MT Electrods
MT Electrods
Plug & Play means reliability With the comprehensive range of Plug & Play pH, platinum and silver titration sensors, any application challenge can be overcome. The Sensor Chip in the sensor head stores data such as sensor type, serial number, calibration data and usable life, which is automatically read out to the titrator setup when connected. That ensures, without any action on the part of the operator, that only the correct sensor with the specific, valid data is used.
Enormous capabilities METTLER TOLEDO has been a source of skills and expertise for the production of a vast range of titration sensors capable of meeting the specific analytical requirements of every industry for over 40 years.
Precision and reliability Alongside experienced craftsmanship, maximum utility of automated production methods ensures the consistently high quality expected of the sensors.
Guaranteed quality No sensor leaves the production facility untested. Only on successful completion of the final check do the sensors receive their individual quality certificates ready for dispatch. Strict guidelines regarding the slope or membrane glass resistance of the pH sensors guarantee ultimate performance.
Smart design A clean diaphragm is a fundamental requirement for precise measurements. It is the interface between the reference system and the sample. If it is clogged with precipitation deposits, precise measurement cannot be guaranteed. The METTLER TOLEDO ARGENTHAL Ag/AgCl reference system with silver-ion trap keeps the reference electrolyte completely free of silver ions, preventing precipitation with sulfide, protein or TRIS buffer containing solutions.
Applications
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Chemical
Precise sulfuric acid content using the pH sensor DGi111-SC The precise determination of sulfuric acid concentration is of major significance not only for the chemical industry but for others too, as small differences can sometimes have serious consequences for product characteristics. A titration system consisting of T70 Excellence titrator, Rondo 20 sample changer and DGi111-SC pH sensor enables automated detection of 9% sulfuric acid concentration with a deviation of only 0.01% and an outstanding repeatability of only 0.05% in 6 sample series. Ultimate precision in routine analysis.
Pharmaceutical
Clotrimazole titration in acetic acid using the pH sensor DGi113-SC Important pharmaceuticals such as clotrimazole have to be titrated directly in non-aqueous solvents due to their low acidic strength. In accordance with the requirements of the European approved drugs list and USP, pure acetic acid is used as the solvent and perchloric acid as the titrant. The outstanding chemical stability and ease of regeneration of the DGi113-SCs pH glass membrane guarantee the required durability under such demanding conditions. The high electrolyte flow from the moving plastic sleeve is essential for rapid response and stability of the sensor signal. The DGi113-SC has all the attributes required for precise results in non-aqueous titration applications.
Water
Chloride titration in drinking water using the silver ring sensor DMi141-SC Chloride in water can occur naturally (e.g. mineral solutions such as brine) but can also be the result of contamination by fertilizer or waste water. Among other things, a high chloride content has a destructive effect on concrete and ferrous metals. With the DMi141-SC, chloride in water can be titrated with excellent repeatability (relative standard deviation < 0.5%) over a range of concentrations from 15 ppm to 1% using the appropiate concentration of silver nitrate titrant.
Beverages
Determining the pH and acidity of wine using the pH sensor DGi115-SC The pH and acidity of wine are essential parameters for assessing its quality. Laboratories have to analyze large numbers of wine samples for these two variables on a daily basis. A T70 and Rondo 20 sample changer with the DGi115-SC provide the means for mastering the task as precisely and efficiently as possible.
Electroplating
Automated nickel and hypophosphite titration using the DP5 Phototrode and platinum ring sensor DMi140-SC Tribological coatings for the automotive industry consist of metal or metal oxides electroplated or anodized from aqueous solutions. For quality assurance, the baths have to be checked every day. Nickel and hypophosphite/ orthophosphite are titrated in electroless nickel baths using the DP5 and the DMi140-SC, respectively. The two titrations are handled by two Rondo 20 sample changers that are controlled by a T90 Excellence titrator. At least 70 samples a day can be analyzed very efficiently and reliably.
Chemical
Mobility means flexibility The movable sleeve holder enables individual positioning of the sensor in the manual titration vessel or on the Rondo or Rondolino sample changer. That means that smaller sample volumes can be titrated in METTLER TOLEDO standard titration beakers or in Rondo 30 titration beakers.
Simple yet stable reference The KCl-ARGENTHAL system reliably delivers stable sensor signals within a temperature range of 0 to 80 C for the entire life of the sensor. The system is maintenance free and requires only regular filling with 3 M KCl. DGi111-SC
Order number: pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: Classic design: 51109500 0 14 0 80 C HA-taped Ceramic pin Glass ARGENTHAL 3 mol/L KCl S12 (DGi111-SC) S7 (DG111-SC) Plug & Play Sensor Chip 89596 (DG111-SC)
Reliable connection to the outside world A small ceramic pin creates the necessary conditions for slow, even outflow of the electrolyte. If samples with a high sulfide or protein content are avoided, no problems with clogging should be encountered.
Quick stable signals and results The large HA-glass pH membrane has been optimized for rapid response times and stable signals. It delivers reliably repeatable results in aqueous systems.
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Sb850-S7/120
DGi102-Mini
DGi101-SC
DX202-SC
DX202-SC
Order number: Detection range: Temperature range: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: Connection: Detection: 51109295 0 2000 mV 0 80 C Glass fiber Glass fiber Polypropylene Ag/AgCl 3 mol/L KCl 3 mol/L KCl or 1 mol/L KNO3 S7 n/a
Petrochemical
Perfectly shielded The gold shielding on the inner reference provides perfect protection against electrostatic effects. The signal noise is substantially diminished and the result quality significantly improved.
Reliable reference system The LiCl-ARGENTHAL system reliably delivers stable sensor signals within a temperature range of 0 to 60 C for the entire life of the sensor. The system is maintenance free and requires only regular filling with 1 mol/L LiCl in ethanol.
Stable signals and easy cleaning The movable ground glass junction ensures even flow of the electrolyte. The sensor signal stabilizes faster and titrations can be completed in a shorter time. The smooth glass surface prevents oil samples from sticking and considerably simplifies cleaning. DGi116-Solvent
Order number: pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109505 0 12 0 6 0 C A41 spherical Ground glass (moveable) Glass LiCl-ARGENTHAL LiCl, 1 mol/L in ethanol S12 Plug & Play Sensor Chip
Fast response times and durability The large spherical surface area of the glass membrane ensures low membrane resistance and homogeneous distribution of the potential. So, the response time and signal noise are reduced. Due to its chemical stability and easy regeneration, the A41 membrane glass is ideal for non-aqueous titrations in a pH range of 0 to 12.
DMi148-SC
Order number: pH application range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109532 0 14 0 8 0 C Silver ring n/a Glass pH glass membrane n/a S12 Plug & Play Sensor Chip
DG300-SC
DMi148-SC
DX200
DX200
Order number: Detection range: Temperature range: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: 51089935 0 2000 mV 0 80 C Ground glass (moveable) Ceramic pin Glass ARGENTHAL 3 mol/L KCl 3 mol/L KCl 1 mol/L KNO3 1 mol/L LiCl in ethanol 1 m, 4 mm banana n/a
Cable/connection: Detection:
Pharmaceutical/Biotechnology
Secure attachment With the standard glass sleeve holder, the sensor can be easily and securely positioned when fitted in the titration stand.
Maintenance free reference system The DMi147-SC has no diaphragm as the pH glass membrane provides a constant reference potential for the platinum sensor in highly acidic and therefore adequately buffered conditions required for redox titrations. No refilling of electrolyte or cleaning of clogged diaphragms are necessary, adding up to ease-of-use, minimum maintenance and a long service life.
Twice the capabilities The DMi147-SC combines two sensors, making it capable not only of redox titration using the platinum sensor but also of acid-base titration using the pH sensor. In the first case, the pH membrane is the reference, in the second the platinum ring. In both cases, the sample is not contaminated since there is no outflowing electrolyte. The question of the right choice of reference electrolyte is therefore superfluous.
DMi147-SC
Order number: Detection range: pH application range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109522 0 2000 mV 0 14 0 80 C Platinum ring n/a Glass pH glass membrane n/a S12 Plug & Play Sensor Chip
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DGi113-SC
Order number: pH range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: Classic design: 51109502 0 12 0 60 C A41 cylindrical Ground Teflon (moveable) Glass LiCl-ARGENTHAL LiCl, 1 mol/L in ethanol S12 (DGi113-SC) S7 (DG113-SC) Plug & Play Sensor Chip 89632 (DG113-SC)
DGi113-SC
InLab718
Order number: Detection range: Temperature range: Shaft material: Cell constant: Cell type: Temperature sensor: Connection/cable: Detection: 51340266 0.1200 S/cm -5100 C Epoxy Dependent on beaker geometry 2-pole platinum NTC Mini-Din, 1.2 m Presence checking
InLab717
InLab718
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Water
DGi117-Water
Order number: pH application range: Temperature range: Membrane glass type: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: Connection: Detection: 51109506 1 11 0 100 C LoT spherical Ground glass Ceramic pin Glass ARGENTHAL KCl gel 1 mol/L KCl S12 Plug & Play Sensor Chip
DMi144-SC
Order number: Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109521 0 2000 mV 0 80 C Platinum ring Ceramic pin Glass ARGENTHAL 3 mol/L KCl S12 Plug & Play Sensor Chip
DMi102-SC & DMi141-SC Precise Titration from ppm to % Chloride and More
The DMi102-SC and DMi141-SC are silver ring sensors for similar applications, e.g. titrating any ions that form precipitations with silver. This includes all halides (Cl-, Br -, I-), pseudo-halides (CN-, SCN-, ...) and, after prior sulfidizing of the silver ring, sulfides and mercaptans over broad concentration ranges. The DMi141-SC is the generalist, the DMi102-SC is a rugged semimicrosensor for small sample volumes of 10 to 20 mL or for use on the Rondo 30 sample changer. DMi102-SC
Order number: Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109533 0 2000 mV 0 80 C Silver ring Ceramic pin Glass ARGENTHAL 1 mol/L KNO3 S12 Plug & Play Sensor Chip
DMi144-SC
DMi141-SC
Order number: Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: Classic design: 51109530 0 2000 mV 0 80 C Silver ring Ceramic pin Glass ARGENTHAL 1 mol/L KNO3 S12 (DMi141-SC) S7 (DM141-SC) Plug & Play Sensor Chip 89599 (DM141-SC)
Precise ion-selective and conductivity measurements Full details of sodium, ammonia, calcium and other ion-selective sensors as well as the right choice of conductivity sensor for water analysis can be found in the Lab Sensors brochure (order no. 51724332) or at www.mt.com/electrode-guide.
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DMi102-SC
DMi141-SC
Controlled conditions Due to the ARGENTHAL reference system with silver ion trap, the reference electrolyte (3 mol/L KCl) is free of silver ions. There is no danger of food constituents such as sulfides or proteins clogging the diaphragm.
Repeatable precise results The electrolyte flow through the fixed glass junction is constant and guarantees accurate and reproducible pH readings and end point titrations. Food ingredients sticking to the glass surface can be cleaned off easily. DGi115-SC Fast results The HA glass pH membrane features rapid response time, low alkali error and outstanding mechanical durability. It is the right combination for consistently high performance.
Order number: pH application range: Temperature range: Membrane glass type: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: Classic design: 51109504 0 14 0 100 C HA cylindrical Ground glass Glass ARGENTHAL with silver ion trap 3 mol/L KCl S12 (DGi115-SC) S7 (DG115-SC) Plug & Play Sensor Chip 89806 (DG115-SC)
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DM143-SC
Order number: Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51107699 0 2000 mV 0 200 A 0 100 C Double platinum pin n/a Glass n/a n/a S7 n/a
DMi145-SC
Order number: Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109531 0 2000 mV 0 80 C Silver ring Ground Teflon (moveable) Glass ARGENTHAL 1 mol/L KNO3 S12 Plug & Play Sensor Chip
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DP5 Phototrode
Order number: 51109300 inc. region-specific power adaptor (Europe/USA/UK) and cable
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DGi112-Pro
Order number: pH range: Temperature range: Membrane glass type: Ext. diaphragm: Int. diaphragm: Shaft material: Reference system: Int. reference electrolyte: Bridge electrolyte: Connection: Detection: 51109501 0 14 0 60 C HA cylindrical Ground Teflon (moveable) Ceramic pin Glass ARGENTHAL 3 mol/L KCl 1 mol/L KCl 3 mol/L KNO3 S12 Plug & Play Sensor Chip
DMi101-Mini
DMi140-SC
DGi112-Pro
DMi101-Mini
Order number: Detection range: Temperature range: Sensor element: Diaphragm: Shaft material: Reference system: Reference electrolyte: Connection: Detection: 51109523 0 2000 mV 0 80 C Platinum ring Ceramic pin Glass ARGENTHAL 3 mol/L KCl S12 Plug & Play Sensor Chip
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Stable conditions The ARGENTHAL reference system with 3 mol/L KCL electrolyte withstands high temperatures and frequent temperature changes providing a long-lasting and stable reference system.
Simple maintenance The movable diaphragm with its high electrolyte flow enables fast and reproducible potential adjustment and adds to the ease of cleaning and maintenance all in all an optimum design for equivalence point titrations with difficult pulp samples. DGi114-SC
Order number: pH application range: Temperature range: Membrane glass type: Diaphragm: 51109503 0 14 0 60 C HA cylindrical Ground Teflon (moveable) Glass ARGENTHAL 3 mol/L KCl S12 Plug & Play Sensor Chip
Durability for reliable results The outstanding durability of the HA glass membrane makes it perfect for the demanding conditions of acid-base titrations of black, green or white liquors.
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DS500
Order number: pH applic. range: Detection range: Temperature range: Sensor element: Membrane resistance: Shaft material: Reference system: Connection: Detection: Resistant to: 51107670 2 10 <10 5 mol/L to critical micelle concentration 0 50 C Polymer membrane <1 M PVC External reference required S7 n/a Ethanol
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Titration Excellence
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Fully equipped as standard Every Excellence titrator comes with a versatile pH sensor card. There are 2 Plug & Play compatible pH/mV sensor inputs, one of which also features current or voltage polarization, a Pt1000 temperature sensor input and a reference input. This means it has the facility for direct pH or ISE(pX) measurement, pH end point or pH/mV/pX equivalence point titrations as well as amperometric and voltametric titrations. If needed, more sensor cards can be added in the available slots.
Expandable to conductivity With the unique conductivity sensor card, new application possibilities such as conductometric titrations or direct measurements can be easily and reliably done with the full functionality of a modern Excellence titrator there is no need for an extra meter. The conductivity card features automatic detection of the conductivity sensor and an additional Plug & Play pH/mV sensor input.
Ensuring performance capability In order to ensure the performance capabilities of the sensor inputs, they can be periodically adjusted with certified resistors and the test unit. The process is traceable, unambiguously documented, and guarantees identical measurement conditions for all the sensor inputs of a sensor card. A calibrated pH sensor can simply be switched from one input to the other without the need for recalibration.
Automatic chemical detection In addition to the Plug & Play sensors the pH buffers used for sensor calibration are also automatically detected by the titrator. It makes no difference in which order the buffers are measured, saving time and providing certainty.
Efficient method development The intelligent application modes of the titrators make method optimization easy. Just select the titration method and titration speed and the optimum control parameters are automatically set to suit the selected sensor simple and efficient method development.
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Accessories
51343182
51340047
51340234
Useful Accessories
Whether a temperature sensor for temperature-compensated pH measurement or simply wetting caps for correct storage of titration sensors are required, METTLER TOLEDO offers useful accessories.
Accessory DT1000 temperature sensor Wetting caps (minimum order 5 items) Description Pt1000 temperature sensor for temperature-compensation of pH-level readings For sensors with shaft diameter of 12 mm For sensors with ground diaphragm (DGi112-SC, DG(i)113-SC, DGi114-SC, DG(i)115-SC, DGi116-Solvent, DGi117-Water) For sensors with shaft diameter of 8 mm (DGi102-Mini, DMi101-Mini, DMi102-SC) For sensors with shaft diameter of 6 mm (DGi101-SC) Order number 51109828 51340020 51340022 51340021 51340019
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DM143-SC double platinum pin sensor: for this model, classic sensor cables are used, which can also be used with all classic sensors. As with the Plug & Play cables, the signal integrity is protected from interference effects.
Connection S7 grey Cable length (cm) 70 100 160 Lemo Designation Connector Order number 51109183 51109184 51109185
Rainbow I (3x10 sachets of 20 mL 4.01/7.00/9.21) Rainbow II (3x10 sachets of 20 mL 4.01/7.00/10.00) 4.006 pH buffer solutions according to NIST and DIN 19266 6.885 9.180 10.012 4.01 DKD certified buffer solutions Redox buffer solutions E (Ag/AgCl) 25 C 7.00 9.21 10.00 220 mV UH = 427 mV 51340039 51340041 51340042 51340044 52118093 52118094 52118095 52118096 51340065 51319059 51319060 51319061 51319062 51340081
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Applications
Industry
Titration application Acidic and basic solutions Concentrated alkalis Nitrating acids SiO2 and Na2O in water glass Acidity/alkalinity of polyols Chlorine and chlorate in alkalis Chloride in alcohol solutions Identification of indigo and hydrosulphite TAN according to ASTM D664, IP177, EN12634 TBN according to ASTM D4739, IP276, ISO 3771, ASTM D2896 Mercaptans in oils according to ASTM D3227, IP272, ISO 3012 Chloride in crude oil Bromine number according to ASTM D1159, IP130, ISO 3839
Titration type Acid-/base, aqueous, potentio- or conductometric Acid-/base, aqueous Acid-/base, non-aqueous Acid-/base, aqueous Acid-/base, non-aqueous Redox, iodometric Precipitation Redox, iodometric Acid-/base, non-aqueous Acid-/base, non-aqueous Precipitation, non-aqueous Precipitation, non-aqueous Redox, bromatometric Redox, iodometric Conductometric Acid-/base, non-aqueous Redox, iodometric Acid-/base, non-aqueous, potentio- or photometric Acid-/base, non-aqueous potentiometric, conductometric Redox, bromatometric, iodometric, cerimetric Redox, diazotitration Precipitation Precipitation, potentiometric Precipitation, photometric (turbidity) Acid-/base, aqueous Conductivity measurement
Chemical
Petrochemical
Iodine value in biodiesel according to EN14111 Titration of oils according to IP400 Epoxy value of polymers (ASTM D1652, DIN 53188) Peroxide number in oils Acid numb. in B100 biodiesel (EN14104) or E85 bioethanol (ASTM D1613) Pharmaceutical constituents and active ingredients (aspartame, clotrimazole, etc.) Pharmaceutical constituents and active ingredients (phenol, glycerine, ampicillin, vitamin E, etc.)
Pharmaceutical/ Biotechnology
Sulfonamides Halides according to the European Pharmacopoeia and USP Chloride in physiological solutions Non-ionic surfactants in pharmaceutical products Free acids in glycerine according to Pharmacopoeia 5.0 Conductivity of purified water to USP26
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see brochure page 7 7 6 17 18 pH DGi-114-SC DGi115-SC DGi117-Water DG300-SC DGi113-SC DGi116-Solvent DMi101-Mini DMi140-SC Platinum DM144-SC DMi147-SC DM143-SC DMi102-SC DMi141-SC DMi145-SC DMi148-SC DM405-SC 19 DS800-TwoPhase 19 DS500 16 DP5 Phototrode 11 InLab717 11 InLab718 7 Sb850 9 DX200 7 DX202-SC * DX218, 219, 223, 240 * DX264 * InLab710, 731 * InLab720, 741 Surfactant DGi112-Pro DGi111-SC DGi102-Mini DGi101-SC
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Conductivity, directmeasurement
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Applications
Industry
Titration application Acidity/alkalinity of domestic, natural source and rainwater Total hardness of water Chemical oxygen demand (COD) Perborate, percarbonate, persulfate in water Chlorine residues according to ASTM D1253 Chloride in water Ammonia, fluoride, sodium and calcium in water Conductivity of domestic, natural source and rainwater Vitamin C in food and beverages Acid content of fruit/vegetable juices, wine, milk, vinegar Chloride in foods (ketchup, vegetable juices, spices) Free and total sulfur dioxide in wine Reducing sugar according to Rebelein Saponification no. of fats in oil, margarine, butter (DIN 53401) Acid number of oils, margarine, fats Peroxide number of edible oils and fats Anionic/cationic surfactants in coolant/lubricants Nickel in electroless nickel baths Hypophosphite/orthophosphite in electroless nickel baths
Titration type Acid-/base, aqueous Complexometry, photometric and potentiometric Redox, chromatometric Redox, iodometric Redox, arsenometric, amperometric indication Precipitation Direct measurement Conductivity measurement Redox with amperometric or voltametric indication Acid-/base, aqueous Precipitation Redox, iodometric, voltametric indication Redox, iodometric Acid-/base, aqueous Acid-/base, non-aqueous Redox, iodometric Two-phase precipitation (EN14468, 14469, 14480) Complexometry, photometric Redox, iodometric Precipitation Acid-/base, aqueous Redox, iodometric Complexometry, potentiometric Redox, cerimetric Precipitation, single-phase, aqueous Two-phase precipitation (EN14468, 14469, 14480) Precipitation, photometric (turbidity) Acid-/base, non-aqueous Acid-/base, aqueous Precipitation Redox, iodometric Redox, cerimetric Precipitation Complexometry, photometric Acid-/base, aqueous Redox, iodometric
Water
Electronics/electroplating/engineering/ automotive
Free cyanide in zinc baths Acid mixtures in electrolysis baths Cr(VI), Sn(II) in electrolysis baths Cu(II) and Zn(II) in electrolysis baths Hydrogen peroxide Anionic surfactants in liquid detergents Anionic/cationic surfactants in cosmetic products Non-ionic surfactants in raw materials Betaine content in shampoo ABC titration of white and green liquor
Cosmetics
Paper/cellulose, textiles
Silver in alloys Al(III), Fe(III), Ca(II), Mg(II) in cement components (EN196-2) Aldehydes in oil of lemons according to AOAC 955:32 Peroxide number of etheric oils, essences
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see brochure page 7 DGi101-SC DGi102-Mini DGi111-SC DGi112-Pro DGi-114-SC pH DGi115-SC DGi117-Water DG300-SC DGi113-SC DGi116-Solvent DMi101-Mini DMi140-SC DM144-SC DMi147-SC DM143-SC 15 13 DMi102-SC 13 DMi141-SC 15 DMi145-SC 9 DMi148-SC DM405-SC 19 DS800-TwoPhase 19 DS500 16 DP5 Phototrode 11 InLab717 11 InLab718 7 Sb850 9 DX200 7 DX202-SC * DX218, 219, 223, 240 * DX264 * InLab710, 731 * InLab720, 741
7 6 17 18 14 12 9 11 8 17 17 Platinum 13 10 Sensor name Silver Surfactant Color Conductivity, titration Antimony Reference ISE
Conductivity, directmeasurement
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www.mt.com
For more information
Mettler-Toledo AG, Analytical CH-8603 Schwerzenbach, Switzerland Tel. +41 44 806 77 11 Fax +41 44 806 72 40
Environmental management system according to ISO 14001. European conformity. The CE conformity mark provides you with the assurance that our products comply with the EU directives.
Subject to technical changes 02/2012 Mettler-Toledo AG, 51724662A Marketing Titration / MarCom Analytical