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CH 06 Binary Phase
CH 06 Binary Phase
Temperature oc
1200
1150
1100
1050
1000
950
900
10
20
30
40
50
60
70
80
90
100
Percent Glass
Fig. 6-1. From Wright and Okamura, (1977) USGS Prof. Paper, 1004.
Clinopyroxene
Plagioclase
Opaque
1250
Liquidus
note olivine
decreases
below
1175oC
Temperature oC
1200
1150
1100
Melt
Crust
1050
1000
Solidus
950
10 0
10
20
30 40 50 0
10
20
30 40 50 0
10
Fig. 6-2. From Wright and Okamura, (1977) USGS Prof. Paper, 1004.
Olivine
Augite
Plagioclase
Weight % Glass
90
80
70
60
50
.9
.8
.7
Mg / (Mg + Fe)
.9
.8
.7
Mg / (Mg + Fe)
.6 80
70
An
Fig. 6-3. From Wright and Okamura, (1977) USGS Prof. Paper, 1004.
60
= # of phases
phases are mechanically separable constituents
= # of phases
phases are mechanically separable constituents
Graphite Furnace
1 cm
Talc
SAMPLE
Talc
Carbide
Pressure
Vessle
Furnace
Assembly
Fig. 6-5. After Boyd and England (1960), J. Geophys. Res., 65, 741-748. AGU
1 - C Systems
1. The system SiO2
1 - C Systems
2. The system H2O
2 - C Systems
F=2
1. Must specify 2 independent intensive
variables in order to completely determine
the system
= a divariant situation
same as:
liq
liq
Must specify T and X An
or can vary these without
changing the number of phases
F = 2 - 2 + 1 = 1 (univariant)
Must specify only one variable from among:
plag
liq
plag
T X liq
X
X Ab
X Ab (P constant)
An
An
X liq
An
plag
An
and X
are dependent upon T
The slope of the solidus
and liquidus are the
expressions of this
relationship
A continuous reaction
of the type:
liquidA + solidB =
liquidC + solidD
ef
de
liquidus
de
ef
solidus
plag
An
= 0.60
Numbers refer
to the behavior
of melts observations
Fractional crystallization:
Remove crystals as they form so they cant
undergo a continuous reaction with the melt
At any T Xbulk = Xliq due to the removal of the crystals
Partial Melting:
Remove first melt as forms
Melt Xbulk = 0.60 first liquid = g
remove and cool bulk = g final plagioclase = i
Liquid
Plagioclase
plus
Liquid
Plagioclase
Fig. 6-11. Isobaric T-X phase diagram at atmospheric pressure. After Bowen (1915), Amer. J. Sci. 40, 161-185.
Cool composition a:
bulk composition = An70
at 1274oC = 3 so F = 2 - 3 + 1 = 0 invariant
(P) T and the composition of all phases is fixed
Must remain at 1274oC as a discontinuous
reaction proceeds until a phase is lost
#s are listed
points in text
Gabbro of
the
Stillwater
Complex,
Montana
Diabase dike
Also note:
The last melt to crystallize in any binary eutectic
mixture is the eutectic composition
Equilibrium melting is the opposite of equilibrium
crystallization
Thus the first melt of any mixture of Di and An
must be the eutectic composition as well
Fractional crystallization:
Fig. 6-11. Isobaric T-X phase diagram at atmospheric pressure. After Bowen (1915), Amer. J. Sci. 40, 161-185.
Partial Melting:
i = peritectic point
1557oC have colinear Fo-En-liq
geometry indicates a reaction: Fo + liq = En
consumes olivine (and liquid) resorbed textures
When is the reaction finished?
1557
im
k
d
Fo
Bulk X
En
x
i
m
k
1557
1543
c
bulk X
Fo
En
Cr
i
1557
1543
c
bulk X
Fo
En
Cr
Immiscible
Cool X = n
At 1960oC hit solvus
exsolution
2 liquids o and p
=2 F=1
both liquids follow solvus
Crst
Silica-rich
liquid
Liquids
Pressure Effects
Different phases have different compressibilities
Thus P will change Gibbs Free Energy differentially
Raises melting point
Shift eutectic position (and thus X of first melt, etc.)
Effect of PH O on Ab-Or
2
Figure 6-17. The Albite-K-feldspar system at various H2O pressures. (a) and (b) after Bowen and Tuttle (1950), J. Geol, (c) after
Morse (1970) J. Petrol.