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Borate sulfate

From Wikipedia, the free encyclopedia

Borate sulfates are mixed anion compounds containing separate borate and sulfate anions. They are distinct from the borosulfates where the borate is linked to a sulfate via a common oxygen atom.

List

[edit]
chem mw crystal system space group unit cell Å volume density comment references
sulfoborite Mg3(OH)[B(OH)4]2(SO4)F orthorhombic Pnma a=10.132 b=12.537 c=7.775 987.6 Biaxial (-) nα = 1.527 nβ = 1.536 nγ = 1.551

2V 79°

Max birefringence δ = 0.024

[1]
Heidornite Na2Ca3B5O8(OH)2(SO4)2Cl monoclinic C2/c a = 10.19, b = 7.76, c = 18.81

β = 93.33° Z=4

1,485 2.753 Biaxial (+) nα = 1.579 nβ = 1.588 nγ = 1.604

2V 63° to 77°

Max birefringence δ = 0.025

[2]
Charlesite Ca6Al(SO4)2B(OH)4(O,OH)12•26H2O trigonal P31c a = 11.161, c = 21.212 2,288 1.77 Uniaxial (-) nω = 1.492(3) nε = 1.475(3)

Max birefringence δ = 0.017

[3]
Vitimite Ca6B14O19(SO4)(OH)14•5H2O monoclinic P2/m a = 14.10, b = 19.53, c = 14.05 β = 120.39°=4 3,337 Biaxial (-) nα = 1.532(3) nβ = 1.537(1) nγ = 1.540(1)

Max birefringence δ = 0.008

[4]
Harkerite Ca12Mg4Al(BO3)3(SiO4)4(CO3)5 · H2O trigonal R3m a = 18.131 Å α = 33.46° 1,614 Uniaxial nα = 1.649 - 1.653 nβ = 1.649 - 1.653 [5]
Tatarinovite Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O Hexagonal P63 a = 11.1110, c = 10.6294 1,136 1.79 colourless

Uniaxial (+) nω = 1.475 nε = 1.496

Max birefringence δ = 0.021

[6]
Sturmanite Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12•25H2O trigonal P31c a = 11.16, c = 21.79 Z=2 2,350 yellow

Uniaxial (+/-) nω = 1.499 - 1.500 nε = 1.497 - 1.505

Max birefringence δ = 0.002

[7]
[Ni(atta)(SO4)0.5]·[B5O6(OH)4] 514.13 monoclinic P21/c a=9.0512 b=15.2776 c =15.0142, β=90.325° Z=4 2076.14 1.645 [8]
Buryatite Ca3(Si,Fe,Al)(SO4)[B(OH)4]O(OH)5 · 12H2O trigonal P31c a = 11.14, c = 20.99 Z=4 2,256 1.89 Uniaxial (-) nω = 1.523(3) nε = 1.532(3)

Max birefringence δ = 0.009

[9]
Rb3H(SO4)2(B2O3)2 hexagonal P63/m a = 6.502, c = 19.02 Z=2 2.803 [10]
Fontarnauite Na2Sr(SO4)B5O8(OH)•2H2O monoclinic P21/c a=6.458 b=22.299 c=8.571 β=103.05 Z=4 1,203 [11]
Y(SO4)[B(OH)4](H2O)·H2O triclinic P1 a=5.9679 b=6.8559 c=10.1698 α=79.608 β=76.673 γ=89.220 Z=2 398.02 2.502 [12]
Cs3H(SO4)2(B2O3)2 hexagonal P63/m a = 6.5648, c = 19.5669 Z = 2 3.322 [10]
La(SO4)[B(OH)4](H2O) 331.83 triclinic P1 a=6.2808 b=6.8321 c=8.6830 α=82.475 β=76.758 γ=87.300 Z=2 359.51 3.065 [12]
Pr(SO4)[B(OH)4](H2O)2 351.84 monoclinic P21/m a=6.2359 b=9.5542 c=6.8236 β=93.852 Z=2 405.64 2.881 [12]
Nd(SO4)[B(OH)4](H2O)2 355.17 monoclinic P21/m a=6.2119 b=9.5328 c=6.7923 β=93.755 Z=2 401.35 2.939 [12]
Sm(SO4)[B(OH)4](H2O) 343.27 triclinic P1 a=6.1467 b=6.7280 c=8.6068 α=81.769 β=76.653 γ=87.259 Z=2 342.71 3.326 [12]
Sm(SO4)[B(OH)4](H2O)2 361.30 monoclinic P21/m a=6.1601 b=9.5416 c=6.7589 β=93.816 Z=2 396.39 3.027 [12]
Eu(SO4)[B(OH)4](H2O) 344.88 triclinic P1 a=6.1205 b=6.7090 c=8.5844 α=81.713 β=76.680 γ=87.294 Z=2 339.40 3.375 [12]
Eu(SO4)[B(OH)4](H2O)2 362.89 monoclinic P21/m a=6.1322 b=9.5139 c=6.7343 β=93.683 Z=2 392.08 3.074 [12]
Gd(SO4)[B(OH)4](H2O)2 368.19 monoclinic P21/m a=6.1148 b=9.5078 c=6.7164 β=93.611 Z=2 389.70 3.138 [12]
Tb(SO4)[B(OH)4](H2O)·H2O 369.87 triclinic P1 a=6.0139 b=6.8972 c=10.1753 α=79.616 β=76.590 γ=89.106 Z=2 403.42 3.045 [12]
Dy(SO4)[B(OH)4](H2O)·H2O 373.43 triclinic P1 a=5.9880 b=6.8728 c=10.1638 α=79.652 β=76.597 γ=89.153 Z=2 400.12 3.100 [12]
Ho(SO4)[B(OH)4](H2O)·H2O 375.86 triclinic P1 a=5.9701 b=6.8570 c=10.1580 α=79.588 β=76.636 γ=89.193 Z=2 397.75 3.138 [12]
Er(SO4)[B(OH)4](H2O)·H2O 378.19 triclinic P1 a=5.9529 b=6.8401 c=10.1553 α=79.598 β=76.642 γ=89.198 Z=2 395.54 3.175 [12]
Tm(SO4)[B(OH)4](H2O)·H2O 379.86 triclinic P1 a=5.9289 b=6.8232 c=10.1422 α=79.531 β=76.663 γ=89.263 Z=2 392.40 3.215 [12]
Yb(SO4)[B(OH)4](H2O)·H2O 383.97 triclinic P1 a=5.9150 b=6.8090 c=10.1454 α=79.541 β=76.669 γ=89.243 Z=2 390.82 3.263 [12]
Lu(SO4)[B(OH)4](H2O)·H2O 385.91 triclinic P1 a=5.8992 b=6.7954 c=10.1322 α=79.551 β=76.691 γ=89.266 Z=2 388.53 3.299 [12]
Pb2[(BO2)(OH)](SO4) 570.26 monoclinic P21/m a=6.982 b=5.3917 c=8.167 β=98.643° 303.9 6.231 decompose 335 °C; band gap 4.08 [13]
Pb4(BO3)2(SO4) 1042.44 monoclinic P21/c a=6.9363 b=15.8784 c=9.6053 β=110.770° Z=4 989.15 7.000 melt 689 °C; band gap 4.03 eV [13][14]

References

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  1. ^ "Sulfoborite". www.mindat.org. Retrieved 2020-12-15.
  2. ^ "Heidornite". www.mindat.org. Retrieved 2020-12-15.
  3. ^ "Charlesite". www.mindat.org. Retrieved 2020-12-15.
  4. ^ "Vitimite". www.mindat.org. Retrieved 2020-12-14.
  5. ^ "Harkerite". www.mindat.org. Retrieved 2020-12-14.
  6. ^ "Tatarinovite". www.mindat.org. Retrieved 2020-12-15.
  7. ^ "Sturmanite". www.mindat.org. Retrieved 2020-12-15.
  8. ^ Li, Wei; Deng, Yan-Ling; Pan, Chun-Yang (2022-05-11). "Structural Characterization and ORR Activity of a Copper Complex Borate and an Unexpected [Ni(atta)(SO 4 ) 0.5 ] + Borate-Sulfate". Inorganic Chemistry. 61 (20): 7787–7793. doi:10.1021/acs.inorgchem.2c00187. ISSN 0020-1669. PMID 35543612. S2CID 248695560.
  9. ^ "Buryatite". www.mindat.org. Retrieved 2020-12-15.
  10. ^ a b Daub, Michael; Hillebrecht, Harald (September 2015). "Borosulfates Cs 2 B 2 S 3 O 13 , Rb 4 B 2 S 4 O 17 , and A 3 HB 4 S 2 O 14 ( A = Rb, Cs) - Crystalline Approximants for Vitreous B 2 O 3 ?: Borosulfates Cs 2 B 2 S 3 O 13 , Rb 4 B 2 S 4 O 17 , and A 3 HB 4 S 2 O 14 ( A = Rb, Cs)". European Journal of Inorganic Chemistry. 2015 (25): 4176–4181. doi:10.1002/ejic.201500603.
  11. ^ Cooper, Mark A.; Hawthorne, Frank C.; García-Veigas, Javier; Alcobé, Xavier; Helvaci, Cahit; Grew, Edward S.; Ball, Neil A. (September 2015). "Fontarnauite, (Na,K) 2 (Sr,Ca)(SO 4 )[B 5 O 8 (OH)](H 2 O) 2 , A New Sulfate-Borate Mineral From Doğanlar (Emet), Kütahya Province, Western Anatolia, Turkey". The Canadian Mineralogist. 53 (5): 803–820. Bibcode:2015CaMin..53..803C. doi:10.3749/canmin.1400088. ISSN 0008-4476.
  12. ^ a b c d e f g h i j k l m n o p Wang, Wen-Wen; Xu, Xiang; Kong, Jin-Tao; Mao, Jiang-Gao (2018-01-02). "RE (SO 4 )[B(OH) 4 ](H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures". Inorganic Chemistry. 57 (1): 163–174. doi:10.1021/acs.inorgchem.7b02317. ISSN 0020-1669. PMID 29240405.
  13. ^ a b Ruan, Ting-Ting; Wang, Wen-Wen; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (April 2018). "Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures". Journal of Solid State Chemistry. 260: 39–45. Bibcode:2018JSSCh.260...39R. doi:10.1016/j.jssc.2018.01.013.
  14. ^ Xie, Huiyuan; Wang, Fu; Liao, Biru; Liao, Xiaomin; Chen, Jiayu; Yu, Yang; Hou, Seng; Fan, Xiaoyun (September 2021). "A novel double anion layered photocatalyst Pb4(BO3)2SO4 with enhanced photocatalytic performance for antibiotic degradation". Chemical Engineering Journal. 429: 132344. doi:10.1016/j.cej.2021.132344. ISSN 1385-8947. S2CID 239660006.