high sensitivity, and high performance.
Crystals 2023, 13, 158 13 of 15
Table 2. Comparison of the proposed structure with those reported in the literature.
Resonance
Range Absorption Gas Eq.
Design Frequency Sensitivity FWHM (THz) FoM
of R.I Rate Detection ckt
(THz)
Ref. [35] 1 to 1.39 99% 2.249 23.7 GHz/µm 0.102 2.94 No No
Ref. [36] 1 to 1.8 99.8% 1.8 187.5 GHz/RIU - 223 No No
Ref. [37] 1 to 1.8 99.6% 2.26 360 GHz/RIU - 431 No No
0.119 THz/RIU,
Ref. [38] 1 to 2 - 0.64, 1.94, 2.67 0.248 THz/RIU, - - No No
0.662 THz/RIU
Ref. [39] 1.2 to 2 96.4% - 34.40% RIU−1 - 19.35 No No
Ref. [31] 1 to 1.8 - 0.6376 163 GHz/RIU 0.061 2.67 No No
Ref. [40] 1 to 1.08 99.3% 3.62 and 3.814 3 and 3.59 THz/RIU 0.07 and 0.0027 1329.63 Yes No
Proposed 1.000 to
99.75% 3.045 3.01 THz/RIU 0.035 86 Yes Yes
Work 1.030
5. Conclusions
In summary, a highly sensitive refractive index reconfigurable terahertz metamaterial
absorber is designed to sense the refractive index of toxic gases whose refractive index
varies from 1.00 to 1.03. Using numerical simulations based on the finite element method,
we demonstrated that the absorption rate is 99.75% at the resonance frequency of 3.045 THz.
The proposed structure was also verified through its equivalent circuit model and the
results are in good agreement with the simulated ones. Since the FWHM is 0.035 THz with
high sensitivity of 3.01 THz/RIU and Q-factor of 87, this absorber can be widely used as
a refractive index sensor of toxic gases. The structure is symmetrical in the y-direction
so it is polarization insensitive up to an incidence angle of 60°. The parametric analysis
was also studied and the optimum values of all the design parameters were chosen for the
maximum absorption rate.
Author Contributions: Conceptualization, S., S.P. and B.A.; methodology, B.A.; software, S. and S.P.;
validation, B.A. and A.S.; investigation, S., S.P. and B.A.; resources, N.B., P.T. and B.A.; data curation,
B.A., A.S. and P.T.; writing—original draft preparation, S., S.P. and B.A.; supervision, B.A. and N.B.;
project administration, B.A. and N.B.; formal analysis: N.B. and P.T.; funding acquisition: N.B. and
P.T.; visualization: B.A., N.B. and P.T.; writing—review and editing: N.B., P.T. and B.A. All authors
have read and agreed to the published version of the manuscript.
Funding: This work was supported in part by the Framework Agreement between University of
Pitesti (Romania) and King Mongkut’s University of Technology North Bangkok (Thailand), in part
by an International Research Partnership “Electrical Engineering—Thai French Research Center (EE-
TFRC)” under the project framework of the Lorraine Université d’Excellence (LUE) in cooperation
between Université de Lorraine and King Mongkut’s University of Technology North Bangkok,
and in part by the National Research Council of Thailand (NRCT) under Senior Research Scholar
Program under Grant No. N42A640328.
Data Availability Statement: Not applicable.
Conflicts of Interest: The authors declare no conflict of interest.
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