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    Organo Metallic S

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    Organo Metallic S

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    Organo Metallic s

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    Organo Metallic S

    Uploaded by

    chudaljisan

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    of 16

    Organometallics

    For Class - XII


    Introduction
    The compounds in which C is bonded to metals like lithium, boron, sodium,
    magnesium copper etc.

    1. Organolithium (RLi)
    2. Organocopper ( R2CuLi)
    3. Grignard Reagent (RMgX)
    4. Organomercury ( R2Hg)
    5. Organocadmium ( R2Cd)
    6. Tetracarbonyl nickel [ Ni(CO)4]
    Nature of metal carbon bond
    Preparation of organometallic compounds
    TRANSMETALLATION
    a type of organometallic reaction that involves the transfer of ligands from one metal to
    another.
    Grignard Reagent
    - Alkyl magnesium halide
    Preparation
    Reactions - a. With carbonyl compound
    Reactions with water
    Reaction with alcohol and ammonia

    RMgX + NH3 ⟶ RH + MgNH2X


    Reactions with HCN
    Reaction with alkyl cyanide
    Reaction with acid halide
    Reaction with ester
    Corey House synthesis

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